原子吸收分光光度法快速测定铬铁矿中钙、镁、锰

通过在标液中加入相应的Sr来消除离子干扰,采用原子吸收分光光度法快速测定CaO、MgO、MnO的含量,方法经国家标准物质验证,其RSD<2%(n=6)。其结果与标准值相符。方法达到了准确、简便、快速、实用性强。     

利用中心差分法进行GPS定速时最佳点数的选取

分析了利用中心差分法进行GPS定速时的主要误差来源,证明了当数据采样率一定时,增加中心差分法的点数可减少微分过程中的截断误差,但同时会放大导出相位率的观测误差,得出中心差分法的最佳点数应使这两种误差之和最小的结论。实验结果表明,当数据采样间隔为1s、载体平均速度和加速度为20m.s-1和0.2m.s-2时,9个点的中心差分法定速精度最高。     

利用C波段转发数据实现GEO卫星轨道确定

为了提高我国卫星导航系统GEO卫星定轨能力,针对我国卫星导航系统所特有的新数据和新方法,利用CAPS系统的C波段转发式测距数据进行了单GEO卫星定轨实验.在分析该方法技术特点的基础上,从定轨残差和轨道重叠弧段比较等方面,对定轨结果进行了分析.由于设备转发时延是影响该方法定轨精度的重要因素,因此同时还分析了系统偏差对定轨精度的影响,得出了一些有益的结论.     

利用GPS伪距导出的多普勒频移测速

推导了利用伪距观测值获取多普勒频移的公式,并利用导出的多普勒频移来确定载体的速度。实测数据表明,利用伪距导出的多普勒频移测速,可以达到dm/s级的水平。在没有原始多普勒观测值或者相位观测出现了频繁周跳的情况下,可以利用伪距导出的多普勒频移获得载体概略的速度信息。     

The Data Depth-weight-kernel Estimation of the Model Error of Satellite Orbit Determination

It is an objective fact that there exists error in the satellite dynamic model and it will be transferred to satellite orbit determination algorithm, forming a part of the connotative model error. Mixed with the systematic error and random error of the measurements, they form the unitive model error and badly restrict the precision of the orbit determination. We deduce in detail the equations of orbit improvement for a system with dynamic model error, construct the parametric model for the explicit part of the model and nonparametric model for the error that can not be explicitly described. We also construct the partially linear orbit determination model, estimate and fit the model error using a two-stage estimation and a kernel function estimation, and finally make the corresponding compensation in the orbit determination. Beginning from the data depth theory, a data depth weight kernel estimator for model error is proposed for the sake of promoting the steadiness of model error estimation. Simulation experiments of SBSS are performed. The results show clearly that the model error is one of the most important effects that will influence the precision of the orbit determination. The kernel function method can effectively estimate the model error, with the window width as a major restrict parameter. A data depth-weight-kernel estimation, however, can improve largely the robustness of the kernel function and therefore improve the precision of orbit determination.     

Multiple solutions in preliminary orbit determination from three observations

Charlier’s theory (1910) provides a geometric interpretation of the occurrence of multiple solutions in Laplace’s method of preliminary orbit determination, assuming geocentric observations. We introduce a generalization of this theory allowing to take into account topocentric observations, that is observations made from the surface of the rotating Earth. The generalized theory works for both Laplace’s and Gauss’ methods. We also provide a geometric definition of a curve that generalizes Charlier’s limiting curve, separating regions with a different number of solutions. The results are generically different from Charlier’s: they may change according to the value of a parameter that depends on the observations.     

微波消解等离子体发射光谱和石墨炉原子吸收光谱法联合测定土壤中多元素

采用密闭式微波消解系统处理土壤样品,电感耦合等离子体发射光谱法或石墨炉原子吸收光谱法测定土壤样品中铜、砷、铅、锌、钴、铬、锰、镍、钒9个元素。分别从消解液的选择、用酸量及样品消解量等方面进行消解条件的优化,确定了一个最适合土壤消解的前处理体系。各元素的检出限为0.16～2.52μg/g,回收率为95.2%～106.6%,精密度为2.03%～9.79%(n=7)。方法简单快速,效率高,劳动强度低,是进行土壤中多元素测定的高效方法。     

波长色散X射线荧光光谱法测定铜精矿中铜铅锌硫镁砷

采用偏硼酸锂和四硼酸锂混合熔剂熔融法制样,波长色散X射线荧光光谱法测定铜精矿中铜、铅、锌、硫、镁、砷,考察了熔剂、玻璃化试剂和预氧化条件对制样的影响。采用理论α系数和经验系数相结合的方法校正元素间的效应。测定铜精矿试样各组分的相对标准偏差(RSD,n=12)均小于3%,结果与化学分析法吻合。     

Rock Stress,Rock Stress Measurements,and the Integrated Stress Determination Method (ISDM)

The primary objectives of this work are to (1) improve the understanding of the prevailing stress distribution at the Äspö Hard Rock Laboratory (HRL) in SE Sweden by employing an integrated stress determination approach, and in order to accomplish this (2) extend the existing stress integration methodology denominated integrated stress determination method (ISDM; Cornet in Comprehensive Rock Engineering vol 3, Pergamon Press, Oxford, pp 413–432, 1993a). The new developments of the ISDM involve a 12-parameter representation of the regional stress field in the rock mass (i.e., the full stress tensor and its variation with depth) that is applicable to hydraulic stress data (sleeve fracturing, hydraulic fracturing, and hydraulic tests on pre-existing fractures), overcoring data (CSIR- and CSIRO-type of devices), and to combinations of hydraulic and overcoring stress data. For the latter case, the elastic parameters of the overcoring technique may be solved in situ by allowing the hydraulic stress data to constrain them. As a result, the problem then involves 14 model parameters. Results from the study show that the ISDM effectively improves the precision of the prevailing stress field determination and that it is especially powerful for identification of consistencies/inconsistencies in an existing data set. Indeed, this is the very basic premise and goal of stress integration; combine all available data to achieve as complete a characterization of the mechanical stress model as possible, and not to identify a solution that fits only loosely the maximum amount of stress data.     

Evidence for microbiological manganese oxidation in the river Tamar Estuary, South West England

Water samples from the Tamar Estuary oxidized manganese when supplemented with Mn²⁺ (2 mgl⁻¹). The rates of oxidation were depressed in the presence of various metabolic inhibitors. The effect of Mn²⁺ and temperature on the rate of manganese oxidation suggested that a biological process was largely responsible for converting Mn²⁺ to Mn⁴⁺. Rates of manganese oxidation were much higher in freshwater (3·32 μgl⁻¹ h⁻¹ in water containing 30 mgl⁻¹ of suspended matter) than in saline water (0·7 μgl⁻¹ h⁻¹ in water of salinity 32‰) containing the same amount of particulate matter. The rate of manganese oxidation was proportional to the particulate load (up to 100 mgl⁻¹ particulates).