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31.
文章主要介绍应用 X射线荧光现场取样技术在新疆喀拉通克铜镍矿井下现场测定铜镍品位 ,快速评价矿石质量和降低工人劳动强度的方法和效率 相似文献
32.
热液矿床石英铅同位素组成及其地质意义 总被引:1,自引:0,他引:1
作者以若尔盖铀矿床为例,研究了含矿热液形成的石英脉石英的铅同位素组成,并将其作为联系母源铅同位素组成的桥梁,判别铀的来源。结果表明,矿床中石英铅同位素组成与含矿黄铁矿和中酸性构造-岩浆成因的花岗岩铅同位素组成具线性演化关系。由此提出含矿热液中的铀来自中酸性构造-岩浆岩而不是地层岩石的新见解,同时提出利用热液石英铅同位素组成判别非放射性矿床成矿元素来源的可能性。 相似文献
33.
催化褪色光度法测定痕量锰的研究及应用 总被引:2,自引:0,他引:2
本研究了在PH=4.0醋酸-醋酸钠缓冲溶液中,锰催化KIO4氧化5-Br-PADAP的褪色反应及其动力学条件,建立了一个痕量锰的高灵敏度新方法,方法灵敏度为1.32×10^-10g/ml,测定范围Mn^2+浓度为0 ̄1.5μg/ml,用于测定人发,自来水,茶叶中痕量锰,结果满意。 相似文献
34.
本文详细论述了微波焙烧炉代替马弗炉应用于样品焙烧、熔融、活性炭灰化工作中的实际效果。结果表明:其应用不但可行,而且与马弗炉相比,微波焙烧炉具有更加优越的经济性与环保效果。 相似文献
35.
药用滑石粉酸中可溶物测定方法考察 总被引:1,自引:0,他引:1
考察药用滑石粉酸中可溶物测定方法的重复性、耐用性 ,分析主要影响因素。比较酸溶物提取液滤过介质对测定结果差异的影响 ;采用重量法随机测定酸溶物含量和室间差异。两种滤过介质处理对测定结果没有显著差异 ;室间测定结果没有显著差异 ;30批样品平行测定结果的 RSD值范围为 0 %~ 18.2 %。酸中可溶物测定法存在重复性和耐用性不佳的问题 ,应相应调整酸中可溶物含量限度 相似文献
36.
37.
M. Roy-Barman C. Jeandel M. Souhaut M. Rutgers van der Loeff I. Voege N. Leblond R. Freydier 《Earth and Planetary Science Letters》2005,240(3-4):681-693
230Th, 232Th and 234Th were analyzed in sinking particles collected by moored and drifting sediment traps in the NE Atlantic Ocean (POMME experiment) in order to constrain the phase(s) carrying Th isotopes in the water column. It reveals a contrasted behaviour between 234Th and 230Th. 234Th is correlated to the particulate organic carbon suggesting that it is primarily scavenged by organic compounds in the surface waters. 230Thxs is correlated with Mn, Ba and the lithogenic fraction that are enriched in small suspended particles and incorporated in the sinking particulate flux throughout the water column. The lack of correlation between 230Thxs and CaCO3 or biogenic silica (bSi) indicates that CaCO3 and bSi are not responsible for 230Th scavenging in the deep waters of this oceanic region. 230Th is generally correlated with the lithogenic content of the trapped material but this correlation disappears in winter during strong atmospheric dust inputs suggesting that lithogenic matter is not directly responsible for 230Th scavenging in the deep waters or that sufficient time is required to achieve particle–solution equilibration. MnO2 could be the prevalent 230Thxs-bearing phase. The narrow range of Kd_MnO2Th obtained for very contrasted oceanic environments supports a global control of 230Thxs scavenging by MnO2 and raises the possibility that the 230Th–231Pa fractionation is controlled by the amount of colloidal MnO2 in seawater. 相似文献
38.
Abstract. Chemistry and sulfur isotopes are analyzed for a series of rocks in the chert‐dominant sequence around the stratiform manganese ore deposit of the Noda‐Tamagawa mine in the northern Kitakami Terrane, northeast Japan. The sequence is litholog‐ically classified into six units in ascending order: lower bedded chert, lower black shale, massive chert, manganese ore, upper black shale, and upper bedded chert. The rocks around the manganese ore deposit exhibit anomalous enrichment in Ni (max. 337 ppm), Zn (102) and U (30) in the upper part of lower bedded chert, Mo (122), Tl (79) and Pb (33) in the lower black shale, MnO, Cu (786) and Co (62) in the manganese ore, and As (247) and Sb (17) in the upper black shale. The aluminum‐normalized profiles reveal zonal enrichment of redox‐sensitive elements around the manganese bed: Zn‐Ni‐Fe‐Mo‐U(‐Co), Tl‐Pb(‐Mo), Mn‐Fe‐Cu‐V‐Cr‐Co(‐Zn) and As‐Sb in ascending order. The uppermost part of the lower bedded chert and black shale exhibit negative Ce/Ce* values, whereas the massive chert, manganese ore and lower part of the upper bedded chert display positive values. The isotopic δ34S values are 0±6 % in the lower part of the lower bedded chert, ‐19 to ‐42 % in the upper part of the lower bedded chert, ‐36 to ‐42 % in the lower black shale, ‐28 to ‐35 % in the massive chert, manganese ore and upper black shale, and ‐23±5 % in the upper bedded chert. Thus, there is a marked negative shift in δ34S values in the lower bedded chert, and an upward‐increasing trend in δ34S through the manganese ore horizon. The present data provide evidence for a change in the paleoceanographic environmental resulting from inflow of oxic deepwater into the stagnant anoxic ocean floor below the manganese ore horizon. This event is likely to have triggered the precipitation of manganese oxyhydroxides. The redistribution of redox‐sensitive elements through the formation of metalliferous black shale and manganese carbonate ore may have occurred in association with bacterial decomposition of organic matter during early diagenesis of initial manganese oxyhydroxides. 相似文献
39.
Abstract. Inorganic chemical compositions are determined for a series of rocks crossing an Early Jurassic stratiform manganese ore deposit in a chert‐dominant sequence at Katsuyama, in the Mino Terrane of central Japan. The lithology in the vicinity of the manganese ore bed is classified into lower bedded chert, black shale, massive chert, manganese ore and upper bedded chert, in ascending order. The rocks surrounding the manganese deposit are anomalously high in certain elements: Pb (max. 29 ppm), Ni (1140) and Co (336) in the lower bedded chert, Mo (438), As (149), Tl (29) and U (12) in the black shales, V (210) and Cr (87) in the massive chert, and MnO and W (24) in the manganese ore. The aluminum‐normalized profiles reveal a distinct zonation of redox‐sensitive elements: Pb‐Zn, Ni‐Co‐Cu(‐Zn) and U‐Cr in the lower bedded chert, Mo‐As‐Tl in the black shale, V(‐Cr) in the massive chert, and Mn‐Fe‐Ba‐W in the manganese ore, in ascending order. The lower and upper bedded cherts and manganese ore generally exhibit flat rare earth element patterns with positive Ce anomalies, whereas the uppermost part of the lower bedded chert, the black shale and massive chert have flat patterns with weak or nonexistent negative Ce anomalies and weak positive Eu anomalies. The strong enrichment in Ni, Co, W, Tl and As detected in the Katsuyama section is not recognized in other sediments, including those of anoxic deposition origin, but is identified in modern ferromanganese nodules, suggesting that metal enrichment in the Katsuyama section is essentially due to the formation of ferromanganese nodules rather than to deposition in an anoxic environment. The observed elemental zonation is well explained by equilibrium calculations, reflecting early diagenetic formation and associated gradual reduction with depth. The concentration profiles in combination with litho‐ and biostratigraphical features suggest that formation of these bedded manganese deposits was triggered by an influx of warm, saline and oxic water into a stagnant deep ocean floor basin in Panthalassa at the end of the middle Early Jurassic. Paleoceanographic environmental controls thus appear to be important factors in the formation and preservation of this type of stratiform manganese deposit. 相似文献
40.
湖南省沉积型锰矿地质环境及成矿作用 总被引:2,自引:0,他引:2
湖南省沉积型锰成矿时代跨度大,最早由早元古代板溪群马底驿期至早二叠世孤峰期。其中,早南华纪大塘坡期、中奥陶世烟溪期及中二叠世孤峰期为三个最主要成锰集中期,并且大体呈现出朝东南方向成矿时代变新的趋势。成锰沉积盆地是锰矿床就位的重要场所,相应的岩相古地理环境为锰成矿创造了有利条件,即相对缺氧的、滞流的安静环境。这种环境在诸多古地理环境中都可以形成,导致了锰成矿岩相古地理环境的多样性,如浅海陆棚相、次深海棚缘盆地相、次深海台缘斜坡相及陆表次深海海盆相。三个主要成锰期锰成矿作用具有统一性,成矿作用与地壳拉张、海侵事件、缺氧事件等区域性重大地质事件关联密切。 相似文献