南阿尔金尤努斯萨依花岗质高压麻粒岩的发现及其地质意义

南阿尔金尤努斯萨依地区首次发现一套高压麻粒岩相特征矿物组合的含蓝晶石石榴子石的花岗质片麻岩,其矿物组合为Grt+Ky+Per(+Ksp)+Ru+Q。依据矿物内部一致性热力学数据,基于THERMOCALC 3. 40程序平台,计算出P-T视剖面图,并结合矿物等值线、矿物组合稳定域及三元长石温度计等,确定其早期变质温压条件为T=970～1010℃,P=23. 2～25. 3kbar,达到了榴辉岩相变质条件。同时,根据岩相学观察获得的矿物共生组合与矿物变质显微结构以及P-T视剖面图,可识别出该岩石在早期变质之后还经历了以矿物组合Grt+Ky+Per(+Ksp)+Pl+Ru+Q为代表的麻粒岩相、以及Grt+Ky+Ksp+Pl+Bi+Ru+Ilm+Q为代表的麻粒岩-高角闪岩相和以Ky+Ksp+Pl+Q+Bi+Mu+Ru+Ilm为代表的角闪岩相三期退变质作用,它们共同构成了一个顺时针型降温降压的退变质P-T演化轨迹,指示出与大陆俯冲-深俯冲相关的高压变质事件和俯冲碰撞后的折返事件。利用LA-ICP-MS进行的锆石原位微区U-Pb定年和微量元素分析表明,该高压岩石峰期变质年龄497. 8±2. 7Ma,与南阿尔金地区已发现的高压-超高压岩石的峰期变质时代完全一致,表明它们应属同一变质岩带;其原岩形成时代为900. 2±4. 1Ma,与南阿尔金已报道的正变质的高压-超高压岩石原岩的形成时代基本一致,指示它们可能具有相同的原岩属性。这套花岗质高压麻粒岩的确定为进一步约束南阿尔金早古生代高压-超高压变质岩带的时空分布规律提供了新的限定。     

Permo-Triassic high-pressure metamorphism in the central western Korean Peninsula,and its link to Paleo-Tethyan Ocean closure: Key issues revisited

Permo-Triassic high-pressure(HP) mafic granulites, together with the Bibong retrogressed eclogite,preserved along the central western Korean Peninsula provide important insights into the Late Permian to Triassic collisional orogeny in northeast Asia. The metamorphic pressureetemperatureetime(P-T-t)paths of these rocks, however, remain poorly constrained and even overestimated, owing to outdated geothermobarometers and inaccurate isopleth techniques. Here we evaluate the metamorphic Pe T conditions of Triassic HP mafic granulites including those in Baekdong, Sinri and Daepan and the Bibong Triassic retrogressed eclogite in the Hongseong area, and the Permo-Triassic Samgot mafic granulite in the Imjingang Belt of the central western Korean Peninsula through the application of modern phase equilibria techniques. The Baekdong and Samgot mafic granulites and the Bibong retrogressed eclogite yield a range of 12.0 -16.0 kbar and 800 -900℃, representing HP granulite facies conditions. The Sinri and Daepan granulites from the Hongseong area show relatively lower grade metamorphic conditions between HP granulite and normal granulite facies, and are characterized by sub-isothermal decompression during exhumation. The similarities in the metamorphic ages and the post-collisional igneous activity from the central western Korean Peninsula indicate that the Triassic ages represent the retrograde stage of the metamorphic Pe T paths. In contrast, the Late Permian metamorphic ages, which are older than protolith ages of the post-collisional igneous rocks, correspond to the possible prograde stage of metamorphism. The P-T-t paths presented in this paper, together with the metamorphic ages and post-orogenic igneous events reported from these areas suggest trace of the subduction, accretion and exhumation history, and indicate a tectonic linkage among the northeast Asian continents during the Paleo-Tethyan Ocean closure.     

西秦岭天水地区晚三叠世柴家庄二长花岗岩及其暗色包体地球化学——岩石成因及岩浆混合作用

晚三叠世花岗岩类在秦岭-大别造山带西端广泛分布,其成因机制及地球动力学背景的研究对于反演华北、扬子两大板块沿秦岭-大别造山带在三叠纪时期的拼合历史具有重要意义.本文选择西秦岭天水地区柴家庄晚三叠世二长花岗岩及其中的暗色包体进行精细的岩石学和地球化学研究.暗色包体中普遍发育针状磷灰石及斜长石捕掳晶,暗示岩浆混合作用;暗色包体具有较低的SiO₂（60.27%~60.38%）、高的Mg#（54~55）和Nb/Ta比值（14.8~16.6）,表明其来源于富集岩石圈地幔的部分熔融作用;寄主二长花岗岩表现出典型埃达克岩的地球化学特征,其富集Sr、Ba,亏损Y和HREE,岩石的Sr/Y比值介于88~98之间,Y/Yb比值介于13~15之间,暗示源区有石榴石残余.结合前人的研究结果,提出柴家庄二长花岗岩可能为增厚的造山带下地壳在碰撞后伸展环境下发生部分熔融作用的产物,可能与晚三叠世时期秦岭造山带的板片断离作用有关     

Using calculated chemical potential relationships to account for replacement of kyanite by symplectite in high pressure granulites

Calculated mineral equilibria are used to account for the formation of sapphirine–plagioclase, spinel–plagioclase and corundum–plagioclase symplectites replacing kyanite in quartz–plagioclase–garnet–kyanite granulite facies gneisses from the Southern Domain of the Athabasca granulite terrane, a segment of the Snowbird tectonic zone in northern Saskatchewan, Canada. Metamorphic conditions of >14 kbar and 800 °C are established for the high pressure, garnet–kyanite assemblage using constraints from P–T pseudosections and Zr‐in‐rutile thermometry. Replacement of kyanite by symplectites reflects the reaction of kyanite with the matrix following near‐isothermal decompression to <10 kbar. The chemical potential gradients developed between the kyanite and the matrix led to diffusion that attempted to flatten the gradients, kyanite persisting as a stable phase while it is consumed by symplectite from its edge. In this local equilibrium model, the mineral and mineral compositional spatial relationships are shown to correspond to paths in μ(Na₂O)–μ(CaO)–μ(K₂O)–μ(FeO)–μ(MgO) in the model chemical system, Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂ (NCKFMAS), with SiO₂ and Al₂O₃ taken to be completely immobile. The values of μ(Na₂O) and μ(CaO) are constrained by fixing P–T conditions and choosing appropriate μ(Na₂O) and μ(CaO) values that correspond to the observed plagioclase compositions. μ(FeO)–μ(MgO) diagrams show the corresponding spatial relationships with kyanite and the symplectite phases. These results demonstrate that the replacement of kyanite by sapphirine–plagioclase and spinel–plagioclase appears to be metastable with respect to replacement by corundum–plagioclase. Replacement by corundum–plagioclase does also occur, apparently overprinting pre‐existing symplectite and also kyanite. Ignoring corundum, the resulting diagrams account for the spatial relationships and compositions observed in the spinel–plagioclase and sapphirine–plagioclase symplectites. They are predicted to occur over both a wide range of P–T conditions (6–11 kbar, 650–850 °C) and plagioclase compositions (X_An = 0.5–0.9). The wide range of P–T conditions that may result in identical spatial and compositional relationships suggests that such reaction textures may be of limited use in accurately quantifying the P–T conditions of retrograde metamorphism.     

Juxtaposition of India and Antarctica During the Precambrian: Inferences from Geochemistry of Mafic Dykes

There are several geological, geochemical and geophysical evidences, which corroborate reconstruction of Gondwanaland and juxtaposition of India and Antarctica. Petrology of the Precambrian mafic dykes of East Antarctica and Central-East India also support juxtaposition of India and Antarctica. Mafic dykes of different generations are emplaced in the Archaean granite gneisses of these regions. These dykes appear to be an important tool to support juxtaposition of India and Antarctica. Geological and petrological data of the Central-East India Precambrian mafic dykes suggest four episodes of mafic magmatism in the region - three tholeiitic and one noritic (?). Similarly, East Antarctica also comprises four dyke suites, emplaced during three distinct periods. These suites are 2.4 Ga meta-tholeiites, 2.4 Ga high-Mg tholeiites, 1.8 Ga dolerites and 1.2–1.4 Ga dolerites. Geochemical compositions of these mafic dykes are compared and they show good relationships with each other. Similarities in petrological and geochemical characteristics of Precambrian mafic dykes of East Antarctica and Central-East India strongly support juxtaposition of these two continents.     

安徽铜陵地区幔源镁铁质团块研究及其地质意义

幔源岩石包体研究,是认识上地幔岩石圈物质组成、幔源岩浆演化及壳幔动力学过程的重要手段。铜陵地区小铜官山石英二长闪长岩中发育有微粒闪长质包体,并且这些微粒闪长质包体中不均匀地分布着镁铁质团块,三者的形成过程可视为铜陵地区岩浆演化的缩影,为了解本区深部岩浆作用过程提供了有力的证据。在前人研究的基础上,笔者借助电子探针、扫描电镜、电镜能谱和二次飞行时间离子探针(Tof-SIMS)对产于铜陵地区微粒闪长质包体中的镁铁质团块进行了详细的研究,首次获得了一套精确的矿物化学资料和元素分布图,总结了镁铁质团块的特征,并讨论了本区的深部岩浆作用过程。矿物学研究表明,镁铁质团块中的角闪石和辉石均已发生了不同程度的透闪石化和阳起石化蚀变,蚀变过程中,从镁钙闪石到镁角闪石,再到透闪石,随着Si的增加,角闪石呈现出Mg的富集和Ti、Al贫化的特点。团块中的富Cr磁铁矿、Ti磁铁矿和少量的铝直闪石指示了其具有深源性。Tof-SIMS元素分布图显示,透闪石主要由Al、Si、Ca、Sc、V、Cr、Mn、Cu和Sr元素组成,透辉石主要由Si、Mg、Ca、Cu和Rb组成。在铜陵地区,上地幔部分熔融形成一套玄武岩浆,受岩浆底侵作用影响,玄武岩浆上侵,进入下地壳深位岩浆房,与下地壳硅镁层发生同化混染作用,形成一套轻度演化的中基性(辉长质)玄武岩浆,镁铁质团块就是这类中基性玄武岩浆直接结晶形成的。后受构造作用影响,这类中基性玄武岩浆上侵到中地壳岩浆房(12~16 km),与中地壳的变质岩系发生同化混染和结晶分异作用形成一套中性闪长质岩浆,微粒闪长质包体就是这套闪长质岩浆发生结晶分异作用而形成的。镁铁质团块和微粒闪长质包体清楚地解释了铜陵地区深部岩浆作用过程,并有力地证明了铜陵地区中地壳的闪长质岩浆来源于下地壳的壳幔混源岩浆。     

Petrology and geochemistry of the ultramafic–mafic Mawpyut complex,Meghalaya: a Sylhet trap differentiation centre in northeastern India

The present article describes, for the first time, petrological and geochemical details of the Mawpyut differentiated complex which is related to the Sylhet trap located at Jaintia Hills district, Meghalaya, northeastern India. The Mawpyut complex occurs as an arcuate body that intrudes into the surrounding Shillong Group rocks. The complex in general contains ‘ultramafic’ and ‘mafic’ rocks, as well as minor syenitic veins that postdate the main units. The lithotypes correspond to cumulate and noncumulate units. The cumulate unit is represented by olivine clinopyroxenite, clinopyroxenite, plagioclase‐bearing ultramafic, olivine gabbronorite, mela‐gabbronorite, melagabbro, orthopyroxene gabbro, and gabbro, all with a pronounced cumulus texture. The noncumulate unit is marked by gabbro, monzonite, monzodiorite, and quartzsyenite. The use of several major and trace element variation diagrams suggests that magmatic differentiation led to the formation of cumulate and noncumulate units. In chondrite‐normalized REE diagrams the cumulate rocks show flat LREE and MREE patterns and a moderate positive Eu anomaly (in plagioclase‐bearing ultramafics) due to plagioclase cumulation. The rocks of the noncumulate unit show a strongly fractionated REE pattern and no Eu anomaly. The noncumulate mafic rocks are geochemically comparable to high‐phosphorous/high‐titanium basalts (HPT) indicative of low pressure fractional crystallization. In a primitive mantle‐normalized multielement diagram some of the cumulate rocks show pronounced negative anomalies for K and P, indicating anorogenic mafic magmatism in a within‐plate setting. The rocks of the noncumulate unit show a slight negative anomaly for Yb and a Nb–Ta trough, indicating a subduction‐related signature that perhaps is inherited from subducted sedimentary rocks incorporated during crustal contamination of the derived magma (left after crystal cumulation) with country rocks. Various trace element ratios for the cumulate mafic rocks indicate parent EMI/EMII/HIMU sources with a very limited crustal signature. The noncumulate mafic rocks (corresponding to the derived evolved magma) indicate EMI/EMII/HIMU sources with a pronounced crustal contamination. The Sr–Nd isotopic compositions of the Mawpyut samples typically plot in the continental flood basalt field, with an affinity to the EMII source. The isotopic compositions of the noncumulate rocks also clearly indicate crustal contamination. We suggest that partial melting (involving garnet in the residue) of the enriched mantle source EMI/EMII/HIMU could have derived the parental melt; this melt, in turn, underwent assimilation and fractional crystallization to produce the variety of cumulate‐noncumulate lithologies of the Mawpyut complex. Copyright © 2013 John Wiley & Sons, Ltd.     

中国显生宙造山带麻粒岩相高级变质岩石的地质特征、变质时代、P-T轨迹及其形成的大地构造背景

本文重点介绍我国显生宙造山带中麻粒岩的地质特征、岩石类型、P-T轨迹、变质时代及其形成的大地构造背景。我国显生宙造山带主要包括阿尔泰造山带、南天山-西南天山造山带、西昆仑造山带、东昆仑造山带、阿尔金-柴北缘造山带、北秦岭造山带、南秦岭勉略造山带、东秦岭-桐柏-大别造山带、班公湖-怒江造山带和喜马拉雅中东段造山带。这些造山带中麻粒岩的围岩有许多为蛇绿岩套或蛇绿混杂岩带,部分为副片麻岩和花岗质片麻岩,并一起经历了麻粒岩相变质改造,造山带中大多出现一种高压麻粒岩,有的与榴辉岩并存,但少数造山带中(例如阿尔泰造山带)多种压力类型麻粒岩并存,既有低-高压泥质麻粒岩、中低压基性麻粒岩、高压基性和长英质麻粒岩,又有高温-超高温泥质麻粒岩。变质时代除个别为新元古代晚期外,变质时间多为加里东、海西、印支、燕山、喜山期。麻粒岩的P-T轨迹除西天山木札尔特河低压麻粒岩具逆时针轨迹,反映大陆弧构造环境外,其它都是具有等温降压(ITC)特点的顺时针轨迹,形成的大地构造环境大部分为洋陆俯冲碰撞环境,少部分为陆-陆碰撞环境。目前显生宙造山带中麻粒岩的研究大多数尚在起步阶段,少数研究较详细,不少造山带中麻粒岩的类型和变质时代以及形成的构造背景还不清楚,有待深入研究,新的麻粒岩产地有待发现。     

http://www.sciencedirect.com/science/article/pii/S1674987112000588

Large charnockite massifs occur in the high-grade Southern Granulite Terrain(SGT) and Eastern Ghats Belt(EGB) crustal provinces of Peninsular India.Available geochronological data indicate that the magmatism is episodic,associated with distinct orogenic cycles in the different crustal domains. The geochemical data also indicate a change in composition from trondhjemitic at～3.0—2.9 Ga to dominantly tonalitic at～2.6—2.5 Ga to tonalitic-granodiorite-granitic at—2.0—1.9 Ga to dominantly tonalitic at 1.7—1.6 Ga to quartz monzonitic or tonalitic at～1.0—0.9 Ga to granodiorite-granitic at～0.8—0.7 Ga. The trondhjemitic and tonalitic end members are metaluminous.magnesian and calcic to calc-alkalic, characteristic of magnesian group charnockites.The granodioritic to granitic end members are metaluminous to slightly peraluminous.ferroan and calc-alkalic to alkali-calcic,characteristic of ferroan group charnockites.The quartz monzonitic end members are metaluminous to peraluminous,magnesian to ferroan and calcic to calc-alkalic.neither characteristic of the magnesian group nor of the ferroan group of charnockites. Based on the occurrence and difference in composition of the charnockite massifs,it is suggested that the charnockite magmatism registers the crustal growth of the Indian plate on its southern(SGT) and eastern(EGB) sides,along active continental margins by accretion of arcs.     

山东半岛高压麻粒岩中花岗质浅色脉体的成因

山东半岛早前寒武纪变质基底部分熔融现象十分发育,常见新生的花岗质浅色脉体呈形态各异的网脉状、细脉状、不规则的透镜状、雾迷状分布于高压基性麻粒岩中。锆石中矿物包体的激光拉曼鉴定、阴极发光图像分析、锆石原位LA-ICP-MSU-Pb定年以及稀土元素、微量元素分析的综合研究结果表明,山东半岛早前寒武纪变质基底在麻粒岩相变质作用的同时伴随着明显的部分熔融作用。花岗质浅色脉体中的锆石具有完好的自形晶形态,矿物包体主要为石英(Qtz)+钾长石(Kfs)+斜长石(Pl)±磷灰石(Ap),与花岗质脉体矿物组成完全一致,相应的阴极发光图像自核部到边部均显示明显的岩浆结晶环带。这些新生锆石U含量变化较大(31×10-6～779×10-6)、Th含量(0.03×10-6～1.3×10-6)和相应的Th/U比值(<0.0081)异常偏低,其稀土元素配分模式具有重稀土HREE相对平坦、中等-强烈的负Eu异常(Eu/Eu*=0.13～0.65)和显著的正Ce异常(Ce/Ce*=11～32)的特点。新生锆石的上述性质与世界典型地区混合岩中深熔锆石的特征十分相似,充分表明研究区花岗质浅色脉体中的锆石为深熔成因。野外及室内系统的岩相学观察发现,花岗质浅色脉体的寄主岩石——高压基性麻粒岩并未显示含水矿物脱水(如角闪石)熔融和长英质矿物部分熔融的证据,而其围岩如孔兹岩系则保存含水矿物(如黑云母)脱水熔融和长英质矿物部分熔融的确凿证据。此外,高压基性麻粒岩中的花岗质浅色脉体集中分布于构造变形相对较强、破碎较明显的部位。由此可见,高压麻粒岩中的花岗质浅色脉体不是寄主岩石深熔作用的产物,而更有可能来源于围岩变质表壳岩(如孔兹岩系)的部分熔融。深熔锆石LA-ICP-MSU-Pb定年结果表明,四十个相同性质锆石微区记录了十分一致的207Pb/206Pb年龄,集中变化于1870±11Ma至1843±20Ma(2σ)之间,加权平均年龄为1859.6±2.2Ma(MSWD=0.74),应代表研究区早前寒武纪变质基底的深熔时代。该组年龄比研究区变质杂岩峰期高压麻粒岩相变质时代(1900～1866Ma)明显偏新,而与峰后近等温减压中-低压麻粒岩相退变质时代(1855～1830Ma)大致相当,表明研究区深熔作用与碰撞造山带构造"热"抬升减压过程存在密切的成因关系。区域强烈的深熔事件是导致高压麻粒岩相岩石发生明显退变的主要控制因素之一。