Potential for localized groundwater contamination in a porous pavement parking lot setting in Rhode Island

The control of polluted surface runoff and the assessment of possible impacts on groundwater is a concern at the local and regional scale. On this background, a study investigates possible impacts of organic and inorganic pollutants (including bacteria) originating from a permeable asphalt parking lot on the water quality immediately beneath it. The functioning of the permeable pavement, including clogging and restricted vertical percolation, was also evaluated. Four nested sample ports (shallow and deep) were installed below low- and high-traffic areas, including one port outside the parking lot. At least initially there was a good hydraulic connection between the parking surface and the shallow sample ports. The presence of a geotextile layer at the base of the parking lot structure, however, was identified in lab tests as one factor restricting vertical percolation to the deeper ports. Clogging of the permeable surface was most pronounced in heavy traffic areas and below snow pile storage areas. Corroborated by high electric conductivity and chloride measurements, sand brought in by cars during winter was the principal cause for clogging. No bacteria or BOD were found in percolating water. Polycyclic aromatic hydrocarbons (PAH) were present at concentrations near minimum detection limit. Nutrients (nitrate and phosphate) were being leached into the ground via the permeable parking lot surface at annual flux rates of 0.45–0.84 g/m²/year. A multi-species tracer test demonstrated a retention capacity of the permeable parking lot structure of >90% for metals and 27% for nutrients, respectively.     

Magma Ascent and Crustal Accretion at Ultraslow-Spreading Ridges: Constraints from Plagioclase Ultraphyric Basalts from the Arctic Mid-Ocean Ridge

Plagioclase ultraphyric basalts (PUBs) with up to 54% plagioclasephenocrysts were dredged in the rift valley and adjacent flanksof the ultraslow-spreading Mohns and Knipovich ridges. The PUBsshow large variations in crystal morphologies and zoning. Thelarge variations suggest that single basalt samples containa mixture of plagioclase crystals that aggregated at differentlevels in the magma conduits. Resorbed crystals and repeatedreverse zones suggest that the magma reservoirs were replenishedand heated several times. Thin concentric zones with melt inclusions,and sharp reductions in the anorthite content of 3–7%,are common between the reverse zones. These zones, and skeletalcrystals with distinctly lower anorthite contents than massivecrystals, are interpreted to be the result of rapid crystalliztionduring strong undercooling. The changes between short periodsof cooling and longer periods with reheating are explained bymultiple advances of crystal-rich magma into cool regions followedby longer periods of gradual magma inflow and temperature increase.The porphyritic basalts are characterizd by more depleted andmore fractionated compositions than the aphyric basalts, withlower (La/Sm)_N, K₂O and Mg-numbers. This relationship, and theobservation that PUBs are sampled only close to segment centresalong these ridges, suggests that the PUBs formed by higherdegrees of melting and evolved in more long-lived magma reservoirs.We propose that the zoning patterns of plagioclase crystalsand crystal morphologies of these PUBs reflect the developmentand flow of magma through a stacked sill complex-like conduitsystem, whereas the aphyric equivalents represent later flowof magma through the conduit. The formation of voluminous higher-degreemelts may trigger the development of the magma conduits andexplain the generally depleted compositions of PUB magmas. KEY WORDS: basalt; mineral chemistry; MORB; magma mixing; magma chamber; major element     

Pressures of Crystallization of Icelandic Magmas

Iceland lies astride the Mid-Atlantic Ridge and was createdby seafloor spreading that began about 55 Ma. The crust is anomalouslythick (20–40 km), indicating higher melt productivityin the underlying mantle compared with normal ridge segmentsas a result of the presence of a mantle plume or upwelling centeredbeneath the northwestern edge of the Vatnajökull ice sheet.Seismic and volcanic activity is concentrated in 50 km wideneovolcanic or rift zones, which mark the subaerial Mid-AtlanticRidge, and in three flank zones. Geodetic and geophysical studiesprovide evidence for magma chambers located over a range ofdepths (1·5–21 km) in the crust, with shallow magmachambers beneath some volcanic centers (Katla, Grimsvötn,Eyjafjallajökull), and both shallow and deep chambers beneathothers (e.g. Krafla and Askja). We have compiled analyses ofbasalt glass with geochemical characteristics indicating crystallizationof ol–plag–cpx from 28 volcanic centers in the Western,Northern and Eastern rift zones as well as from the SouthernFlank Zone. Pressures of crystallization were calculated forthese glasses, and confirm that Icelandic magmas crystallizeover a wide range of pressures (0·001 to 1 GPa), equivalentto depths of 0–35 km. This range partly reflects crystallizationof melts en route to the surface, probably in dikes and conduits,after they leave intracrustal chambers. We find no evidencefor a shallow chamber beneath Katla, which probably indicatesthat the shallow chamber identified in other studies containssilica-rich magma rather than basalt. There is reasonably goodcorrelation between the depths of deep chambers (> 17 km)and geophysical estimates of Moho depth, indicating that magmaponds at the crust–mantle boundary. Shallow chambers (<7·1 km) are located in the upper crust, and probablyform at a level of neutral buoyancy. There are also discretechambers at intermediate depths (11 km beneath the rift zones),and there is strong evidence for cooling and crystallizing magmabodies or pockets throughout the middle and lower crust thatmight resemble a crystal mush. The results suggest that themiddle and lower crust is relatively hot and porous. It is suggestedthat crustal accretion occurs over a range of depths similarto those in recent models for accretionary processes at mid-oceanridges. The presence of multiple stacked chambers and hot, porouscrust suggests that magma evolution is complex and involvespolybaric crystallization, magma mixing, and assimilation. KEY WORDS: Iceland rift zones; cotectic crystallization; pressure; depth; magma chamber; volcanic glass     

Crystal-Melt Separation and the Development of Isotopic Heterogeneities in Hybrid Magmas

If a magma is a hybrid of two (or more) isotopically distinctend-members, at least one of which is partially crystalline,separation of melt and crystals after hybridization will leadto the development of isotopic heterogeneities in the magmaas long as some of the pre-existing crystalline material (antecrysts)retains any of its original isotopic composition. This holdstrue whether the hybridization event is magma mixing as traditionallyconstrued, bulk assimilation, or melt assimilation. Once a magma-scaleisotopic heterogeneity is formed by crystal–melt separation,it is essentially permanent, persisting regardless of subsequentcrystallization, mixing, or equilibration events. The magnitudeof the isotopic variability resulting from crystal–meltseparation can be as large as that resulting from differentialcontamination, multiple isotopically distinct sources, or insitu isotopic evolution. In one model, a redistribution of one-thirdof the antecryst cargo yielded a crystal-enriched sample with⁸⁷Sr/⁸⁶Sr of 0·7058, whereas the complementary crystal-poorsample has ⁸⁷Sr/⁸⁶Sr of 0·7068. In other models, crystal-richsamples are enriched in radiogenic Sr. Isotopic heterogeneitiescan be either continuous (controlled by the modal distributionof crystals and melt) or discontinuous (when there is completeseparation of crystals and liquid). The first case may be exemplifiedby some isotopically zoned large-volume rhyolites, formed bythe eruptive inversion of a modally zoned magma chamber. Inthe latter case, the isotopic composition of any (for example)interstitial liquid will be distinct from the isotopic compositionof the bulk crystal fraction. The separation of such an interstitialliquid may explain the presence of isotopically distinct late-stageaplites in plutons. Crystal–melt separation provides anadditional option for the interpretation of isotopically zonedor heterogeneous magmas. This option is particularly attractivefor systems whose chemical variation is otherwise explicableby fractionation-dominated processes. Non-isotopic chemicalheterogeneities can also develop in this fashion. KEY WORDS: isotopic heterogeneity; zoning; hybrid magma; crystal separation; Sr isotopes; aplite; rhyolite     

柴达木盆地北缘侏罗系两类不同有机质丰度泥岩的 生物标志物特征对比研究

在柴达木盆地北缘地区,分别选取有机碳含量很低和较高的侏罗系泥岩样品,对比分析了它们在生物标志物组成上的差异。结果发现,高有机质丰度泥岩的生标组成与我国西北地区侏罗纪煤系有机质的特征差异不大,相比而言,低有机质丰度泥岩的正烷烃以前主峰为特征,Pr/Ph比值在1.0左右,三环萜烷和伽马蜡烷丰度较高,并在部分样品中检出了25 降藿烷系列。结合泥岩的有机岩石学特征,认为这些差异可能反映了泥岩沉积环境和生烃母质的不同:高有机质丰度泥岩的有机显微组分以相对弱还原条件下的形态有机质为主,包括藻类体、孢子体和角质体等,而低有机质丰度泥岩的有机显微组分以相对强还原条件下的矿物沥青基质为主,其母质可能来源于低等显微菌藻类。进一步通过对比不同有机质丰度泥岩,以及区内原油生标组成之间的相互关系,讨论了研究区的油源问题。     

近190ka BP以来菲律宾海黑潮源区的碳酸盐旋回及其控制因素

对取自西菲律宾海黑潮源区的Ph05-5和WF3岩芯进行了CaCO3和钙质超微化石研究.在利用氧同位素曲线对比和AMS14C数据进行地层划分的基础上,结合钙质超微化石的碳酸盐溶解指数和初级生产力指标,分析了晚第四纪黑潮源区碳酸盐旋回特征及其控制因素.约190ka BP以来CaCO3含量整体上都表现为冰期高、间冰期低的"太平洋型"旋回特征,但菲律宾以东海区在末次冰期(MIS 4到MIS 2期)内部又显示出间冰段含量高、冰段含量低的"大西洋型"旋回特征.碳酸盐旋回的控制因素在黑潮源区内部也有明显的差异,菲律宾以东海区以碳酸盐溶解作用为主,初级生产力起次要作用;而台湾东南部海区的主要因素则是初级生产力变化引起的钙质生物输入量的波动.菲律宾以东海区末次冰期内部表现出的"大西洋型"旋回特征则是溶解作用和初级生产力共同影响的结果.     

Glass inclusions in volcanic rocks in the Okinawa Trough back-arc basin:constraints on magma genesis and evolution

INTROOUcr1ONThe Okinawa Trough is a typical marginal back-arc basin, where its oPening began in rela-tively recent years* There is a great controversy about the origin of its initial magYna. haltand acid volcanic pumice make up the bimedal volcanism in the Okinawa Trough. MOSt of geol-ogists believed that the acid pumice was the preduct of extremely crystal fractionation of baseltInagTna, but the others argued that it should com from the melting of lower-crust. Som de-tailed petrolOgic…     

标志沉积层磁组构特征及其古环境意义研究

通过对长江三角洲及其邻近区域埋藏古土壤、潮坪、长江下游河道浸滩、舟山滨岸风成沙丘、南京黄土古土壤序列沉积体的磁组构测量统计分析，取得了各自的标志特征。该２特征揭示出，舟山滨岸风成沙丘与南京黄土吉土壤序列沉积的搬运介质能量位相基本一致，其物源来向却显示出巨大差异；上述两类沉积体与上述现今潮坪、河道漫滩沉积体地搬运介质能量位相及物源来向均显示出绝然不同的标志特征。然而浸滩物源来民南京黄土的物尖兵为向却     

南黄海陆架沉积学研究

黄海中部、济州岛西南,存在厚层的泥质沉积,它们分别与上述地区的冷涡活动区相对应。在两个泥质沉积区之间又出现连接它们的通道,形成别有特征的“冷涡-通道”沉积体系。经分析发现,这个沉积体系,完全受控于黄海暖流、冷涡及其相关的环流体系。此外,在黄海西南部及东海北部海底发现大面积砂岩及其砾石,揭示了黄、东海陆架沉积物的新源地。     

漳州地区热田的水热活动及其成因

本文通过漳州地热田及其周围地区的水热活动、地质构造特征及人工爆破、重力、地磁、电性结构、地震活动性等综合地球物理场之间关系分析，得出漳州地热田是高热异常背景下产生的对流型水热系统：深切到上地幔的ＮＥ向长乐－南澳断裂、ＮＷ向九龙江断裂及Ｅ－Ｗ向南靖－厦门断裂控制了地下水的深循环，使大气降水得以下渗到〉３ｋｍ深度，被地温加热并富集起来，在静水压力作用下沿通道－断裂带的交汇部位上涌。热田区破碎的岩石导致