电感耦合等离子体发射光谱法测定铅锌矿中15个主次量元素

铅锌矿多元素同时测定中,样品预处理过程受多种不同因素的影响,单因素试验往往无法同时为多因素实验提供合理的优化方案。本文采用盐酸-硝酸溶矿,考察了样品预处理过程中混合酸配比、混合酸体积、消解时间及消解温度对消解效果的影响,利用正交试验设计及极差分析确定了最优消解条件:盐酸-硝酸混合酸配比3∶1,混合酸体积10 m L,消解时间120 min,消解温度90℃,用电感耦合等离子体发射光谱法同时测定铅锌矿中15个主次量元素(铅锌铜锰砷银铋镉钴镍镓铟钼锗锑)的含量。在最优条件下,用富铅锌矿石国家标准物质(GBW 07165)进行试验,大多数元素的精密度(RSD,n=12)和准确度小于5%,方法检出限为0.0019~0.048μg/g。基于铅锌矿主要是以硫化物形式存在,采用一系列硫化物国家标准物质验证方法的准确度及可行性,检测结果基本都在标准值的误差范围内。应用该方法分析湖南某矿区中大批量铅锌矿样品,标样质量统计合格率为100%,密码质量统计合格率大于97%。     

既有路基下浅埋隧道开挖引起地层的位移及应力解析解

在既有公路下进行浅埋隧道开挖会引起地层产生位移,导致地表沉降。为了保证施工安全,快速精确地计算地层位移及应力,有效地控制地表沉降,对浅埋隧道的设计与施工均十分重要。在镜像法原理的基础上,引入等效模量当层法,推导出了在有上覆不同材料下浅埋圆形隧道开挖引起地层位移、应力及地表沉降的解析分布规律。计算结果表明,既有路基下开挖隧道引起地层产生的位移和应力解析解能够很好地体现上层高弹性模量路基对沉降及应力的扩散作用,可以求得隧道开挖后洞周地层包括上覆路基及下卧层中任意位置处的位移、应力以及地表沉降,为在双层地基材料中开挖浅埋隧道引起地层位移及地表沉降的计算提供了一种新的解析方法。     

Upper Ocean Four-Dimensional Variational Data Assimilation in the Arabian Sea and Bay of Bengal

A regional ocean circulation model with four-dimensional variational data assimilation scheme is configured to study the ocean state of the Indian Ocean region (65°E–95°E; 5°N–20°N) covering the Arabian Sea (AS) and Bay of Bengal (BoB). The state estimation setup uses 10 km horizontal resolution and 5 m vertical resolution in the upper ocean. The in-situ temperature and salinity, satellite-derived observations of sea surface height, and blended (in-situ and satellite-derived) observations of sea surface temperature alongwith their associated uncertainties are used for data assimilation with the regionally configured ocean model. The ocean state estimation is carried out for 61 days (1 June to 31 July 2013). The assimilated fields are closer to observations compared to other global state estimates. The mixed layer depth (MLD) of the region shows deepening during the period of assimilation with AS showing higher MLD compared to the BoB. An empirical forecast equation is derived for the prediction of MLD using the air–sea forcing variables as predictors. The surface and sub-surface (50 m) heat and salt budget tendencies of the region are also investigated. It is found that at the sub-surface, only the advection and diffusion temperature and salt tendencies are important.     

番红砗磲外套膜色素提取条件优化及成分分析

以番红砗磲(Tridacna crocea)为实验对象,通过单因素对比实验对其外套膜色素的提取条件进行了优化,并利用薄层层析色谱法对色素组成进行了初步分析。结果表明:丙酮和乙醇为适宜的番红砗磲外套膜色素提取剂;使用丙酮为提取剂时,浸提时间为4 h,提取温度为25℃,料液比为1︰40。使用乙醇为提取剂时,浸提时间为4 h,提取温度为30℃,料液比为1︰200;利用薄层色谱法分离外套膜颜色为蓝色和红棕色的番红砗磲外套膜色素后发现,蓝色番红砗磲外套膜色素由9种色素组分构成,红棕色个体番红砗磲外套膜色素由10种色素组分构成。     

时间域航空电磁数据的反演

本文用广义逆矩阵理论讨论了时间域航空电磁数据的反演方法.以水平二层大地和球体模型为例进行了计算,结果表明这种方法对时间域电磁数据的反演是行之有效的.对于理论数据,一般仅需迭代数次即可稳定地收敛到真值.通过奇异值分析,可以确定一个模型中的相对重要参数和无关紧要参数;对于求解某一特定参数,可确定哪些数据起决定性的作用.由奇异值分解而得出的信息密度矩阵、模型分辨矩阵,分别给出了模型响应拟合数据和模型参数分辨率的度量.这些信息对于时间域航空电磁系统的设计、野外测量和资料解释都具有重要的参考价值.最后给出了实例.     

“暖池”表层对大气局地强迫的响应特征

利用湍流动能垂直混合模式和ＴＯＧＡ－ＣＯＡＲＥ加强观测期的观测资料,对“暖池”上混合层的垂直混合过程进行数值试验和数值模拟,分析表层温度、盐度的变化特征。结果表明：ＴＫＥ模式可以较好地模拟混层,尤其是表层温度、盐度对大气局地强迫的响应;太阳辐射是热源,感热、潜热通量等会造成“暖池”上混合层的温度降低,“暖池”对大气释放热量;降水有利于“淡水盖”形成和维持,从则使层结稳定,ＳＳＴ升高。但在气温低于海     

Role of buffer layer in electronic structures of iron phthalocyanine molecules on Au(111)

We investigate the electronic structures of one and two monolayer iron phthalocyanine (FePc) molecules on Au(111) surfaces. The first monolayer FePc is lying flat on the Au(111) substrate, and the second monolayer FePc is tilted at ～15° relative to the substrate plane along the nearest neighbour [101^-] direction with a lobe downward to the central hole of the unit cell in the first layer. The structural information obtained by first-principles calculations is in agreement with the experiment results. Furthermore, it is demonstrated that the electronic structures of FePc molecules in one-monolayer FePc/Au(111) system are perturbed significantly, while the electronic structures of FePc molecules in the second monolayer in two-monolayer FePc/Au(111) system remain almost unchanged due to the screening of the buffer layer on Au(111).     

Tides in the Tongan Region of the Pacific Ocean

Tidal levels and currents in the Tongan region of the Pacific were simulated using a two-dimensional frequency-domain finite element model. The eight major diurnal and semidiurnal tidal constituents were modeled successfully, using open boundary conditions taken from a global tidal model based on the Topex/Poseidon satellite altimeter. Comparison of model results with observations from the single tide gauge site in the area were later used to adjust the boundary conditions. The validity of omitting horizontal eddy viscosity from the finite element model was checked by running an equivalent finite difference model. The results show that although the submarine Tongan ridge does not appear to trap tidal energy, there are residual tidal currents and possible recirculations which are capable of influencing biological productivity around Tonga. The model results are reduced to a simple method for predicting tidal heights in outlying areas, based only on the tidal calendar for the capital, Nuku'alofa.     

Nitrogen utilisation by size‐fractionated phytoplankton assemblages associated with an upwelling event off Westland,New Zealand

Abstract

Uptake rates of ammonium (NH₄ ⁺ ), nitrate (NO₃ ^? ), and urea by three subgroups of phytoplankton (< 200, < 20, < 2 μm) off Westland, were measured using ¹⁵ N tracer techniques in midwinter 1988, after a recent upwelling. For all size fractions at surface irradiance (I₁₀₀), nitrogen (N) was taken up primarily as NO₃ ^?. This accounted for 67–85% of total N uptake (SρN), whereas at 40 and 7% of surface irradiance, the regenerated N (NH₄ ⁺ ) and urea) made up 31–72% of SρN. Depth profile experiments for all three size components showed that uptake of NO₃ ^? was most light‐sensitive, followed by that of NH₄ ⁺ and urea. The irradiance and nutrient availability plot indicated that light was substantially more important than the nutrient concentrations in controlling the assimilation of N by microplankton (20–200 μm). Nano‐ (2–20 μm) and picoplankton (< 2 μm) however, were not as sensitive to either light or nutrient concentrations. High winds and the resulting deep mixing, combined with offshore and alongshore advection in the midwinter, were suggested to be the major cause of the low biomass and N productivity.