Low-pressure evolution of arc magmas in thickened crust: The San Pedro–Linzor volcanic chain,Central Andes,Northern Chile

Magmatism at Andean Central Volcanic Zone (CVZ), or Central Andes, is strongly influenced by differentiation and assimilation at high pressures that occurred at lower levels of the thick continental crust. This is typically shown by high light to heavy rare earth element ratios (LREE/HREE) of the erupted lavas at this volcanic zone. Increase of these ratios with time is interpreted as a change to magma evolution in the presence of garnet during evolution of Central Andes. Such geochemical signals could be introduced into the magmas be high-pressure fractionation with garnet on the liquidus and/or assimilation from crustal rocks with a garnet-bearing residue. However, lavas erupted at San Pedro–Linzor volcanic chain show no evidence of garnet fractionation in their trace element patterns. This volcanic chain is located in the active volcanic arc, between 22°00^′S and 22°30^′S, over a continental crust ∼70 km thick. Sampled lavas show Sr/Y and Sm/Yb ratios <40 and <4.0, respectively, which is significantly lower than for most other lavas of recent volcanoes in the Central Andes. In addition, ⁸⁷Sr/⁸⁶Sr ratios from San Pedro–Linzor lava flows vary between 0.7063 and 0.7094. This is at the upper range, and even higher than those observed at other recent Central Andean volcanic rocks (<0.708). The area in which the San Pedro–Linzor volcanic chain is located is constituted by a felsic, Proterozoic upper crust, and a thin mafic lower crustal section (<25 km). Also, the NW–SE orientation of the volcanic chain is distinctive with respect to the N–S orientation of Central Andean volcanic front in northern Chile. We relate our geochemical observations to shallow crustal evolution of primitive magmas involving a high degree of assimilation of upper continental crust. We emphasize that low pressure AFC- (Assimilation Fractional Crystallization) type evolution of the San Pedro–Linzor volcanic chain reflects storage, fractionation, and contamination of mantle-derived magmas at the upper felsic crust (<40 km depth). The ascent of mantle-derived magmas to mid-crustal levels is related with the extensional regime that has existed in this zone of arc-front offset since Late-Miocene age, and the relatively thin portion of mafic lower crust observed below the volcanic chain.     

太行山东麓构造岩浆带在豫北安林地区的活动特点及控矿特征

安林地区的构造活动,对剖析太行山东麓构造岩浆带成生、演化具有一定的代表性。本区自燕山运动开始就受到了变质核杂岩和伸展拆离构造控制,区内主要构造有NNE向和NW向两组,其中NNE向构造在区内等间距形成了五条规模大的深断裂,均具高角度正断层性质。NW向构造形成了天喜镇-磊口北西向构造岩浆岩带,包括了塔山穹窿式背斜和白玉村-宝山墙状岩体,两组构造均对燕山晚期中-碱性岩浆上侵和安林式矽卡岩型铁矿的形成具重要控制作用。     

IGS精密星历和钟差对天顶对流层延迟精度的影响

为研究IGS精密轨道和钟差产品对天顶对流层延迟精度的影响,文章利用位于中国北京、上海、拉萨等地的6个IGS跟踪站所提供的2013年4月7日～10日4天的数据,采用GPSTools软件进行实验,计算各跟踪站的天顶对流层延迟(ZTD),并与IGS提供的对流层延迟产品进行对比.结果表明,利用IGS精密轨道解算的ZTD与IGS提供的ZTD相当,两者偏差的平均RMS优于5mm,利用IGS超快速钟差预报部分解算的ZTD与IGS提供的ZTD存在2cm～3cm误差,平均RMS大于1cm.     

测量监测技术在高层钢结构施工中的应用实践

本文结合大连期货大厦高层钢结构施工放样工程论述了高层钢结构主体施工控制和监测的工艺方法,具体介绍了首层控制网建立,内控点投测、轴线控制,标高控制、标高传递的步骤,以及钢柱扭转、错位、垂直度纠正的方法,对其它高层钢结构施工有参考价值。     

浙江中生代陆缘火山岩金矿成矿系统

浙江地处中国东南沿海大陆边缘火山岩成矿带，已发现众多金（银）矿床（点），它们在空间上往往不是孤立地出现，而是在数十至数百平方公里内围绕岩浆热中心相对集中，并与有色金属在矿田范围内伴生。研究证明，金（银）及有色金属矿床是同一火山—侵入旋回过程中形成的有成因联系的矿床。笔者将这种在同一火山—侵入旋回间，围绕同一个岩浆热中心，在不同深度和水平距离内形成的一系列具有成因联系的金（银）和有色金属矿床的总和称为火山岩金矿成矿系统。本文在此概念基础上，详细论述了浙江中生代陆线火山岩金矿成矿系统的类型。时空结构和物质来源。     

数字地图生产流程中质量的数据控制

本文将着重讨论在ISO9001质量控制体系下、数字地图生产流程中影响地图质量的各类数据文件的设定与控制,从而进一步探讨在电子出版系统及CTP系统中,数字地图生产规范化、标准化、程序化作业的质量控制内容及方法。     

我国水产品国际竞争力的提升策略

当前我国水产品出口屡屡受挫．如何提升我国水产品的国际竞争力是我们面临的一个重要课题。通过分析认为。制约我国水产品国际竞争力的外部因素：发达国家技术壁垒的强化；反倾销、反补贴和特殊保障措施使我国在保护水产品生产和贸易上处于严重的不利地位；生态标签成为新的非关税壁垒，威胁着国际贸易的发展。内部因素：政府管理体制方面的制约；水产品生产加工方面的制约；行业组织化程度低，恶性竞争没有得到有效遏制；生产服务和信息服务能力弱；水产品市场体系的制约因索。在此基础上，提出了增加政府补贴、加强养殖监管、健全合作组织、实施品牌战略等一系列提升我国水产品国际竞争力的策略。     

Liquidus Equilibria in the System K2O-Na2O-Al2O3-SiO2-F2O-1-H2O to 100 MPa: II. Differentiation Paths of Fluorosilicic Magmas in Hydrous Systems

We investigated phase equilibria in the six-component systemNa₂O–K₂O–Al₂O₃–SiO₂–F₂O_–1–H₂Oat 100 MPa to characterize differentiation paths of naturalfluorine-bearing granitic and rhyolitic magmas. Topaz and cryoliteare stable saturating solid phases in calcium-poor systems.At 100 MPa the maximum solidus depression and fluorine solubilityin evolving silicic melts are controlled by the eutectics haplogranite–cryolite–H₂Oat 640°C and 4 wt % F, and haplogranite–topaz–H₂Oat 640°C and 2 wt % F. Topaz and cryolite form a binaryperalkaline eutectic at 660°C, 100 MPa and fluid saturation.The low-temperature nature of this invariant point causes displacementof multiphase eutectics with quartz and alkali feldspar towardsthe topaz–cryolite join and enables the silicate liquidusand cotectic surfaces to extend to very high fluorine concentrations(more than 30 wt % F) for weakly peraluminous and subaluminouscompositions. The differentiation of fluorine-bearing magmasfollows two distinct paths of fluorine behavior, depending onwhether additional minerals buffer the alkali/alumina ratioin the melt. In systems with micas or aluminosilicates thatbuffer the activity of alumina, magmatic crystallization willreach either topaz or cryolite saturation and the system solidifiesat low fluorine concentration. In leucogranitic suites precipitatingquartz and feldspar only, the liquid line of descent will reachtopaz or cryolite but fluorine will continue to increase untilthe quaternary eutectic with two fluorine-bearing solid phasesis reached at 540°C, 100 MPa and aqueous-fluid saturation.The maximum water solubility in the haplogranitic melts increaseswith the fluorine content and reaches 12· 5 ±0· 5 wt % H₂O at the quartz–cryolite–topazeutectic composition. A continuous transition between hydrousfluorosilicate melts and solute-rich aqueous fluids is not documentedby this study. Our experimental results are applicable to leucocraticfluorosilicic magmas. In multicomponent systems, however, thepresence of calcium may severely limit enrichment of fluorineby crystallization of fluorite. KEY WORDS: granite; rhyolite; topaz; cryolite; magmatic differentiation     

The Upper Crustal Evolution of a Large Silicic Magma Body: Evidence from Crystal-scale Rb Sr Isotopic Heterogeneities in the Fish Canyon Magmatic System, Colorado

Batholith-sized bodies of crystal-rich magmatic ‘mush’are widely inferred to represent the hidden sources of manylarge-volume high-silica rhyolite eruptive units. Occasionallythese mush bodies are ejected along with their trapped interstitialliquid, forming the distinctive crystal-rich ignimbrites knownas ‘monotonous intermediates’. These ignimbritesare notable for their combination of high crystal contents (35–55%),dacitic bulk compositions with interstitial high-silica rhyoliticglass, and general lack of compositional zonation. The 5000km³ Fish Canyon Tuff is an archetypal eruption deposit of thistype, and is the largest known silicic eruption on Earth. Ejectafrom the Fish Canyon magmatic system are notable for the limitedcompositional variation that they define on the basis of whole-rockchemistry, whereas 45 vol. % crystals in a matrix of high-silicarhyolite glass together span a large range of mineral-scaleisotopic variability (microns to millimetres). Rb/Sr isotopicanalyses of single crystals (sanidine, plagioclase, biotite,hornblende, apatite, titanite) and sampling by micromillingof selected zones within glass plus sanidine and plagioclasecrystals document widespread isotopic disequilibrium at manyscales. High and variable ⁸⁷Sr/⁸⁶Sr_i values for euhedral biotitegrains cannot be explained by any model involving closed-systemradiogenic ingrowth, and they are difficult to rationalize unlessmuch of this radiogenic Sr has been introduced at a late stagevia assimilation of local Proterozoic crust. Hornblende is theonly phase that approaches isotopic equilibrium with the surroundingmelt, but the melt (glass) was isotopically heterogeneous atthe millimetre scale, and was therefore apparently contaminatedwith radiogenic Sr shortly prior to eruption. The other mineralphases (plagioclase, sanidine, titanite, and apatite) have significantlylower ⁸⁷Sr/⁸⁶Sr_i values than whole-rock values (as much as –0·0005).Such isotopic disequilibrium implies that feldspars, titaniteand apatite are antecrysts that crystallized from less radiogenicmelt compositions at earlier stages of magma evolution, whereashighly radiogenic biotite xenocrysts and the development ofisotopic heterogeneity in matrix melt glass appear to coincidewith the final stage of the evolution of the Fish Canyon magmabody in the upper crust. Integrated petrographic and geochemicalevidence is consistent with pre-eruptive thermal rejuvenationof a near-solidus mineral assemblage from 720 to 760°C (i.e.partial dissolution of feldspars + quartz while hornblende +titanite + biotite were crystallizing). Assimilation and blendingof phenocrysts, antecrysts and xenocrysts reflects chamber-wide,low Reynolds number convection that occurred within the last10 000 years before eruption. KEY WORDS: Fish Canyon Tuff; Rb–Sr isotopes; microsampling; magmatic processes; crystal mush     

江西德兴斑岩铜矿石英闪长玢岩成因及成矿学意义

为探究石英闪长玢岩成因及幔源基性岩浆对斑岩铜矿的贡献,本文选取德兴矿床石英闪长玢岩开展了锆石U-Pb定年、Hf同位素和全岩地球化学研究。获得石英闪长玢岩LA-ICP-MS锆石U-Pb年龄为169 Ma,与成矿花岗闪长斑岩侵位时间一致,岩体为中侏罗世岩浆活动的产物。石英闪长玢岩具有低的SiO₂(58.41%~63.12%)和K₂O(1.68%~2.94%)含量及A/CNK值(0.85~1.04),富集大离子亲石元素和轻稀土元素,亏损高场强元素Nb、Ta、Ti和重稀土元素,属于钙碱性到高钾钙碱性系列岩石。具有相对亏损的锆石Hf同位素组成,εHf(t)=2.20~7.93(最大值7.93),指示其源区为岩石圈地幔。锆石稀土元素配分模式图显示出明显的正Ce异常,岩浆氧逸度(lg f_O2)为-20.05~-6.66,达到磁铁矿-赤铁矿氧逸度等级,指示石英闪长玢岩结晶自高氧逸度岩浆。全岩地球化学特征显示,德兴石英闪长玢岩与成矿花岗闪长斑岩及其暗色包体符合岩浆混合的演化趋势,说明成矿花岗闪长斑岩可能是中侏罗世幔源基性岩浆和地壳酸性岩浆大规模混合作用的产物,并且石英闪长玢岩代表了岩浆混合过程中的幔源基性端员。结合前人研究成果,认为在中侏罗世伸展构造背景下,软流圈物质上涌导致新元古代受交代的岩石圈地幔部分熔融形成幔源基性岩浆,基性岩浆的底侵作用诱发下地壳物质熔融并与之发生一定程度的岩浆混合作用,形成了花岗闪长斑岩的母岩浆。高氧逸度幔源岩浆的加入可抑制斑岩体系硫化物的过早饱和,同时为德兴矿床注入了成矿所需的部分挥发分和金属元素。