广西佛子冲铅锌矿田地质特征及找矿前景

通过对佛子冲铅锌矿田成矿地质条件、控矿因素、成矿规律的系统总结，区分了相同矿种不同型式矿床的基本特征，进而提出矿床成因类型。在矿田内外一些工作程度较低的地段，通过研究和对比，提出下一步找矿靶区，并指出了该地区找矿由铅锌向银金转化的初步方向     

湖南津市黄牯山第四纪泥砾混杂堆积成因探讨

湖南省津市黄牯山发育一套泥砾混杂堆积,前人曾认为属冰川成因。近年笔者对该套堆积的沉积层序、结构组成、横向变化、砾石组构与表面特征等作了详细考察,发现堆积中下细上粗的层序特征,砾石扁平面的优选定向,沿层理经差异风化和磨蚀所形成的假"冰川擦痕",由壳状裂口经磨蚀、圆化所形成的凹面石,沉积体短距离内的相变,以及周边仅有低矮丘陵的地貌背景等,表明泥砾混杂堆积为泥石流产物,而不是冰川成因。     

Isotopic composition of precipitation over Arid Northwestern China and its implications for the water vapor origin

In order to reveal the characteristics and climatic controls on the stable isotopic composition of precipitation over Arid Northwestern China, eight stations have been selected from Chinese Network of Isotopes in Precipitation (CHNIP). During the year 2005 and 2006, monthly precipitation samples have been collected and analyzed for the composition of δD and δ18O. The established local meteoric water line δD=7.42δ18O+1.38, based on the 95 obtained monthly composite samples, could be treated as isotopic input function across the region. The deviations of slope and intercept from the Global Meteoric Water Line indicated the specific regional meteorological conditions. The monthly δ18O values were characterized by a positive correlation with surface air temperature (δ18O (‰) =0.33 T (℃)–13.12). The amount effect visualized during summer period (δ18O (‰) = –0.04P (mm)–3.44) though not appeared at a whole yearly-scale. Spatial distributions of δ18O have properly portrayed the atmospheric circulation background in each month over Arid Northwestern China. The quantitative simulation of δ18O, which involved a Rayleigh fractionation and a kinetic fractionation, demonstrated that the latter one was the dominating function of condensation of raindrops. Furthermore, the raindrop suffered a re-evaporation during falling processes, and the precipitation vapor might have been mixed with a quantity of local recycled water vapor. Multiple linear regression equations and a δ18O–T relation have been gained by using meteorological parameters and δ18O data to evaluate physical controls on the long-term data. The established δ18O–T relation, which has been based on the present-day precipitation, could be considered as a first step of quantitatively reconstructing the historical environmental climate.     

东营凹陷不同超压成因的有效应力特征

利用实测流体压力(DST)测试结果,结合声波和密度测井资料,对超压段所识别的不均衡压实作用和生烃作用两种超压成因机制下的实测压力和有效应力随深度的变化特征进行了分析,结果表明:①两种不同成因机制下的实测压力和有效应力特征具有明显的差异性,不均衡压实作用在压实过程中导致流体排出受阻,地层流体承担上覆岩层压力形成超压,表现为阻止了地层有效应力增大,因此其实测压力增大段和静岩压力增大趋势大体一致,而有效应力随深度基本保持不变;生油作用在地层正常压实之后形成超压,发育程度不受上覆岩层压力的影响,因此超压的增大在深度上与上覆岩层压力增大不具有一致性,且超压对有效应力的影响要小于不均衡压实作用;②这两种不同的超压成因使得有效应力的变化随着声波速度而出现加载和卸载两种趋势,从而可以用来判断超压成因,利用实测资料计算的有效应力结果说明东营凹陷超压成因机制包括不均衡压实作用和生油作用,但不均衡压实作用形成超压的范围和规模较小,生油作用对深部大规模超压和强超压的形成至关重要.     

湖相叠层石纹层的碳氧同位素特征及其生长节律的古环境意义

青藏高原北部渐新统雅西措组湖相地层中的叠层石,具有典型的毫米级暗色富有机质纹层与浅色富碎屑纹层交替的生长节律,纹层形态呈穹窿状产出。为了探索湖湘叠层石纹层的成因和时间意义,我们采用激光微区采样技术分别对单个暗色纹层和浅色纹层进行了碳氧同位素分析。结果表明,每一个共轭纹层对中,暗色纹层相对于浅色纹层明显富集δ18O和δ13C,而且δ18O和δ13C之间具有正向变化关系,即δ18O和δ13C显示同步亏损和富集,反映季节性气候变化是影响纹层同位素信号周期性波动的主要因素,支持叠层石的对偶纹层为年纹层成因,它可以为气候和环境变化研究提供一种高分辨率地质材料。     

Rare-earth and trace element imprints on the origin and tectonic setting of gabbro-diorite complex in the Pan-African belt of Southeast Obudu Plateau,Nigeria

A gabbro-diorite plutonic complex from the Southeast Obudu Plateau, representing limited volumes of magma, was studied for its trace and rare-earth element characteristics, in an attempt to document its genetic and geodynamic history. Geochemical studies indicate that the gabbro samples are characterized by variable concentrations and low averages of such index elements as Cr (40×10-6–200×10-6; av. 80×10-6), Ni (40×10-6–170×10-6; 53.33×10-6) and Zr (110×10-6–240×10-6; 116.67×10-6); variable and high average...     

川东北地区酸性气体中CO2成因与TSR作用影响

通过对川东北地区52个天然气样品化学组分和稳定碳同位素分析,天然气以烃类气体为主,且甲烷占绝对高含量,重烃气体甚微,干燥系数C1/C1+为0.989～1.0。非烃气体H2S和CO2含量变化较大,当二者含量大于5.0％时,具有较好的正相关性。川东北地区天然气中CO2主要包括碳酸盐岩热分解和TSR作用,其中碳酸盐岩热分解生成的CO2含量一般小于5.0％,13CCO2值小于-2‰,且CO2含量与13CCO2值具有正相关性;而TSR作用生成的CO2含量大于5.0％,13CCO2值多大于-2‰,且CO2含量与13CCO2值具有较弱的负相关性。CH4/CO2比值和（H2S+CO2）/（H2S+CO2+∑C1-3）比值能够较好地反映TSR作用程度;当CH4/CO2比值和（H2S+CO2）/（H2S+CO2+∑C1-3）比值分别小于10和大于0.1时,随着TSR作用增强,CH4/CO2比值减少,而（H2S+CO2）/（H2S+CO2+∑C1-3）比值呈指数增加。同时,遭受TSR作用改造的天然气具有较高CO2含量和重的13CCO2,造成13CCO2值与实验结果不一致性的可能原因是在TSR反应过程中部分CO2与硫酸盐中Mg2+、Fe2+和Ca2+等金属离子以碳酸盐的形式沉淀且残余的重碳同位素组成的CO2与酸性气体腐蚀碳酸盐储层形成的CO2相混合。     

中国大陆环境斑岩型矿床：基本地质特征、岩浆热液系统和成矿概念模型

中国大陆环境斑岩型矿床包括斑岩型Cu(-Mo、-Au)、斑岩型Mo、斑岩型Au和斑岩型Pb-Zn等矿床类型,主要产出于青藏高原大陆碰撞带、东秦岭大陆碰撞带和中国东中部燕山期陆内环境,在地球动力学背景、深部作用过程、岩浆起源演化、流体与金属来源等方面与岩浆弧环境斑岩型矿床存在重要差异.在大洋板块俯冲形成的岩浆弧,主要发育斑岩Cu-Au矿床或富金斑岩Cu矿(岛弧)和斑岩Cu-Mo及斑岩Mo矿床(陆缘弧).相比,在大陆碰撞带,晚碰撞构造转换环境发育斑岩Cu、Cu-Mo和Cu-Au矿床,矿床受斜交碰撞带的走滑断裂系统控制,后碰撞地壳伸展环境则主要发育斑岩Cu-Mo矿床,矿床受垂直于碰撞带的正断层系统控制;在陆内造山环境,早期发育斑岩Cu-Au矿床,晚期发育斑岩Pb-Zn矿床,它们主要沿古老的但再活化的岩石圈不连续带分布,受网格状断裂系统控制;在后造山(或非造山)伸展环境,则大量发育斑岩Mo矿和斑岩Au矿,它们则主要围绕大陆基底-克拉通(或地块)边缘分布,受再活化的岩石圈不连续带控制.大陆环境斑岩Cu(-Mo,-Au)矿床的含矿斑岩多为高钾钙碱性和钾玄质,以高钾为特征,显示埃达克岩地球化学特性.岩浆通常起源于加厚的新生镁铁质下地壳或拆沉的古老下地壳.上地幔通过三种可能的方式向岩浆系统供给金属Cu(和Au):①提供大批量的幔源岩浆并底垫于加厚下地壳底部,构成含Cu岩浆的源岩;②提供小批量的软流圈熔体交代和改造下地壳,并诱发其熔融;③与拆沉的下地壳岩浆熔体发生反应.大陆环境含Mo岩浆系统高SiO_2、高K_2O,岩相以花岗斑岩为主,花岗闪长斑岩次之,既不同于Climax型,又有别于石英二长斑岩型Mo矿床,岩浆起源于古老的下地壳.金属Mo主要为就地熔出,部分萃取于上部地壳.大陆环境含Pb-Zn花岗斑岩多属铝过饱和型,与S型花岗岩相当,以高δ~(18)O(>10‰)和高放射性Pb为特征,Sr-Nd-Pb同位素组成反映其来源于中下地壳的深熔作用,金属Pb-Zn主要来源于深融的壳层.大陆环境含Au岩浆系统以富B花岗闪长斑岩为主,常与矿前闪长岩密切共生.Sr-Nd-Pb同位素显示,含Au岩浆主要来源于上部地壳,但曾与幔源岩浆发生相互作用.金属Au部分来源于上地壳,部分来源于地幔岩浆.大陆环境斑岩型矿床显示各具特色的蚀变类型和蚀变分带,其中,斑岩型Cu(-Mo,-Au)矿热液蚀变遵循Lowell and Guilbert模式;斑岩型Mo矿主要发育钙硅酸盐化、钾硅酸盐化和石英-绢云母化;斑岩型Pb-Zn矿主要发育绿泥石-绢云母化和绢云母-碳酸盐化,缺乏钾硅酸盐化;斑岩型Au矿强烈发育中度泥化.斑岩型矿床的成矿流体初始为高温、高fO_2、高S、富金属的岩浆水,由浅成侵位的长英质岩浆房在应力松弛环境下出溶而来,晚期有天水不同程度地混入.Cu、Mo、Pb-Zn通常沉淀于流体分相和流体沸腾过程中,而Au则主要沉淀于岩浆-热液过渡阶段.     

Cometary nuclei internal structure from early aggregation simulations

A new model for the aggregation of cometesimals in the primordial solar nebula is proposed. The simulation of the aggregation takes into account disruptive and sticking effects of impacts on the aggregates properties together with the temporal evolution of cohesive strength during accretion due to sintering processes. Different regimes of aggregation are obtained depending on the value of the homogeneity exponent, μ, that indicates the fraction of kinetic energy available for cohesive energy dissipation during an impact. Porous fractal aggregates with different cohesive strength blocks are formed for 0 < μ < 0.4, while they are compact with a layered structure of different strengths for 0.4 < μ < 0.6 and weak ‘rubble piles’ for 0.6 < μ < 1. Cohesive strength estimations of the final cometary nuclei obtained give values generally lower than 10 kPa. The layered aggregates present the highest global cohesive strength, increasing their probability to survive collisions or moderate tidal stress. These results compare well with the structural and cohesive properties of comets deduced from observations and laboratory simulations.     

天津表土PAHs的空间主成分与污染源分析

在多元空间结构分析的基础上,应用空间主成分分析方法研究了天津表层土壤16种多环芳烃(PAHs)的空间主成分特征,并在此基础上探讨了空间污染源问题。分析结果显示,从总体来看,PAHs主要的污染源是燃烧源和石油源。从不同空间尺度来看,石油源的影响范围一般在5km以内,而燃烧源的主要影响范围在5~10km之间,在更大的范围上,可能是天然源,或者区域性的大气沉降。