Fresh snow chemistry from high mountain regions in central himalayas

Investigations of atmospheric composition in the Himalayas has been limited in both temporal and spatial scales, mainly due to difficult logistics. Ideal sites for monitoring atmospheric composition and its evolution should be free from local pollution and representative of the remote troposphere (HUEBERT et al., 1980). As the Himalayas are far removed from highly industrialized regions they provide suitable locations to monitor the chemistry of the remote troposphere and to study the evolu…     

地域功能-结构的空间组织途径——对国土空间规划实施主体功能区战略的讨论

地域功能-结构的空间组织规律是人地系统耦合研究的基本理论问题,也是开展国土空间规划、塑造可持续地理格局的基础理论。从地理学对地理过程的重复、预测、调控、优化的讨论入手,阐释了空间治理体系是现代地理学用于调控和优化可持续地理过程与格局的重要途径。采用生态-生活-生产等三生空间构成的地域功能空间结构呈现的时空演变特征,表达了地域功能-结构的空间有序性法则,阐释了地域功能与自然地理环境相协调、同一地域单元各类功能及不同单元之间冲突最小化、地域功能在不同空间尺度有效传导、以及长时间尺度综合效益最大化等空间组织目标。从可持续性出发,建立自然要素的资源、环境、生态和灾害四大属性的概念,并通过四大属性集成构成自然承载力,分析承载力的原值、余量和潜力在空间规划中的作用,形成自下而上解析空间组织的基本方法。从新空间均衡出发,基于承载力、融入位置和空间结构参量后构成的地域功能适宜性,形成自上而下解析空间组织的基本方法。进而讨论了集成两种方法形成的主体功能区具备的对空间组织与规划的基础价值和战略价值,提出主体功能区的区划、战略、制度和规划用途分离及相互关联的新思路。以实施主体功能区战略为主线、以空间降尺度传导主体功能为核心科学问题、以关键约束参数为空间结构控制性指标,讨论了数据库与地域功能谱系、功能和尺度依赖的承载力评价方法与模型库、“三区三线”的建构框架,论证了空间规划实施主体功能区战略的途径,提出地理学应着力加强大、中空间尺度（区域性）国土空间规划基础理论和方法、强化技术等科技支撑体系建设的建议。     

TOC-IRMS联用在线高温氧化测定溶解有机碳稳定同位素组成的方法研究

本研究利用总有机碳分析仪联用稳定同位素质谱仪(TOC-IRMS)技术,探讨了高温氧化法测试水体中溶解有机碳(Dissolved Organic Carbon, DOC)含量及稳定碳同位素组成。根据溶解有机碳的组成特征,从氧化难易程度、分子结构等方面选取5种可溶于水的化合物：咖啡因、葡萄糖、邻苯二甲酸、乙酸钾和腐殖酸钠,配置成DOC溶液。通过改变溶液碳含量、氧化温度、通氧量大小,载气流速等参数,研究不同实验条件对DOC碳转化率及δ¹³C值的影响。TOC-IRMS在氧化温度850℃,通氧时长20 s(流速10 cm³/min),载气流速80 cm³/min的条件下,测得5种化合物不同浓度DOC溶液的平均碳转化率为95.69%～103.57%;δ¹³C值与标定参考值基本一致,差值范围为-0.82‰～0.55‰。在上述实验条件下,测得不同类型水样的DOC含量相对标准偏差小于3.7%,δ¹³C值的标准偏差小于0.2‰,结果表明TOC-IRMS联用在线高温氧化法测定不同类型水样的DOC含量...     

FLOW SEPARATION IN UNDISTURBED SOILS USING MULTIPLE ANIONIC TRACERS. PART 1. ANALYTICAL METHODS AND UNSTEADY RAINFALL AND RETURN FLOW EXPERIMENTS

Tracers provide one of the few ways of obtaining realistic information on the flows of water and solutes in undisturbed structured soils. Three fluorinated organic acids [pentafluorobenzoic acid, 2,6-diflurobenzoic acid and o-(trifluoromethyl) benzoic acid] and bromide were tested as anionic tracers in situations where the separation of different flow components is of interest. The fluorobenzoates were relatively conservative (approximately 90% for loam soil) although, in some instances, co-elution or complexation may lead to apparently non-conservative behaviour. Tracer mixtures applied to soils, were separated and quantified by high-performance liquid chromatography. The relative mobilities of the tracers were studied during unidirectional steady flow in large undisturbed soil columns brought back to the laboratory. The breakthrough curves showed highly dispersive behaviour, with very early breakthrough of solute and a long tail. Contributions to the column outflow of different simultaneous applications of rainfall and return flow, labelled with different tracers, were separated using multicomponent mixing equations. The results show the importance of preferential flow and relatively immobile storage in the transport process.     

FLOW SEPARATION IN UNDISTURBED SOIL USING MULTIPLE ANIONIC TRACERS. PART 2. STEADY-STATE CORE-SCALE RAINFALL AND RETURN FLOWS AND DETERMINATION OF DISPERSION PARAMETERS

A series of experiments designed to study the separation of flow components from two large undisturbed cores under steady-state rainfall (downward) and return (upward) flows under near-saturated conditions is summarized. The experiments were conducted on soil columns collected from Lancaster University and the Slapton Wood catchment, Devon. The use of the relatively conservative tracers, potassium bromide, o-(trifluoromethyl)benzoic acid and 2,6-difluorobenzoic acid and a combination of application rates made it possible to quantify the different sources of water contributing to the discharge hydrographs. There is significant retention of tracer within the cores, despite the application of several pore volumes of water. The use of steady flow conditions allowed the determination of dispersion coefficients, dispersivity and proportion of ‘mobile’ water content parameters of the advection–dispersion equation. It was found that there were significant differences between the dispersivities at different flow-rates under upward and downward flux conditions and that in the undisturbed cores studied here the apparent proportions of mobile pore water ranged between 0.33 and 1.0, with an apparently complex relationship to flux rate. Prediction of transport in undisturbed soil remains problematic and tracer experiments will continue to be needed to provide a fundamental understanding of the complex flow processes involved.     

额济纳绿洲沙尘暴沉积特征

1 Introduction Oases are unique ecosystems and important residences for our ancestors in arid and semiarid regions of the world, and have deeply been imprinted by human actions, such as Jericho oasis of Jordan Valley, Jarmo oasis of the Euphrates River an…     

华南红土主元素表生地球化学特征

华南红土从其母岩到表土,普遍表现为主元素SiO2、K2O、Na2O淋失,Fe2O3、Al2O3、N、S富集。红土饱和水含量最高的是D2型红土,最低的是老红沙型红土。在岩石与上层红土风化特征中,风化强度以γ型红土最强,而灰岩型红土最弱;淋溶系数最大的是灰岩型红土,最小的为γ型红土;变异系数最大的为灰岩型红土,最小的为Q2型红土。从空间上看,红土的表生地球化学特征、红土成分的变异系数、红土的淋溶系数、红土的风化率和风化强度、红土湿度和温度等均受母岩、气候纬度效应制约。相关分析表明,华南红土中的水含量和土温与Fe2O3含量呈正相关关系。初步研究表明,华南红土的表生地球化学特征是长期和多种环境变化的真实记录。     

西北太平洋低纬度区域海水中溶解氨基酸的分布及组成研究

本文对2018年秋季西北太平洋低纬度区域上层海洋(5~200 m)中溶解氨基酸(THAA)的分布和组成进行了研究。结果表明,该海域表层海水中THAA的浓度范围为0.40~0.97μmol/L,平均浓度为0.58±0.14μmol/L;5~200m垂直断面上THAA的平均浓度为0.59±0.16μmol/L,范围为0.30~1.05μmol/L。调查海域内THAA浓度明显低于中国近海,在5~200m内的垂直分布基本表现出随深度增加而增加的趋势。将表层和垂直水体中的THAA分别与DOC、Chla等环境因子进行相关性分析,结果显示均无显著相关性。西北太平洋低纬度区域海水中的优势氨基酸是天冬氨酸(Asp)、谷氨酸(Glu)、丝氨酸(Ser)、甘氨酸(Gly)、苏氨酸(Thr)和丙氨酸(Ala)。基于氨基酸的碳归一化产率(THAA-C%)、降解因子(DI)值,表明该海域表层海水中的有机质降解程度较高,且随深度的增加而降低。     

国土空间规划的海洋分区研究

国土空间分区作为国土空间规划编制和自然资源统一管理的基础,对整个规划体系具有重要的支撑作用。在统一的国土空间规划体系下,用海分区既有其独立性与特殊性,也面临着陆海统筹、生态文明建设、海洋高质量发展等政策提出的 新要求。文章系统梳理了 1983 年以来海洋功能分区体系 4 次演变历程,结合国土空间规划改革对分区体系的内在需求,指出海洋功能分区体系存在未覆盖海域全域,分区层级的尺度、分工、内容和结构与国土空间规划的要求不一致,分区方案未考虑用途管制的需求,以及陆海统筹不足等问题。在剖析现有各类规划政策分区、管制分区和功能分区在国土空间规划体系中的定位和作用的基础上,提出以海洋主体功能区为基础,海洋生态红线为底线,以原海洋功能区划分区为主体,将无居民海岛纳入规划范围,并在生态、农业、城镇空间的大框架下统筹协调海陆分区,形成国土空间规划中的海洋分区体系。全国和省级国土空间规划统筹海陆主体功能,划定主体功能区,并建立海洋产业保障区名录、无居民海岛保护与利用名录和海洋自然保护地名录。市县级国土空间规划划定“功能+管制”的利用分区,共划分出海洋保护区、海洋发展区和海洋保留3个一级分区以及核心保护区、一般控制区、海水增养殖区等 12 个二级分区。     

Trace metal composition of colloidal organic material in marine environments

Marine colloidal material (1 kDa–0.2 μm) was isolated by cross-flow ultrafiltration followed by diafiltration and freeze-drying from surface waters of the Gulf of Mexico and the Middle Atlantic Bight (MAB), as well as from estuarine waters of Galveston Bay. Elemental characterization of isolated colloidal material included organic carbon (OC) and selected trace metal (Cu, Pb, Zn, Cd, Co, Ni, Cr, Be, Fe, Al, Mn, V, Ba, and Ti) determinations. It was found that levels of these metals in marine colloids ranged from <0.1 to 50 μg/g colloidal matter, except for Fe which generally had a concentration >120 μg/g. Most metals (Cu, Pb, Zn, Ni, Al, Mn, V, and Ti) had an average concentration >1 μg/g while concentrations of Cd, Co and Be were usually <1 μg/g. Metal concentrations (μg/g) in isolated colloids were, in general, higher in Galveston Bay than in the Gulf of Mexico, suggesting either high abundance of trace metals in estuarine waters or differences in organic matter composition. Higher colloidal metal concentrations in the MAB than in the Gulf of Mexico might be due to higher terrestrial inputs in the MAB. Colloidal metal concentrations (μg/g) were generally lower than those in average soils, continental crust and suspended particles. However, metal/aluminum ratios (Me/Al) in isolated marine colloids were significantly higher than those for average soils and continental crust. Most importantly, colloids had a metal composition and metal/OC ratio (Me/C) similar to humic substances and marine plankton, suggesting that marine colloids largely originate from planktonic sources and are composed of predominately organic components. The Me/C ratios of Galveston Bay colloids followed the sequence of Cu>Ni, Cr, Zn>Mn>Co>Pb, Cd, which is similar to the Irving–Williams order except for Mn, suggesting that the interaction of metals with marine colloids is determined by the affinity of metals for specific organic ligands.