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51.
华南热水成因硅质岩建造的稀土元素地球化学特征 总被引:11,自引:2,他引:11
本文在华南地区若干个重要层位热水成因硅质岩建造的稀土元素地球化学数据的基础上,讨论了热水成因硅质岩的REE特征及其与形成环境的关系。指出典型热水沉积建造的δCe为负异常,而δEu为正异常,且LREE>HREE;这种热水成因的硅质岩REE总量普遍较低,且有从热水喷口向外REE总量增高的趋势。热水成因硅质泥岩与正常沉积成因硅质泥的混合存在使稀土元素分布状况变得更复杂。 相似文献
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The ultramafic-hosted Logatchev Hydrothermal Field (LHF) at 15°N on the Mid-Atlantic Ridge and the Arctic Gakkel Ridge (GR) feature carbonate precipitates (aragonite, calcite, and dolomite) in voids and fractures within different types of host rocks. We present chemical and Sr isotopic compositions of these different carbonates to examine the conditions that led to their formation. Our data reveal that different processes have led to the precipitation of carbonates in the various settings. Seawater-like 87Sr/86Sr ratios for aragonite in serpentinites (0.70909 to 0.70917) from the LHF are similar to those of aragonite from the GR (0.70912 to 0.70917) and indicate aragonite precipitation from seawater at ambient conditions at both sites. Aragonite veins in sulfide breccias from LHF also have seawater-like Sr isotope compositions (0.70909 to 0.70915), however, their rare earth element (REE) patterns show a clear positive europium (Eu) anomaly indicative of a small (< 1%) hydrothermal contribution. In contrast to aragonite, dolomite from the LHF has precipitated at much higher temperatures (~ 100 °C), and yet its 87Sr/86Sr ratios (0.70896 to 0.70907) are only slightly lower than those of aragonite. Even higher temperatures are calculated for the precipitation of deformed calcite veins in serpentine–talc fault schists form north of the LHF. These calcites show unradiogenic 87Sr/86Sr ratios (0.70460 to 0.70499) indicative of precipitation from evolved hydrothermal fluids. A simple mixing model based on Sr mass balance and enthalpy conservation indicates strongly variable conditions of fluid mixing and heat transfers involved in carbonate formation. Dolomite precipitated from a mixture of 97% seawater and 3% hydrothermal fluid that should have had a temperature of approximately 14 °C assuming that no heat was transferred. The much higher apparent precipitation temperatures based on oxygen isotopes (~ 100 °C) may be indicative of conductive heating, probably of seawater prior to mixing. The hydrothermal calcite in the fault schist has precipitated from a mixture of 67% hydrothermal fluid and 33% seawater, which should have had an isenthalpic mixing temperature of ~ 250 °C. The significantly lower temperatures calculated from oxygen isotopes are likely due to conductive cooling of hydrothermal fluid discharging along faults. Rare earth element patterns corroborate the results of the mixing model, since the hydrothermal calcite, which formed from waters with the greatest hydrothermal contribution, has REE patterns that closely resemble those of vent fluids from the LHF. Our results demonstrate, for the first time, that (1) precipitation from pure seawater, (2) conductive heating of seawater, and (3) conductive cooling of hydrothermal fluids in the sub-seafloor all can lead to carbonate precipitation within a single ultramafic-hosted hydrothermal system. 相似文献
55.
湘中锡矿山式锑矿形成于晚白垩-古新世,空间上与岩脉关系密切,各锑矿床、矿化点都伴有或附近发育有煌斑岩及中-酸性岩脉群,在锑矿成矿同期地质事件中,还有周缘一些中-新生代红色盆地的形成及基性火山岩喷发,据之,提出湘中锡矿山式锑矿成矿与燕山晚期拉张构造-岩浆活化作用有关.锑矿床(点)基本上都产出于两组或两组以上断裂的交汇点附近,3组断裂的交汇部位对应于最主要的锑矿床(点).矿体具体受断裂交汇部位附近的次级短轴背斜轴部、倾伏背斜的倾伏端及其翼部被纵向陡倾角断裂构造所切穿的部位控制,是断裂导矿与背斜构造圈闭的体现.岩性组合控矿表现为易于硅化蚀变交代的砂质碳酸盐岩与隔挡层泥质岩所构成的岩性圈闭.根据包裹体均-温度和盐度测定成果,推算成矿压力为(200~300)×105Pa,成矿深度约为1 km. 相似文献
56.
Abstract. Several epithermal gold deposits occur in the Hoshino area, which is located in the western end of the late Cenozoic Hohi volcanic zone, north‐central Kyushu, Japan. The area is characterized by intermediate to felsic extrusive rocks of Pliocene age. In the Hoshino area, the shallow manifestation of the hydrothermal activity is exposed on the surface. Several outcrops of sinter are still preserved on the top of hydro thermally altered volcanic rocks, and high‐grade gold‐bearing quartz veins occur on the surface at lower levels. The hydrothermal alteration resulted into well‐developed alteration zones. The zonal alteration pattern, primarily of near‐neutral pH type, is characterized by the outer smectite zone of a lower temperature, and the inner mixed layer minerals zone of a higher temperature. Quartz vein‐related or fracture‐controlled alteration, is represented by the occurrence of interstratified illite/smectite and K‐feldspar, suggesting a potassium‐enriched alteration. The mineralization in the Hoshino area is recognized on the surface by the occurrence of gold‐bearing quartz veins distributed mainly in the mixed layer minerals zone. The fracture system related to the gold mineralization is mainly characterized by NW‐SE trend. The alteration pattern and the mineralogical composition of the veins suggest that the mineralizing fluids had near‐neutral pH and the mineralization is of low‐sulfidation‐type. Fluid inclusion data and textures observed in quartz veins indicate that gold precipitated during boiling. The chemical composition of quartz veins shows that high‐grade gold‐bearing quartz veins are characterized by higher content of Al2O3, K2O and Rb. Several outcrops of silica‐sinters are distributed on the top of the mixed layer minerals zone. Although their structures are not very well preserved, because of later silicification, the Hoshino sinters still show characteristic textures identical to those observed in modern sinters, such as the presence of plant fossil incorporated into the sinters, the strongly developed depositional laminations and the columnar structures perpendicular to the depositional surfaces. Quartz is the only silica mineral constituting the Hoshino sinters presently. The conversion of amorphous silica into quartz was probably governed by higher temperatures resulting from later hydrothermal activity. This later hydrothermal activity is reflected by the intense silicification affecting mainly the lower parts of the sinters and also by the presence of quartz veins cutting the sinters. The distribution of sinters in the Hoshino area is very significant. The presence beneath the sinters of concealed high‐grade gold‐bearing quartz veins should be highly considered and exploration work is strongly suggested. 相似文献
57.
四川杨柳坪热液型富铂族元素矿石的发现及其意义 总被引:6,自引:2,他引:6
四川杨柳坪是中国最主要的铂族元素矿床之一,但以往控制的97%以上的储量赋存在蚀变超基性岩体中,品位普遍不高,笔者等1999年通过对杨柳坪主矿体外围热液型矿体的调查,认为其中的热液型矿石可能富含铂族元素,经过初步的分析测试,证实了这一推测,并发现热液成民岩浆作用在杨柳坪地区具有明显不同的表现形式,根据最近在鱼海子等地地调查的新发现,建议在扬子地台西缘进一步开展找热液型铂族元素矿床的工作。 相似文献
58.
Submarine hydrothermal mineralization in the Okinawa Trough, SW of Japan: an overview 总被引:3,自引:0,他引:3
The Okinawa Trough is a heavily sedimented, rifted back-arc basin formed in an intracontinental rift zone. Submarine hydrothermal activity is located within the six back-arc rifts located in the middle and southern Okinawa Trough and its distribution is controlled principally by tectonic factors. Subduction of the Daito and Gagua Ridges beneath the Ryukyu Arc has resulted in fracturing of the brittle lithosphere beneath the Okinawa Trough. Hydrothermal activity is strongest in the volcanic arc-rift migration phenomenon (VAMP) area plus the JADE site and Southernmost Part of the Okinawa Trough (SPOT) area which form the prolongation of these two ridges. These areas are characterized by extremely high heat flow locally. Submarine hydrothermal fluids from the Okinawa Trough tend to be strongly influenced by interaction of the hydrothermal fluids with organic matter in the sediment resulting in high alkalinity and NH4+ concentrations of the fluids. The fluids also contain high concentrations of CO2 of magmatic origin. Submarine hydrothermal mineralization in the trough is diverse. The CLAM site consists principally of carbonate chimneys. Interaction of the hydrothermal fluid with organic matter in the sediment is particularly strong at this site. This is most probably a sediment-hosted deposit in which sulphide minerals have deposited within the sediment column leaving ‘spent ore-fluids’ to emerge at the seafloor. The JADE site consists of active and inactive sulphide–sulphate chimneys and mounds. The Zn–Pb-rich sulphides at this site contain the highest concentrations of Pb, Ag and Au so far recorded in submarine hydrothermal sulphide deposits. At Minami-Ensei Knoll and Hatoma Knoll, active and inactive chimneys consist principally of anhydrite and barite as a result of phase separation of the hydrothermal fluids beneath the seafloor. An intense black smoker has recently been discovered at Yonaguni Knoll in the SPOT area. If it is confirmed that sulphide mineralization is dominant at this site, this could be a highly prospective area. The most prospective areas for economic-grade minerals in the Okinawa Trough appear to be the JADE site and the SPOT area. 相似文献
59.
湖南黄沙坪铅锌矿NNW向构造的识别及其找矿意义 总被引:4,自引:0,他引:4
湖南黄沙坪铅锌矿床属岩浆期后热液型矿床,近年来由于危机矿山深部找矿项目取得重大找矿进展而引起各方关注。矿床经历了多期构造活动,包括NNE向、近NE向和NNW向,但以往一直将NNE向作为控岩控矿构造。系统的地质调查及岩体对比发现,NNE向断裂为成矿前逆冲构造,控制区内的褶皱与石英斑岩的侵入,并在成矿期继续活动。NNW向构造控制了矿区内花岗斑岩(301#、304#)的侵入以及矽卡岩及其相关的钨钼矿、铅锌矿的成矿。铅锌矿体受NNW与NNE向断裂的联合控制,常呈"S"型、或两组断裂交汇处的不规则脉状。矿化以NNW向花岗斑岩为中心形成分带,矽卡岩型钨钼矿化分布于花岗斑岩体边部,铅锌矿体分布于外侧。NNW向控矿构造的认识揭示出黄沙坪矿床301#花岗斑岩体及其东南部深部地区将是重要的找矿方向;同时,301#-304#岩体构成的NW构造线两侧,具有进一步寻找小型铅锌矿体的条件,这些矿体主要位于NNE与NNW向断裂的交汇部位。 相似文献
60.
广西大厂电气石的成分与成因初探 总被引:9,自引:2,他引:9
镁电气石不一定只产于喷气岩或喷气矿床,在花岗岩中也有产出。大厂花岗岩及其有关锡多金属矿床中的电气石属铁镁系列,产于岩体中者富Fe贫Mg,产于矿体中者贫Fe富Mg,并有随远离源区Mg含量增高的趋势,与国内外同类矿床电气石成分的演化规律相一致。锡石硫化物矿体中电气石富镁的原因是多方面的,其中Mg、Fe两元素亲硫性的明显差别可能是导致Fe富集于黄铁矿等硫化物中、而Mg富集于电气石等蚀变矿物内的重要原因 相似文献