药用滑石粉酸中可溶物测定方法考察

考察药用滑石粉酸中可溶物测定方法的重复性、耐用性 ,分析主要影响因素。比较酸溶物提取液滤过介质对测定结果差异的影响 ;采用重量法随机测定酸溶物含量和室间差异。两种滤过介质处理对测定结果没有显著差异 ;室间测定结果没有显著差异 ;30批样品平行测定结果的 RSD值范围为 0 %～ 18.2 %。酸中可溶物测定法存在重复性和耐用性不佳的问题 ,应相应调整酸中可溶物含量限度     

河北省物理地层界线厘定

以现代地层学多重划分为理论依据,以岩石地层单元组的密度、磁化率、剩余磁化强度及厚度加权算术平均值等物性参数为研究对象,以有序地质量最优分割方法为数学手段,进行河北省全区综合地层柱物理地层界线的厘定,并对其地质意义进行了初步讨论。     

引力位虚拟压缩恢复法

提出了一种将地球表面的引力位虚拟地压缩到地球内部的一个球体表面 ,进而求解在整个地球外部空间 (包括地球边界上 )的重力位场以及重力场的方法     

导航卫星自主定轨的算法研究及模拟结果

讨论了利用卫星-卫星间的距离观测值建立导航卫星系统自主定轨的数学方法，并用GPS星座模拟星间观测值，采用滤波算法计算卫星的状态参数。模拟结果表明，在空间测距精度一定的情况下，自主定轨精度能高于GPS广播星历，因而能较精确地维持卫星系统的坐标框架。     

The influence of particle composition on thorium scavenging in the NE Atlantic ocean (POMME experiment)

²³⁰Th, ²³²Th and ²³⁴Th were analyzed in sinking particles collected by moored and drifting sediment traps in the NE Atlantic Ocean (POMME experiment) in order to constrain the phase(s) carrying Th isotopes in the water column. It reveals a contrasted behaviour between ²³⁴Th and ²³⁰Th. ²³⁴Th is correlated to the particulate organic carbon suggesting that it is primarily scavenged by organic compounds in the surface waters. ²³⁰Th_xs is correlated with Mn, Ba and the lithogenic fraction that are enriched in small suspended particles and incorporated in the sinking particulate flux throughout the water column. The lack of correlation between ²³⁰Th_xs and CaCO₃ or biogenic silica (bSi) indicates that CaCO₃ and bSi are not responsible for ²³⁰Th scavenging in the deep waters of this oceanic region. ²³⁰Th is generally correlated with the lithogenic content of the trapped material but this correlation disappears in winter during strong atmospheric dust inputs suggesting that lithogenic matter is not directly responsible for ²³⁰Th scavenging in the deep waters or that sufficient time is required to achieve particle–solution equilibration. MnO₂ could be the prevalent ²³⁰Th_xs-bearing phase. The narrow range of K_{d_MnO2}^Th obtained for very contrasted oceanic environments supports a global control of ²³⁰Th_xs scavenging by MnO₂ and raises the possibility that the ²³⁰Th–²³¹Pa fractionation is controlled by the amount of colloidal MnO₂ in seawater.     

Chemistry and Sulfur Isotopes in a Chert-dominant Sequence around the Stratiform Manganese Deposit of the Noda-Tamagawa Mine, Northern Kitakami Terrane, Northeast Japan: Implication for Paleoceanographic Environmental Setting

Abstract. Chemistry and sulfur isotopes are analyzed for a series of rocks in the chert‐dominant sequence around the stratiform manganese ore deposit of the Noda‐Tamagawa mine in the northern Kitakami Terrane, northeast Japan. The sequence is litholog‐ically classified into six units in ascending order: lower bedded chert, lower black shale, massive chert, manganese ore, upper black shale, and upper bedded chert. The rocks around the manganese ore deposit exhibit anomalous enrichment in Ni (max. 337 ppm), Zn (102) and U (30) in the upper part of lower bedded chert, Mo (122), Tl (79) and Pb (33) in the lower black shale, MnO, Cu (786) and Co (62) in the manganese ore, and As (247) and Sb (17) in the upper black shale. The aluminum‐normalized profiles reveal zonal enrichment of redox‐sensitive elements around the manganese bed: Zn‐Ni‐Fe‐Mo‐U(‐Co), Tl‐Pb(‐Mo), Mn‐Fe‐Cu‐V‐Cr‐Co(‐Zn) and As‐Sb in ascending order. The uppermost part of the lower bedded chert and black shale exhibit negative Ce/Ce* values, whereas the massive chert, manganese ore and lower part of the upper bedded chert display positive values. The isotopic δ³⁴S values are 0±6 % in the lower part of the lower bedded chert, ‐19 to ‐42 % in the upper part of the lower bedded chert, ‐36 to ‐42 % in the lower black shale, ‐28 to ‐35 % in the massive chert, manganese ore and upper black shale, and ‐23±5 % in the upper bedded chert. Thus, there is a marked negative shift in δ³⁴S values in the lower bedded chert, and an upward‐increasing trend in δ³⁴S through the manganese ore horizon. The present data provide evidence for a change in the paleoceanographic environmental resulting from inflow of oxic deepwater into the stagnant anoxic ocean floor below the manganese ore horizon. This event is likely to have triggered the precipitation of manganese oxyhydroxides. The redistribution of redox‐sensitive elements through the formation of metalliferous black shale and manganese carbonate ore may have occurred in association with bacterial decomposition of organic matter during early diagenesis of initial manganese oxyhydroxides.     

Chemical Profiles across a Jurassic Stratiform Manganese Deposit at Katsuyama in the Mino Terrane of Central Japan: Implications for Depositional Environment, Diagenetic Metal Redistribution and Paleoceanography

Abstract. Inorganic chemical compositions are determined for a series of rocks crossing an Early Jurassic stratiform manganese ore deposit in a chert‐dominant sequence at Katsuyama, in the Mino Terrane of central Japan. The lithology in the vicinity of the manganese ore bed is classified into lower bedded chert, black shale, massive chert, manganese ore and upper bedded chert, in ascending order. The rocks surrounding the manganese deposit are anomalously high in certain elements: Pb (max. 29 ppm), Ni (1140) and Co (336) in the lower bedded chert, Mo (438), As (149), Tl (29) and U (12) in the black shales, V (210) and Cr (87) in the massive chert, and MnO and W (24) in the manganese ore. The aluminum‐normalized profiles reveal a distinct zonation of redox‐sensitive elements: Pb‐Zn, Ni‐Co‐Cu(‐Zn) and U‐Cr in the lower bedded chert, Mo‐As‐Tl in the black shale, V(‐Cr) in the massive chert, and Mn‐Fe‐Ba‐W in the manganese ore, in ascending order. The lower and upper bedded cherts and manganese ore generally exhibit flat rare earth element patterns with positive Ce anomalies, whereas the uppermost part of the lower bedded chert, the black shale and massive chert have flat patterns with weak or nonexistent negative Ce anomalies and weak positive Eu anomalies. The strong enrichment in Ni, Co, W, Tl and As detected in the Katsuyama section is not recognized in other sediments, including those of anoxic deposition origin, but is identified in modern ferromanganese nodules, suggesting that metal enrichment in the Katsuyama section is essentially due to the formation of ferromanganese nodules rather than to deposition in an anoxic environment. The observed elemental zonation is well explained by equilibrium calculations, reflecting early diagenetic formation and associated gradual reduction with depth. The concentration profiles in combination with litho‐ and biostratigraphical features suggest that formation of these bedded manganese deposits was triggered by an influx of warm, saline and oxic water into a stagnant deep ocean floor basin in Panthalassa at the end of the middle Early Jurassic. Paleoceanographic environmental controls thus appear to be important factors in the formation and preservation of this type of stratiform manganese deposit.     

湖南省沉积型锰矿地质环境及成矿作用

湖南省沉积型锰成矿时代跨度大,最早由早元古代板溪群马底驿期至早二叠世孤峰期。其中,早南华纪大塘坡期、中奥陶世烟溪期及中二叠世孤峰期为三个最主要成锰集中期,并且大体呈现出朝东南方向成矿时代变新的趋势。成锰沉积盆地是锰矿床就位的重要场所,相应的岩相古地理环境为锰成矿创造了有利条件,即相对缺氧的、滞流的安静环境。这种环境在诸多古地理环境中都可以形成,导致了锰成矿岩相古地理环境的多样性,如浅海陆棚相、次深海棚缘盆地相、次深海台缘斜坡相及陆表次深海海盆相。三个主要成锰期锰成矿作用具有统一性,成矿作用与地壳拉张、海侵事件、缺氧事件等区域性重大地质事件关联密切。     

北斗卫星导航系统双差动力法精密定轨及其精度分析

针对GEO卫星切向轨道分量与双差模糊度强相关的问题,对经典双差动力法进行了改进,提出联合使用载波相位和相位平滑伪距实现北斗系统精密定轨,并从理论上分析了以上处理策略的可行性及对模糊度固定的影响,然后结合北斗系统精密定轨特点,推导给出了利用QIF方法实现北斗卫星双差模糊度固定的基本原理,实测数据分析表明:联合载波相位和相位平滑伪距,既可降低相关性,又可兼顾精度,定轨效果优于经典双差动力法;利用QIF方法能够取得一定的模糊度固定效果,但受观测条件限制,北斗卫星双差模糊度固定成功率整体不高,双差模糊度固定之后对轨道的改进作用有限。     

经验加速度补偿对HY-2A卫星精密定轨的影响

针对HY-2A卫星定轨中存在系统误差的问题,该文提出了加入经验加速度补偿系统误差。为了获得HY-2A卫星的高精度轨道,采用星载DORIS距离变率数据探索了经验加速度对定轨精度的影响。探讨了1d、3d和7d作为经验加速度周期的定轨精度差异,分析了3d作为经验加速度周期时在径向、法向和切向3个方向设置经验加速度对定轨精度的不同影响。研究结果表明:HY-2A卫星在径向和切向不存在系统误差,而在法向存在系统误差,因而在法向设置经验加速度进行力学模型补偿能够取得较好的定轨结果;3d作为经验加速度的补偿周期较为合适,不仅能够减少解算参数个数,缩短计算时间,而且径向定轨精度可达到1.00cm,满足HY-2A卫星精密定轨需求。