精密卫星钟差加密方法及其对星载GPS低轨卫星定轨精度影响

系统分析、比较了几种精密卫星钟差加密方法，研究了利用全球分布的IGS永久跟踪站的GPS观测数据估计高采样率卫星钟差参数的原理与方法，并将各种卫星钟差加密方法得到的结果与IGS数据分析中心估计的卫星钟差结果相比较。最后将不同加密方法得出的精密卫星钟差结果用于基于星载GPS双频非差观测值的CHAMP低轨卫星的定轨，并将不同方法得到的定轨精度进行比较。结果表明，利用地面跟踪站的GPS观测数据，可高精度、高密度地估计GPS卫星钟差，估计精度可达0．1～0．5ns。经地面GPS跟踪站数据估计的GPS卫星钟差，应用于基于PPP方法的低轨卫星定轨，其定轨精度在10cm以内。     

Influence of Atmospheric Carboxylic Acids on Catalytic Oxidation of Sulfur(IV)

The influence of some low weight mono- and di-carboxylic acids, which were selected on the basis of analysis of the water-soluble fraction of size segregated marine and urban aerosols collected in Slovenia, on the kinetics of S(IV) oxidation catalyzed by Mn(II) under conditions representative of tropospheric liquid water, was investigated. Mono-carboxylic acids inhibit the oxidation, with the strongest influence found for formic acid. Inhibition by glycolic and lactic acid was found to be very similar, while the lowest inhibition was caused by acetic acid. Our results are in agreement with the proposed mechanism, i.e. scavenging of sulfate radicals, since the inhibiting effect of the individual acid increases with higher dissociation constant. An exception is formic acid, where the additional inhibiting steps should be responsible for the induction period and thus for higher inhibition. Malic and malonic acids have practically no influence, while oxalic acid slows down the oxidation, although to a lesser extent than mono-carboxylic acids. An extended version of a previously derived generalized simple kinetic model was also derived and applied for predicting the reaction kinetics in the presence of all examined carboxylic acids at pH 3.5 and 4.5.     

Responses of differences in iron and manganese partitioning patterns within and among organs on legume biomass in limestone and sandstone areas

In consideration of the poor correlation between soil and plant nutrient levels, biogeochemists often focus on nutrient stoichiometry, which is mostly used in ecology to indicate the limitation of nutrients in environments. The previous work indicated that the studies of nutrient cycles must go beyond linkage between environmental conditions and plant nutrient concentrations to consider plant internal processes such as growth and nutrient stoichiometry. The plant species composition in calcareous soils with higher pH, generally to be considered P-limited conditions, is expected to differ from that in acidic soils. Many vascular plant species are unable to colonize limestone soils. Thus, floristic composition and soil properties of adjacent limestone and sandstone altitudinal gradients differ greatly in Southwest China. Until now, mechanisms regulating this differing ability of plants to colonize limestone sites have not been elucidated. It is reported that the inability of many plants to establish in limestone sites seems to be related to a low capacity of such plants to solubilize phosphate from these soils. It is reported that the toxicity of manganese and the deficiency of iron were also closely correlated with floristic compositions. We focus on whether similar trends of nutrient distributions occur across different experimental plots during legume growing,     

On the Direction and Magnitude of Oxygen Isotope Fractionation Between Calcite and Aragonite at Thermodynamic Equilibrium

Oxygen isotope fractionation factors between calcium carbonates and water have been applied to ancient marine geochemistry principally for the purpose of geothermometry. The problem was encountered, however, with respect to the direction and magnitude of oxygen isotope fractionation between calcite and aragonite at thermodynamic equilibrium. This basically involves sound understanding of both thermodynamics and kinetics of oxygen isotope fractionation between inorganically precipitated carbonate and water at low temperatures. Thus the crucial issues are to acknowledge the processes of chemical reaction and isotopic exchange during precipitation of CaCO₃ minerals in solution, the kinetic mechanism of isotope equilibrium or disequilibrium, the effect of polymorphic transition from metastable aragonite to stable calcite under hydrous or anhydrous conditions, and the presence or absence of isotope salt effect on oxygen isotope exchange between carbonate and water in response to the hydrous or anhydrous conditions at thermodynamic equilibrium. Because good agreements exist in carbonate–water oxygen isotope fractionation factors between theoretical calculations and experimental determinations, it is encouraging to applying the thermodynamic and kinetic data to isotopic paleothermometry and geochemical tracing.     

微波消解-电感耦合等离子体发射光谱法同时测定白云石中铁铝钙镁钾钠硫

采用微波消解白云石样品，电感耦合等离子体发射光谱法测定其中铁、铝、钙、镁、钾、钠、硫的氧化物，对微波消解条件和等离子体发射光谱仪的工作条件进行了选择，克服了常规化学分析方法步骤繁琐、耗时长、工作量大的不足。利用所建立的方法快速分析了白云石中铁、铝、钙、镁、钾、钠、硫的含量，结果与标准值或化学法相符，10次测定的相对标准偏差（RSD）7种元素均小于1％，可以满足生产和科研的要求。     

官地银金矿中锰的化学物相分析

根据官地银金矿中锰矿物的共生组合情况，引用Al（NO3）3溶液作碳酸锰矿物的选择性溶剂，H2SO4-KF-HF混合溶液作水锰矿、褐锰矿的选择性溶剂，于滤渣中测定软锰矿（包括少量硅酸锰矿物）。实验表明，所引方法适用于官地银金矿区锰矿物的相态分离，所得结果与外检结果一致，满足了矿床划带的实际需要。     

Short Note: On the Relativistic Doppler Effect for Precise Velocity Determination using GPS

The Doppler effect is the apparent shift in frequency of an electromagnetic signal that is received by an observer moving relative to the source of the signal. The Doppler frequency shift relates directly to the relative speed between the receiver and the transmitter, and has thus been widely used in velocity determination. A GPS receiver-satellite pair is in the Earth’s gravity field and GPS signals travel at the speed of light, hence both Einstein’s special and general relativity theories apply. This paper establishes the relationship between a Doppler shift and a user’s ground velocity by taking both the special and general relativistic effects into consideration. A unified Doppler shift model is developed, which accommodates both the classical Doppler effect and the relativistic Doppler effect under special and general relativities. By identifying the relativistic correction terms in the model, a highly accurate GPS Doppler shift observation equation is presented. It is demonstrated that in the GPS “frequency” or “velocity” domain, the relativistic effect from satellite motion changes the receiver-satellite line-of-sight direction, and the measured Doppler shift has correction terms due to the relativistic effects of the receiver potential difference from the geoid, the orbit eccentricity, and the rotation of the Earth.     

A synthetic Earth Gravity Model Designed Specifically for Testing Regional Gravimetric Geoid Determination Algorithms

A synthetic [simulated] Earth gravity model (SEGM) of the geoid, gravity and topography has been constructed over Australia specifically for validating regional gravimetric geoid determination theories, techniques and computer software. This regional high-resolution (1-arc-min by 1-arc-min) Australian SEGM (AusSEGM) is a combined source and effect model. The long-wavelength effect part (up to and including spherical harmonic degree and order 360) is taken from an assumed errorless EGM96 global geopotential model. Using forward modelling via numerical Newtonian integration, the short-wavelength source part is computed from a high-resolution (3-arc-sec by 3-arc-sec) synthetic digital elevation model (SDEM), which is a fractal surface based on the GLOBE v1 DEM. All topographic masses are modelled with a constant mass-density of 2,670 kg/m³. Based on these input data, gravity values on the synthetic topography (on a grid and at arbitrarily distributed discrete points) and consistent geoidal heights at regular 1-arc-min geographical grid nodes have been computed. The precision of the synthetic gravity and geoid data (after a first iteration) is estimated to be better than 30 μ Gal and 3 mm, respectively, which reduces to 1 μ Gal and 1 mm after a second iteration. The second iteration accounts for the changes in the geoid due to the superposed synthetic topographic mass distribution. The first iteration of AusSEGM is compared with Australian gravity and GPS-levelling data to verify that it gives a realistic representation of the Earth’s gravity field. As a by-product of this comparison, AusSEGM gives further evidence of the north–south-trending error in the Australian Height Datum. The freely available AusSEGM-derived gravity and SDEM data, included as Electronic Supplementary Material (ESM) with this paper, can be used to compute a geoid model that, if correct, will agree to in 3 mm with the AusSEGM geoidal heights, thus offering independent verification of theories and numerical techniques used for regional geoid modelling.Electronic Supplementary Material Supplementary material is available in the online version of this article at http://dx.doi.org/10.1007/s00190-005-0002-z     

Characterization and Quantification of Uncertainty in?Coregionalization Analysis

Coregionalization analysis has been presented as a method of multi-scale analysis for multivariate spatial data. Despite an increasing use of this method in environmental and earth sciences, the uncertainty associated with the estimation of parameters in coregionalization analysis (e.g., sills and functions of sills) is potentially high and has not yet been characterized. This article aims to discuss the theory underlying coregionalization analysis and assess the robustness and limits of the method. A theoretical framework is developed to calculate the ergodic and fluctuation variance-covariance matrices of least-squares estimators of sills in the linear model of coregionalization. To adjust for the positive semidefiniteness constraint on estimated coregionalization matrices, a confidence interval estimation procedure for sills and functions of sills is presented. Thereafter, the relative importance of uncertainty measures (bias and variance) for sills and structural coefficients of correlation and determination is assessed under different scenarios to identify factors controlling their uncertainty. Our results show that the sampling grid density, the choice of the least-squares estimator of sills, the positive semidefiniteness constraint, the presence of scale dependence in the correlations, and the number and range of variogram models, all affect the level of uncertainty, sometimes through multiple interactions. The asymptotic properties of variogram model parameter estimators in a bounded sampling domain impose a theoretical limit to their accuracy and precision. Because of this limit, the uncertainty was found to be high for several scenarios, especially with three variogram models, and was often more dependent on the ratio of variogram range to domain extent than on the sampling grid density. In practice, in the coregionalization analysis of a real dataset, the circular requirement for sill estimates in the calculation of uncertainty measures makes the quantification of uncertainty very problematic, if not impossible. The use of coregionalization analysis must be made with due knowledge of the uncertainty levels and limits of the method.