云南白马寨铜镍硫化物矿床铂族元素地球化学及其对矿床成因的制约

采用镍硫火试金ICP-MS法分析了白马寨铜镍硫化物矿床矿石及其主要围岩铂族元素(PGE)含量,结果表明铂族元素总量(ΣPGE)普遍较低,且ΣPGE由矿床核部的块状矿石(78.15×10-9~555.92×10-9)向外围矿化橄榄岩(6.77×10-9~70.95×10-9)至辉长岩(3.02×10-9)逐步降低。煌斑岩脉岩的ΣPGE也较低,为6.86×10-9~17.03×10-9。ΣPGE与Ni含量呈明显的正相关。不同种类岩石和矿石的PGE原始地幔配分模式明显不同,块状矿石为Pt-Pd配分型,Ir较明显亏损;矿化橄榄岩配分曲线较平坦,IPGE和PPGE分异不明显,但均出现Ru正异常。辉长岩样品和煌斑岩PGE配分模式几乎一致,也均出现明显的Ru正异常。矿石和围岩的Cu/Pd值远高于原始地幔,表明原生岩浆发生了较强的硫化物熔离作用。块状富镍矿石的(Pt+Pd)/(Os+Ir+Ru)和Pd/Ir分别为138.24和24.7,指示其母岩浆为演化较为彻底的玄武质岩浆,而矿化橄榄岩的相应值分别为3.02和16.09,具有科马提质岩浆的特征参数,因此白马寨块状矿石和矿化橄榄岩之间可能没有成因联系。块状硫化物熔体侵位前,其母岩浆经历过长时间强烈的硫化物熔离作用,硫化物熔浆作为独立的侵入相而侵入于III号岩体核部。这个过程反映了峨眉山地幔柱尾部岩浆演化和成矿可能经历过高度的S饱和过程。白马寨矿床形成过程中可能受到地壳物质的混染。     

新疆准噶尔—东天山地区产于韧性剪切带中的金矿床成矿流体与碳、硫、铅同位素

韧性剪切带型金矿床是新疆准噶尔-东天山地区重要金矿类型。本文以科克萨依、康古尔、红石金矿为典型矿床,研究它们的流体包裹体均一温度、爆裂温度、包裹体成分、包裹体水的来源等,并进行了硫、铅同位素及近矿围岩碳同位素、矿体石英包裹体中CO2、CH4气体的碳同位素分析。结果表明,硫、铅为深源,暗示了本区金成矿物质的地幔来源。部分碳为有机碳,反映了本区年轻碳质沉积地层中有机碳参与了金的迁移与成矿作用。综合研究表明,在本区特定的后碰撞地质背景下,在构造挤压与伸展作用中形成的韧性剪切带中的金矿床金成矿物质源于深源,成矿流体主要是变质水。岩浆作用、变质作用、碳质围岩地层有机碳参与成矿,变质流体与岩浆热液及天水等流体的不同程度的混合与叠加,形成本区特征的韧性剪切带型金矿床。     

冲绳海槽中部岩心沉积物中浮岩的物理性质和地球化学特征差异及其对岩浆活动的指示

为进一步了解冲绳海槽浮岩的物理性质和地球化学特征差异,对冲绳海槽中部岩心沉积物S9中的浮岩进行了微观结构和地球化学组成分析。结果显示,冲绳海槽中部存在白色、灰白色及棕色3种浮岩,其中灰白色浮岩又可以根据构造特征分为气孔构造和流动构造浮岩两个亚类。浮岩的地球化学组成表明白色、灰白色及棕色浮岩都是由玄武质岩浆经过充分的分离结晶作用形成的流纹质或流纹英安质火山岩。玄武质岩浆在演化的过程中发生了斜长石、角闪石、辉石、Fe-Ti氧化物、磷灰石等矿物的结晶分离。结合有孔虫14C年龄,认为浮岩是冲绳海槽中部距今13.1 ka左右的长英质火山活动的产物。演化程度相对较低的棕色浮岩具有比白色浮岩高的TiO2, Al2O3, Fe2O3, MgO, CaO含量,且棕色浮岩具有相对低的稀土总量和轻稀土总量。根据浮岩的物理性质及地球化学组成差异推测,岩浆的黏度和压力是影响浮岩构造特征的主要因素。黏度大、连续减压的岩浆易于形成具有流动构造和密集气孔的浮岩,黏度小、阶段性减压的岩浆易于形成气孔大而疏松的浮岩。     

贵州从江及毗邻地区岩浆岩形成时代探讨

贵州从江及其毗邻地区的岩浆岩较发育,其岩类较多,有基性岩、超基性侵入岩、酸性侵入岩及基性火山岩。笔者通过收集最新的区域地质调查和同位素年龄测定结果等,对其形成时代进行了探讨,认为岩浆岩活动的高峰期为Ca.825Ma左右,即新元古代早期。     

扬子板块西缘攀西地区白草矿区黄铁矿标型元素特征及其指示意义

黄铁矿是重要的金属硫化物矿物,在多种矿床中均有产出,其标型特征对矿床成因、矿体空间分布等具有重要的指示意义.以扬子板块西缘攀西地区白草矿区黄铁矿为研究对象,利用矿相学、电子探针等分析方法来对比研究浸染状、致密块状、斑杂状、网脉状矿石中黄铁矿的标型元素特征.结果表明:白草矿区黄铁矿Fe、S平均含量(质量分数,下同)分别为...     

岩浆包裹体化学成分研究

岩浆包裹体化学成分研究难度较大,为了获得可信的数据,应当注意:1.非演化型岩浆包裹体的化学成分可以代表其初始成分。演化型岩浆包裹体应先均一、淬火后再行测定。2.均一演化型岩浆包裹体应严格遵守加热规则,否则过热作用会使包裹体壁部分熔化,造成淬火后所测包裹体成分与其真正的初始成分并不相当。3.实测资料证明,“边界层效应”对于岩浆包裹体化学成分影响微不足道。4.岩浆包裹体的化学成分只能代表其主矿物结晶时周围岩浆的成分,即仅相当于岩浆液相线上的一个点。5。把显微冷热台测温、激光喇曼探针和电子探针分析技术结合使用,对查明单个包裹体中挥发组分的性状和浓度具有很大的潜力和前途。     

河北汉诺坝玄武岩中深源包体和巨晶分布的动力学机理

汉诺坝碱性玄武岩是深源包体和巨晶的主要寄主岩,同时,也有不含包体的碱性玄武岩和含包体的拉斑玄武岩。本文基于理论计算,探讨了包体和巨晶分布的动力学机理。     

中国主要含镍岩体特征及其成因

中国目前已发现7条岩带中18个岩体赋存有工业铜镍矿床。这些含镍岩体的岩石组合有三大类,其中以超基性岩中矿床居多,苏长岩与科马提岩中较少。中国含镍岩浆系列属于科马提岩系列而非拉斑玄武岩系列,含矿岩浆来自上地幔的部分熔融,源区具有U、Th值高而Cr低的特点,深大断裂发育的大陆边缘是镍矿床发育最理想的场所。     

Tectonic evolution of lower crustal rocks in an exposed magmatic arc section in the Hidaka metamorphic belt, Hokkaido, northern Japan

Abstract : The Hidaka metamorphic belt consists of an island-arc assembly of lower to upper crustal rocks formed during early to middle Paleogene time and exhumed during middle Paleogene to Miocene time. The tectonic evolution of the belt is divided into four stages, D₀rs, D₁, D₂rs, and D₃, based on their characteristic deformation, metamorphism, and igneous activity. The premetamorphic and igneous stage (D₀) involves tectonic thickening of an uppermost Cretaceous and earliest Tertiary accretionary complex, including oceanic materials in the lower part of the complex. D₁ is the stage of prograde metamorphism with increasing temperatures at a constant pressure during an early phase, and with a slight decrease of pressure at the peak metamorphic phase, accompanying flattening of metamorphic rocks and intrusions of mafic to intermediate igneous rocks. At the peak, incipient partial melting of pelitic and psammitic gneisses took place in the amphibolite–granulite facies transition zone, the melt and residuals cutting the foliations formed by flattening. In the deep crust, large amounts of S-type tonalite magma formed by crustal anatexis, intruded into the granulite facies gneiss zone and also into the upper levels of the metamorphic sequence during the subsequent stage. During D₁ stage, mafic and intermediate magmas supplied and transported heat to form the arc-type crust and at the same time, the magmatic underplating caused extensional doming of the crust, giving rise to flattening and vertical uplifting of the crustal rocks. D₂ stage is characterized by subhorizontal top-to-the-south displacement and thrusting of lower to upper crustal rocks, forming a basal detachment surface (décollement) and duplex structures associated with intrusions of S-type tonalite. Deformation structures and textures of high-temperature mylonites formed along the décollement, as well as the duplex structures, show that the D₂ stage movement occurred under a N-S trending compressional tectonic regime. The depth of intra-crustal décollement in the Hidaka belt was defined by the effect of multiplication of two factors, the fraction of partial melt which increases downward, and the fluid flux which decreases downward. The crustal décollement, however, might have extended to the crust-mantle boundary and/or to the lithosphere and asthenosphere boundary. The subhorizontal movement was transitional to a dextral-reverse-slip (dextral transpression) movement accompanied by low-temperature mylonitization with retrograde metamorphism, the stage defined as D₃. The crustal rocks from the basal décollement to the upper were tilted eastward on the N–S axis and exhumed during the D₃ stage. During D₂ and D₃ stages, the intrusion of crustal acidic magmas enhanced the crustal deformation and exhumation in the compressional and subsequent transpressional tectonic regime.     

胶东金矿成矿系列硫同位素研究

胶东金矿的早晚两期成矿系列中，岩浆成因或在岩浆期即有天然水和表生矿质加入的矿床，δ＾３４Ｓ值均有自早而晚依次降低的规律。为重熔岩浆分异成矿理论和成矿系列的建立提供了重要证据。焦家式和某些晚期矿床，在形成矿液后有表生硫加入，扰乱了这一规律性。胶东群中的硫同位素没有达到均匀化，副变质岩偏重，而斜长角闪岩偏轻，接近陨石硫值，是近似原始岩浆的产物。