动力学模型预测深海鲣鱼(Katsuwonus pelamis)调理食品常温下的货架期

为了预测鲣鱼(Katsuwonus pelamis)调理食品的货架期,将鲣鱼调理食品贮藏在25°C、30°C、35°C温度条件下,通过测定在贮藏期间菌落总数、挥发性盐基氮、过氧化值三个指标的变化,分别对这三个指标与贮藏时间、温度建立一级动力学模型,来预测鲣鱼调理食品的货架期。经计算得出,菌落总数预测模型中的活化能(Ea)及指前因子(k0)分别为30.96 k J/mol和2.06×103,挥发性盐基氮预测模型中的的活化能及指前因子分别为24.35 k J/mol和75.1,过氧化值预测模型中的活化能及指前因子分别为48.75 k J/mol和2.92×106。在32°C和37°C条件下验证动力学模型,结果表明相对误差分别为–5.52%和–6.45%,准确性较好。进一步推算得出,在18°C和23°C常温下贮藏鲣鱼调理食品,产品的货架期为209d和172d。     

中国近海以及邻近海域海洋再分析产品(CORA)中季节内变化的评估

A regional reanalysis product—China Ocean Reanalysis(CORA)—has been developed for the China's seas and the adjacent areas. In this study, the intraseasonal variabilities(ISVs) in CORA are assessed by comparing with observations and two other reanalysis products(ECCO2 and SODA). CORA shows a better performance in capturing the intraseasonal sea surface temperatures(SSTs) and the intraseasonal sea surface heights(SSHs) than ECCO2 and SODA do, probably due to its high resolution, stronger response to the intraseasonal forcing in the atmosphere(especially the Madden-Julian Oscillation), and more available regional data for assimilation. But at the subsurface, the ISVs in CORA are likely to be weaker than reality, which is probably attributed to rare observational data for assimilation and weak diapycnal eddy diffusivity in the CORA model. According to the comparison results, CORA is a good choice for the study related to variabilities at the surface, but cares have to be taken for the study focusing on the subsurface processes.     

Isotope Geochronologic and Geochemical Constraints on the Magmatic Associations of the Collisional Orogenic Zone in the West Kunlun Orogen,China

The Jiajiwaxi pluton in the southern portion of the West Kunlun Range can be divided into two collision–related intrusive rock series, i.e., a gabbro–quartz diorite–granodiorite series that formed at 224±2.0 Ma and a monzonitic granite–syenogranite series that formed at 222±2.0 Ma. The systematic analysis of zircon U-Pb geochronology and bulk geochemistry is used to discuss the magmatic origin(material source and thermal source), tectonic setting, genesis and geotectonic implications of these rocks. The results of this analysis indicate that the parent magma of the first series, representing a transition from I-type to S-type granites, formed from thermally triggered partial melting of deep crustal components in an early island–arc–type igneous complex, similar to an I-type granite, during the continental collision orogenic stage. The parent magma of the second series, corresponding to an S-type granite, formed from the partial melting of forearc accretionary wedge sediments in a subduction zone in the late Palaeozoic–Triassic. During continued collision, the second series magma was emplaced into the first series pluton along a central fault zone in the original island arc region, forming an immiscible puncture-type complex. The deep tectonothermal events associated with the continent–continent collision during the orogenic cycle are constrained by the compositions and origins of the two series. The new information provided by this paper will aid in future research into the dynamic mechanisms affecting magmatic evolution in the West Kunlun orogenic belt.     

Comparative Study of Hydrogen and Carbon Isotopic Composition of Gases Generated from the Pyrolysis of a Peat under Saltwater and Freshwater Conditions

To understand the influence of the diagenetic water medium on the isotopic compositions of thermogenic coalbed gas, both hydrous and anhydrous closed-system pyrolyses were performed at temperatures of 250°C to 650°C on an herbaceous marsh peat. Compared to the results of anhydrous pyrolysis, the hydrocarbon gases generated from hydrous pyrolyses have very different hydrogen isotopic compositions. However, the carbon isotopic compositions of the hydrocarbon gases became only slightly heavier in hydrous pyrolysis, compared to that from anhydrous pyrolysis. With the progress of thermal evolution from peat to a more advanced thermal maturity of vitrinite reflectance values (Ro) of 5.5% during the pyrolysis, the difference in the average δD value increased from 52‰ to 64‰ between the hydrous pyrolysis with saltwater and anhydrous pyrolysis and increased from 18‰ to 29‰ between the hydrous pyrolysis with freshwater and anhydrous pyrolysis, respectively. The difference in the average δ13C value was only 1‰–2‰ between the hydrous and anhydrous pyrolysis. The relationships between the δD values of the generated hydrocarbon gases and Ro values as well as among δD values of the hydrocarbon gas species are established. The close relationships among these parameters suggest that the water medium had a significant effect on the hydrogen isotopic composition and a minimal effect on the carbon isotopic composition of the hydrocarbon gases. The results of these pyrolyses may provide information for the understanding of the genesis of coalbed gas from herbaceous marsh material with the participation of different diagenetic water media.     

Geodynamic setting,structure, and composition of continuous trachybasalt-trachyandesite-rhyolite series in the north of Altai-Sayan area: the role of crust-mantle interaction in continental magma formation

The geologic positions and geochemical and isotope parameters of the Ordovician-early Silurian and Early-Middle Devonian continuous volcanic series of the Minusa basin and its mountainous framing are compared. Both series are composed mostly of moderately alkaline rocks with variations in SiO₂ contents from 45 to 77 wt.%. The Ordovician-early Silurian series differs from the Early-Middle Devonian one in lower contents of TiO₂ (< 1.7 wt.%) and Fe₂O_3tot and higher contents of Al₂O₃ in all rock varieties and in the more fractionated REE patterns of trachybasalts. The compositions of both series reflect two simultaneous mechanisms of magma evolution. The main process was fractional crystallization leading to the formation of rocks from trachybasalts to trachyrhyodacites. The accessory mechanism was the contamination of fractionated melts by crustal material, anatectic melting of crust, and mixing of deep-seated magmas with crustal melts. These processes had specifics at each stage and were controlled by the composition of the sources of parental melts. Their geochemical and isotopic parameters (high alkalinity, high contents of lithophile elements, negative anomalies of Nb, Ta, and Ti, and enrichment in radiogenic Sr) point to the interaction of mantle plumes with the lithospheric mantle that was metasomatically transformed during the preceding Vendian-early Cambrian subduction processes.     

福建凤山矿区石墨矿地质特征及控矿因素分析

通过对福建省漳平市凤山矿区石墨矿近年来硐探、钻探等地质资料系统的梳理,在分析矿区地质特征和矿体特征的基础上,深入研究了石墨矿的控矿因素。研究认为该区石墨矿是由赋存于中二叠统童子岩组的无烟煤经过高温、高压作用进一步变质而成的。煤层受到岩浆热变质作用使碳物质(煤)分解,重新富集形成以隐晶质(土状)为主的隐晶质石墨矿,因此本区石墨矿的控矿因素是温度和构造。由于过往对福建煤系石墨资源的研究程度不够深入,造成大部分煤系石墨矿划归煤矿,致使石墨矿资源被浪费,本次通过野外地质勘查、采样样品测试等工作,确定了凤山矿区为煤系石墨矿,为下一步勘探工作提供有力依据,为合理开发利用矿产资源指明新的方向。     

云南白马寨铜镍硫化物矿床铂族元素地球化学及其对矿床成因的制约

采用镍硫火试金ICP-MS法分析了白马寨铜镍硫化物矿床矿石及其主要围岩铂族元素(PGE)含量,结果表明铂族元素总量(ΣPGE)普遍较低,且ΣPGE由矿床核部的块状矿石(78.15×10-9~555.92×10-9)向外围矿化橄榄岩(6.77×10-9~70.95×10-9)至辉长岩(3.02×10-9)逐步降低。煌斑岩脉岩的ΣPGE也较低,为6.86×10-9~17.03×10-9。ΣPGE与Ni含量呈明显的正相关。不同种类岩石和矿石的PGE原始地幔配分模式明显不同,块状矿石为Pt-Pd配分型,Ir较明显亏损;矿化橄榄岩配分曲线较平坦,IPGE和PPGE分异不明显,但均出现Ru正异常。辉长岩样品和煌斑岩PGE配分模式几乎一致,也均出现明显的Ru正异常。矿石和围岩的Cu/Pd值远高于原始地幔,表明原生岩浆发生了较强的硫化物熔离作用。块状富镍矿石的(Pt+Pd)/(Os+Ir+Ru)和Pd/Ir分别为138.24和24.7,指示其母岩浆为演化较为彻底的玄武质岩浆,而矿化橄榄岩的相应值分别为3.02和16.09,具有科马提质岩浆的特征参数,因此白马寨块状矿石和矿化橄榄岩之间可能没有成因联系。块状硫化物熔体侵位前,其母岩浆经历过长时间强烈的硫化物熔离作用,硫化物熔浆作为独立的侵入相而侵入于III号岩体核部。这个过程反映了峨眉山地幔柱尾部岩浆演化和成矿可能经历过高度的S饱和过程。白马寨矿床形成过程中可能受到地壳物质的混染。     

海洋生产总值核算方法研究

在分析借鉴国内外海洋经济核算相关方法的基础上,研究探索了我国海洋经济核算的模式,以海洋生产总值核算为突破口,系统提出了我国海洋生产总值(GOP)核算的三种基本方法,即剥离法、扩展法、外推法。同时,对几种核算方法进行了综合分析和评估。为我国开展海洋经济核算工作打下了良好的基础。     

中国城市价值链功能分工及其影响因素

价值链的空间重组正在深刻的改变着城市体系的经济景观,建立在价值链分工基础上的城市功能结构的研究已经成为经济地理学的重要课题。将中国上市公司500强企业网络划分为公司总部、商务服务、研究开发、传统制造、现代制造、物流仓储和批发零售七种类型功能区块,研究了中国城市价值链功能分工及其影响因素。结果发现：沿着价值链的功能分工已经成为中国城市体系经济景观的显著特征,功能多样化城市和功能专业化城市并存于中国城市体系,东部地区和城市密集地区的城市在价值链分工中占据了更好的地位;中国城市按照价值链中的优势功能可以划分为九种类型,少数城市转变为承载公司总部、研究开发、商务服务等多样化功能的高等级中心城市,而大量中小城市则转变为传统制造专业化基地;市场潜力、关键资源、区位条件、营商环境等城市属性特征是城市功能分工的重要影响因素,城市资源、区位可达性等属性特征的增强将提高城市成为总部基地、商务中心和研究基地的概率,而降低城市成为传统制造基地的概率。     

基于ROMS和4DVAR的沿轨与网格化SSH数据同化效果评价

Remote sensing products are significant in the data assimilation of an ocean model. Considering the resolution and space coverage of different remote sensing data, two types of sea surface height(SSH) product are employed in the assimilation, including the gridded products from AVISO and the original along-track observations used in the generation. To explore their impact on the assimilation results, an experiment focus on the South China Sea(SCS) is conducted based on the Regional Ocean Modeling System(ROMS) and the four-dimensional variational data assimilation(4 DVAR) technology. The comparison with EN4 data set and Argo profile indicates that, the along-track SSH assimilation result presents to be more accurate than the gridded SSH assimilation, because some noises may have been introduced in the merging process. Moreover, the mesoscale eddy detection capability of the assimilation results is analyzed by a vector geometry–based algorithm. It is verified that, the assimilation of the gridded SSH shows superiority in describing the eddy's characteristics, since the complete structure of the ocean surface has been reconstructed by the original data merging.