Synthesis, crystal structure and crystal chemistry of ferri-clinoholmquistite, ?Li 2Mg 3Fe 3+ 2Si 8O 22(OH) 2

This work reports the synthesis of ferri-clinoholmquistite, nominally _Li2(Mg₃Fe³⁺₂)Si₈O₂₂(OH)₂, at varying f_O2 conditions. Amphibole compositions were characterized by X-ray (powder and single-crystal) diffraction, microchemical (EMPA) and spectroscopic (FTIR, Mössbauer and Raman) techniques. Under reducing conditions ( NNO+1, where NNO = Nickel–Nickel oxide buffer), the amphibole yield is very high (>90%), but its composition, and in particular the FeO/Fe₂O₃ ratio, departs significantly from the nominal one. Under oxidizing conditions ( NNO+1.5), the amphibole yield is much lower (<60%, with Li-pyroxene abundant), but its composition is close to the ideal stoichiometry. The exchange vector of relevance for the studied system is ^M2(Mg,Fe²⁺) ^M4(Mg,Fe²⁺) ^M2Fe³⁺_–1 ^M4Li_–1, which is still rather unexplored in natural systems. Amphibole crystals of suitable size for structure refinement were obtained only at 800 °C, 0.4 GPa and NNO conditions (sample 152), and have C2/m symmetry. The X-ray powder patterns for all other samples were indexed in the same symmetry; the amphibole closest to ideal composition has a = 9.428(1) Å, b = 17.878(3) Å, c = 5.282(1) Å, = 102.06(2)°, V = 870.8(3) ų. Mössbauer spectra show that Fe³⁺ is strongly ordered at M2 in all samples, whereas Fe²⁺ is disordered over the B and C sites. FTIR analysis shows that the amount of ^CFe²⁺ increases for increasingly reducing conditions. FTIR data also provide strong evidence for slight but significant amounts of Li at the A sites.     

浅谈高等级三角高程测量在水电工程高程测量中的应用

水电工程一般建在深山峡谷中,陡坎多、高差大,不利于几何水准测量。三角高程测量不受地形起伏限制,外业测量工作量小、速度快,作业人员少,在水电工程低精度高程测量中应用广泛。怎样提高三角高程测量精度,一直是大家关注的问题。本文介绍了溪洛渡水电站三角高程测量的实践经验供大家借鉴。     

地球物理台网仪器维修信息管理的研究与实现

针对地球物理台网仪器维修信息化薄弱的现状,提出一个规范的地球物理台网仪器维修流程,并对故障仪器的流通和维修订单的处理动作等信息进行研究,设计了满足地球物理台网仪器维修信息管理的数据库结构,设计和实现了基于B/S架构的仪器维修管理系统,并在全国地球物理台网业务中部署使用。该系统具有可视化流程操作、维修资源弹性可扩展、维修信息共享和维修资源协同化的特点,满足地球物理台网仪器维修信息化管理需要,并为其它地震仪器信息化管理系统的设计提供了借鉴。     

基于假三元模型的透辉石-硬玉固溶体热力学性质计算

自然界中矿物多以固溶体形式存在,据其晶体化学特征计算热力学性质是开展矿物成因理论研究的基础。本文引入描述二元矿物固溶体热力学性质的假三元模型,计算得到了透辉石-硬玉固溶体系列的热力学性质。该模型通过构造一种高度有序的中间相,同时考虑长程和短程有序效应,基于热力学平衡态矿物固溶体自由能最低的规律,可以计算特定组分下矿物的平衡自由能、焓和熵等热力学参数。本文针对透辉石-硬玉固溶体体系,取绿辉石为其中间有序态,计算了其活度-成分关系和温度-组分相图等,发现绿辉石随温度升高的有序无序相变为一级相变,相变温度为1 148±25 K,与实验研究结果一致。本文获得的透辉石-绿辉石-硬玉体系的热力学参数可用于视剖面图方法研究MORB成分的岩石的榴辉岩相变质作用过程。     

Dynamic,discontinuous stream networks: hydrologically driven variations in active drainage density,flowing channels and stream order

Despite decades of research on the ecological consequences of stream network expansion, contraction and fragmentation, surprisingly little is known about the hydrological mechanisms that shape these processes. Here, we present field surveys of the active drainage networks of four California headwater streams (4–27 km²) spanning diverse topographic, geologic and climatic settings. We show that these stream networks dynamically expand, contract, disconnect and reconnect across all the sites we studied. Stream networks at all four sites contract and disconnect during seasonal flow recessions, with their total active network length, and thus their active drainage densities, decreasing by factors of two to three across the range of flows captured in our field surveys. The total flowing lengths of the active stream networks are approximate power‐law functions of unit discharge, with scaling exponents averaging 0.27 ± 0.04 (range: 0.18–0.40). The number of points where surface flow originates obey similar power‐law relationships, as do the lengths and origination points of flowing networks that are continuously connected to the outlet, with scaling exponents averaging 0.36–0.48. Even stream order shifts seasonally by up to two Strahler orders in our study catchments. Broadly, similar stream length scaling has been observed in catchments spanning widely varying geologic, topographic and climatic settings and spanning more than two orders of magnitude in size, suggesting that network extension/contraction is a general phenomenon that may have a general explanation. Points of emergence or disappearance of surface flow represent the balance between subsurface transmissivity in the hyporheic zone and the delivery of water from upstream. Thus the dynamics of stream network expansion and contraction, and connection and disconnection, may offer important clues to the spatial structure of the hyporheic zone, and to patterns and processes of runoff generation. Copyright © 2014 John Wiley & Sons, Ltd.     

Solid–fluid transition modelling in geomaterials and application to a mudflow interacting with an obstacle

Given the contrasting behaviour observed for geomaterials, for example, during landslides of the flow type, this contribution proposes an original constitutive model, which associates both an elasto‐plastic relation and a Bingham viscous law linked by a mechanical transition criterion. This last is defined as the second‐order work sign for each material point, which is a general criterion for divergence instabilities. Finite element method with Lagrangian integration points is chosen as a framework for implementing the new model because of its well‐known ability to deal with both solid and fluid behaviours in large deformation processes. A first boundary model considering a sample of initially stable soil, a slope and an obstacle is performed. The results show the power of the constitutive model because the consistent evolution of initiation, propagation and arrest of the mudflow is described. A parametric study is led on various plastic and viscous parameters to determine their influence on the flow development and arrest. Finally, forces against the obstacle are compared with good agreement with those of other authors for the same geometry and a pure viscous behaviour. Copyright © 2014 John Wiley & Sons, Ltd.     

一种基于元规则的地理国情普查元数据时间顺序自动检查方法

元数据作为地理国情普查的重要组成部分,其数据质量决定整个作业流程的可靠性,而元数据的时间顺序检查一直没有自动高效的方法。根据第一次全国地理国情普查对元数据的具体要求,本文提出一种高效准确的检查方法,并得到实践检验,可为地理国情普查质检工作提供技术参考。     

蒙皂石伊利石化反应机理和框架性行为模式

对珠江口盆地两口钻井95个泥质岩样粘土矿物X衍射分析资料的定量研究表明,若反应是以消耗蒙皂石为代价形成伊利石,则反应符合溶解-沉淀机理,但除此以外,蒙皂石还可以净溶解或新增伊利石层的方式加大I/S比。蒙皂石在渐进成岩过程中的框架性行为模式具有三级控制,按顺序分别由温度、基本离子成分和动力学因素控制特定温度段内蒙皂石行为过程的起始和终结、行为过程的方式和行为过程的速率和程度。渐进成岩过程中I/S比的变化主要与第三级控制有关,而游离状蒙皂石和伊-蒙混层粘土的含量变化则是第二三两级共同控制的结果。     

高阶脉冲标定器及观测系统幅频特性

在前阶段理论研究的基础上,搜寻到了几种高阶脉冲波形,其频谱的低频分量平坦,高频分量更丰富。据此制成功能完善,性能优良的标定器。用高阶脉冲标定器产生的标定电流来激励拾震器,使观测系统产生相应的响应,由计算机采集该响应,并进行富氏变换及相关运算。由此可得到系统的幅频特性Ｋ（ω）,为暂态标定结果。对于速度 平坦型观测系统暂态标定与稳定态标定所得的特性曲线完全重合,即标定精度相同。