论地质作用中元素间的相关性及制约因素

本文把地质作用中元素间的相关性划分为曲线相关、准线性相关和线性相关三种类型;并在建立反映岩浆、沉积作用过程中元素间相关关系的数学模型及其它工作的基础上,详细讨论分配系数、源区成分和作用过程等方面对地质作用中元素间相关关系的制约作用。进而获得批式熔融、结晶分异、岩浆混合、化学沉积、碎屑沉积等过程中元素间呈线性和(?)线性关系的一般特征和应用前景。最后还给出La/Ce相关性的应用实例。     

Timing and Processes of Ore Formation in the Qingchengzi Polymetallic Orefield, Northeast China: Evidence from 40Ar/39Ar Geochronology

The Qingchengzi orefield is a large polymetallic ore concentration area in the Liaodong peninsula,northeastern China,that includes twelve Pb-Zn deposits and five Au-Ag deposits along its periphery.The ore-forming age remains much disputed,which prevents the identification of the relationship between the mineralization and the associated magmatism.In this paper,we quantitatively present the feasibility of making ore mineral ~(40)Ar/~(39)Ar dating and report reliable ~(40)Ar/~(39)Ar ages of lamprophyre groundmass,K-feldspar and sphalerite from the Zhenzigou deposit.Direct and indirect methods are applied to constrain the timing of mineralization,which plays a vital role in discussing the contribution of multistage magmatism to ore formation.The low-potassium sphalerite yielded an inverse isochron age of 232.8±41.5 Ma,which features a relatively large uncertainty.Two lamprophyre groundmasses got reliable inverse isochron ages of 193.2±1.3 Ma and 152.3±1.5 Ma,respectively.K-feldspar yielded a precise inverse isochron age of 134.9±0.9 Ma.These four ages indicate that the mineralization is closely associated with Mesozoic magmatism.Consequently,regarding the cooling age of the earliest Mesozoic Shuangdinggou intrusion(224.2±1.2 Ma)as the initial time of mineralization,we can further constrain the age of the sphalerite to 224–191 Ma.These new and existing geochronological data,combined with the interaction cutting or symbiotic relationship between the lamprophyre veins and ore veins,suggest that the Pb-Zn-Au-Ag mineralization in the Qingchengzi orefield mainly occurred during three periods:the late Triassic(ca.224–193 Ma),the late Jurassic(ca.167–152 Ma)and the early Cretaceous(ca.138–134 Ma).This polymetallic deposits are shown to have been formed during multiple events coinciding with periods of the Mesozoic magmatic activity.In contrast,the Proterozoic magmatism and submarine exhalative and hydrothermal sedimentation in the Liaolaomo paleorift served mainly to transport and concentrate the ore-forming substances at the Liaohe Group with no associated Pb-Zn-Au-Ag mineralization.     

Mineralogical and geochemical study of a newly discovered mafic granulite, northwest China: Implications for tectonic evolution of the Altay Orogenic Belt

Abstract A mafic granulite body was newly discovered in the Altay Orogenic Belt, northwest China. The rocks comprise a suite of coarse‐grained and fine‐grained granulites. Orthopyroxenes (hypersthenes) in the rocks have high X_Mg and low Al₂O₃ contents, whereas clinopyroxenes have low TiO₂ and Al₂O₃ contents. Amphiboles and biotites have a high Mg/(Mg + Fe²⁺) ratio and low contents of F and Cl. The peak metamorphic pressure–temperature (P–T) conditions are estimated as 750–780°C and 6–7 kbar, and retrograde P–T conditions are in the range of 590–620°C and 2.3–3.7 kbar, indicating significant decompression. Metamorphic reactions and P–T estimates define a clockwise P–T path. Geochemically, the rocks are high in Mg/(Mg + Fe) and Al₂O₃, depleted in U, Th, K and Rb, and characterized by light rare earth element enrichment and a weak positive Eu anomaly. The Altay mafic granulite shows depleted Nb, P and Ti contents in the mid‐oceanic ridge basalt normalized spider diagram. The geochemical characteristics suggest that the protolith of the Altay mafic granulite was calc‐alkaline basalt and andesite with an island‐arc affinity. The rock has a high ¹⁴³Nd/¹⁴⁴Nd ratio with ?Nd(0) > 0, indicating derivation from a mantle‐depleted source. In the present study, a two‐stage model for the evolution of the Altay mafic granulite is proposed: an early stage in which calc‐alkaline basalt and andesite with island‐arc affinity were subducted into a deeper level of the crust and subjected to granulite‐facies metamorphism generating the mafic granulite, followed by the later stage exhumation of the system into the upper crust by the late Paleozoic thrusting.     

SHRIMP U-Pb zircon age,geochemistry and Nd-Hf isotope of Neoproterozoic mafic dyke swarms in western Sichuan:Petrogenesis and tectonic significance

Neoproterozoic magmatic rocks are widespread in the western margin of the Yangtze block, and their origin and genesis have significant implications for understanding the evolution of the Rodinia super- continent. However, there are currently two opposing interpretations for their petrogenesis and tectonic setting: mantle plume-related and island arc origin. To further verify these two competing models, SHRIMP U-Pb zircon age determinations and geochemical and Nd-Hf isotopic analyses are conducted on the mafic dykes in the Kangdian Rift, western Sichuan. U-Pb dating suggests that these mafic dykes were emplaced at 780―760 Ma, spatially and temporally coeval with the Kangding granitoid complex. The parental magmas of these dykes were derived from a depleted asthenosphere mantle source likely triggered by an anomalously-hot mantle plume. Despite some arc-geochemical features caused by variable degrees of contamination of young island arc crust during magma ascending and emplace- ment, they show general geochemical and Nd-Hf isotopic features similar to those of the intraplate basalts. Our results support the reconstruction model of Rodinia in which the South China block was located between Australia and Laurentia.     

藏南洛扎地区基性岩墙群锆石U-Pb定年、地球化学特征及构造意义

藏南洛扎地区广泛分布有近东西向产出的基性岩墙群,主要侵位于晚侏罗世—早白垩世及其以前的地层中,锆石U-Pb同位素定年获得成岩年龄138.0Ma±3.5Ma。基性岩墙可以划分为2种主要类型:一类低K(K2O=0.06%～0.54%),稀土元素总量和轻、重稀土元素分异程度低[∑REE=58.95×10-6～115.5×10-6,(La/Yb)N=0.23～2.94],亏损LILE;另一类富K(K2O=1.22%～1.67%),稀土元素总量和轻、重稀土元素分异程度较高[∑REE=199.97×10-6～381.47×10-6,(La/Yb)N=6.57～11.5],富集LILE而亏损HFSE。地球化学研究结果表明,基性岩墙为具大陆拉斑玄武岩特征的大陆板内岩浆侵入体,可能分别源于亏损的软流圈地幔和富集的岩石圈地幔。基性岩墙群是新特提斯洋晚期大规模扩张的产物,标志着喜马拉雅被动大陆边缘在晚侏罗世—早白垩世处于强烈的拉张、裂离和岩石圈伸展减薄、软流圈上涌的构造环境与动力学背景。     

华北克拉通基性火山岩高场强元素对Ar-Pt界限及新生代地幔源区特征的示踪

华北克拉通不同时代基性火山岩存在向富集方向演化的趋势,并出现明显的Ａｒ－Ｐｔ界限和新生代异常．元古宙基性火山岩比太古宙富集大部分高场强元素（ＨＦＳＥ）和轻稀土元素（ＬＲＥＥ）,ＲＥＥ分异程度显著增加,而且相容性接近的不相容元素（如Ｎｂ,Ｔａ）的相对不相容性发生了改变．新生代玄武岩ＨＦＳＥ及Ｎｉ高度富集,ＲＥＥ强烈分异,δ（Ｅｕ）值最高．Ａｒ－Ｐｔ界限可能与地幔熔融时物理条件（如氧逸度）的改变和地幔富集作用有关．新生代玄武岩独特的地球化学特征可能主要反映了地幔源区的特殊性———“似ＯＩＢ型”富集地幔,其形成既可能有携带远洋沉积物的俯冲古老玄武岩洋壳部分熔融残余的贡献,也可能有直接循环（如通过拆沉作用）的陆壳物质的贡献,同时还可能涉及了地幔柱活动的影响．     

Post-collisional volcanism in a sinking slab setting—crustal anatectic origin of pyroxene-andesite magma, Caldear Volcanic Group, Neogene Alborán volcanic province, southeastern Spain

Caldear Volcanic Group (CVG), a stratigraphically well defined, calc-alkaline rock complex within S^a de Gata in the eastern part of the Alpine Betic mountain chain, S Spain, consists of three distinct formations: Hernández pyroxene andesites, Bujo hornblende-bearing pyroxene andesites and Viuda hornblende-bearing pyroxene dacites–rhyolites. The letter rock formation may have developed through crystal fractionation of mainly plagioclase and pyroxenes, however there is no direct relation between two formations. CVG has a domainal structure with a northeastern domain where Hernández formation is overlain by Bujo formation while Viuda formation is absent, and a southwestern domain where Viuda formation forms the only fractionate after Hernández formation. Hernández parent magma is thought generated through crustal anatexis by dehydration melting of a predominantly amphibolitic source rock complex which was formed by metamorphism from c. 500 Ma volcano-sedimentary parent material. The domainal structure of CVG is explained by compositional variation within this protogenetic complex. Single crystal U–Pb ages of c. 500 Ma to 1800 Ma for inherited zircon support the presence of clastic material of Proterozoic derivation within the original volcano-sedimentary complex. Regional study of syn-collisional rock formations (Alpine nappe complexes) indicate that the collisional tectonic stage in the Betic-Rif orogenic belt took place rather early (25–30 Ma?) and was followed by a stage of rapid regional rock uplift, fast cooling (c. 500°C/my) and extensional tectonics in the period 22–17 Ma. This later tectonic stage was set into motion by slab break-off which set the stage for a high temperature regime in the overlying lithosphere, providing the framework for the crustal melting and magma production responsible for the calc-alkaline rocks of Alborán volcanic province. Miocene zircon with ages ranging from c. 17 to 11 Ma indicate a rather protracted magmatic development prior to eruption at c. 11 Ma. Post-collisional character of Caldear Volcanic Group thus seems well established.     

Geochemical approach to magmatic evolution of Mt. Erciyes stratovolcano Central Anatolia, Turkey

Erciyes stratovolcano, culminating at 3917 m, is located in the Cappadocian region of central Anatolia. During its evolution, this Quaternary volcano produced pyroclastic deposits and lava flows. The great majority of these products are calc-alkaline in character and they constitute Kocdag and Erciyes sequences by repeated activities. Alkaline activity is mainly observed in the first stages of Kocdag and approximately first-middle stages of Erciyes sequences. Generally, Kocdag and Erciyes stages terminate by pyroclastic activities. The composition of lavas ranges from basalt to rhyolite (48.4–70.5 wt.% SiO₂). Calc-alkaline rocks are represented mostly by andesites and dacites. Some compositional differences between alkaline basaltic, basaltic and andesitic rocks were found; while the composition of dacites remain unchanged. All these volcanics are generally enriched in LIL and HFS elements relative to the orogenic values except Rb, Ba, Nb depleted alkaline basalt. ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd isotopic composition of the volcanics range between 0.703344–0.703964, 0.512920–0.512780 for alkaline basalts and change between 0.704322–0.705088, 0.512731–0.512630 for alkaline basaltic rocks whereas calc-alkaline rocks have relatively high Sr and Nd isotopic ratios (0.703434–0.705468, 0.512942–0.512600). Low Rb, Ba, Nb content with high Zr/Nb, low Ba/Nb, La/Yb ratio and low Sr isotopic composition suggest an depleted source component, while high Ba, Rb, Nb content with high La/Yb, Ba/Nb, low Zr/Nb and low ⁸⁷Sr/⁸⁶Sr ratios indicate an OIB-like mantle source for the generation of Erciyes alkaline magma. These elemental and ratio variations also indicate that the different mantle sources have undergone different degree of partial melting episodes. The depletion in Ba, Rb, Nb content may be explained by the removal of these elements from the source by slab-derived fluids which were released from pre-collisional subduction, modified the asthenospheric mantle. The chemically different mantle sources interacted with crustal materials to produce calc-alkaline magma. The Ba/Nb increase of calc-alkaline samples indicates the increasing input of crustal components to Erciyes volcanics. Sr and Nd isotopic compositions and elevated LIL and HFS element content imply that calc-alkaline magma may be derived from mixing of an OIB-like mantle melts with a subduction-modified asthenospheric mantle and involvement of crustal materials in intraplate environments.     

蔓箐沟一带石榴基性麻粒岩变质反应与矿物演化

蔓箐沟地区石榴基性麻粒岩发育多期变质反应结构。矿物组合演化可划分三个阶段：①峰期阶段（Ｍ１）,以包裹于石榴石中的Ｏｐｘ＋Ｃｐｘ±Ｈｂ＋Ｐｌ±Ｑｚ和由Ｇｔ＋Ｏｐｘ＋Ｃｐｘ±Ｈｂ＋Ｐｌ±Ｑｚ组成基质矿物组合为代表;②退变早期近等温减压阶段（Ｍ２）,形成蠕虫状后成合晶Ｏｐｘ＋Ｈｂ＋Ｐｌ±Ｍｔ;③退变晚期阶段（Ｍ３）,则形成细粒、黄绿色Ｈｂ＋中酸性Ｐｌ的较低温组合。并揭示该区石榴基性麻粒岩从中下部地壳的麻粒岩相变质,到快速抬升至中浅部地壳发生的近等温减压及晚期降温退变的复杂ｐＴ演化历史。