A Study on Sulfate Optical Properties and Direct Radiative Forcing Using LASG-IAP General Circulation Model

The direct radiative forcing(DRF) of sulfate aerosols depends highly on the atmospheric sulfate loading and the meteorology,both of which undergo strong regional and seasonal variations.Because the optical properties of sulfate aerosols are also sensitive to atmospheric relative humidity,in this study we first examine the scheme for optical properties that considers hydroscopic growth.Next,we investigate the seasonal and regional distributions of sulfate DRF using the sulfate loading simulated from NCAR CAM-Chem together with the meteorology modeled from a spectral atmospheric general circulation model(AGCM) developed by LASG-IAP.The global annual-mean sulfate loading of 3.44 mg m 2 is calculated to yield the DRF of 1.03 and 0.57 W m 2 for clear-sky and all-sky conditions,respectively.However,much larger values occur on regional bases.For example,the maximum all-sky sulfate DRF over Europe,East Asia,and North America can be up to 4.0 W m 2.The strongest all-sky sulfate DRF occurs in the Northern Hemispheric July,with a hemispheric average of 1.26 W m 2.The study results also indicate that the regional DRF are strongly affected by cloud and relative humidity,which vary considerably among the regions during different seasons.This certainly raises the issue that the biases in model-simulated regional meteorology can introduce biases into the sulfate DRF.Hence,the model processes associated with atmospheric humidity and cloud physics should be modified in great depth to improve the simulations of the LASG-IAP AGCM and to reduce the uncertainty of sulfate direct effects on global and regional climate in these simulations.     

Biological Processes Responsible for Travertine Deposition: A Review and Future Prospect

The investigation of biological processes responsible for travertine deposition allows us to better understand the travertine petrographic and geochemical signatures as proxies of climatic and environmental change. This paper reviewed the organisms associated with travertines, the biotic micro-fabrics formed within travertines, the biological processes associated with travertine precipitation and their controls on travertine geochemical properties. Prospects of the future research on biological processes responsible for travertine precipitation were provided. Bacteria, algae and mosses are the most important organisms that involve in the precipitation of travertines. The growth of these organisms leads to the formation of a range of various porosity, crystal fabrics and lamination within travertines. Three main biological processes responsible for travertine deposition can be classified, including \mathrm{①} a process of aquatic plant growth generating a turbulent condition and consequent CO₂ evasion, \mathrm{②} a metabolic (mainly photosynthetic) process mediating carbonate precipitation and \mathrm{③} a ‘surface-control’ process influencing nucleation and crystal growth. These processes play an important role in the migration and transformation of elements in travertine-depositing system and thus determine the properties of water chemistry and geochemistry of carbonate deposits. Travertine deposits have great potential to be valuable records for the geobiological study. Further investigation is required to simultaneously track biotic and abiotic interactions in modern travertine-depositing environments and quantify the contribution of these two processes and apply the results to accurately interpret travertine records.     

河南省主要城市浅层地温能特征及开发利用建议

河南省浅层地温能资源具有分布广泛、资源量丰富、开发利用方便等特点,发展前景广阔。通过对河南省主要城市的地质、水文地质条件和岩土体结构特征等浅层地温能赋存特征的分析,采用数理统计和对比分析等综合研究的方法,对比研究了不同地貌类型城市200m以浅的岩土体热物性特征、浅层地温场分布特征和岩土热响应特征等的异同及其分布与变化规律。结果显示:河南省主要城市浅层地温能的赋存层位主要为第四系及新近系上部的各类松散堆积物,这些松散的堆积物和储存于其孔隙内的地下水为浅层地温能的载体;岩土导热系数会随着孔隙率的增加而减小,随岩性颗粒变粗而增大;城市地层综合导热系数和换热能力与地下水径流条件呈正相关;位于盆地和山前地带水文地质条件优越的城市或地段,浅层地温能开发利用宜采用地下水换热方式,松散堆积物厚度较大且以细粒相沉积为主的城市或地段,宜采用竖直地埋管换热方式。     

Effect of saltwater intrusion on groundwater environment in Weihe River downstream,Shandong Province,China

Based on the geological and hydrogeological conditions along with dynamic changes of groundwater level,this paper analyzes the hydrodynamic characteristics of saltwater intrusion in the study area.According to monitoring data of groundwater quality,the distribution characteristics of macro component are analyzed,and then fuzzy comprehensive evaluation method is adopted to evaluate the impact of saltwater intrusion on groundwater environment.Concerning the influence degree of groundwater environment,the study area is divided into brine area,seriously influenced area,moderately influenced zone,slightly influenced zone and uninfluenced zone.The results can offer references for prevention and control of saltwater intrusion as well as the protection of water resources.     

秋免耕对坝上地区农田风蚀及土壤理化性质的影响

秋免耕是中国北方风蚀区农田保护性耕作的主要措施,对土壤风蚀的抑制作用已得到普遍验证,但对土壤性质的影响还缺乏足够认识,是否具有保墒作用还存在争议.以地处北方农牧交错带的河北坝上地区康保县作为典型研究区,采用野外调查取样和室内实验分析手段,通过比较秋免耕地与邻近秋翻耕地风蚀前后表层土壤理化性质变化的差异,研究秋免耕对土壤...     

四硼酸铯溶液的Raman光谱和物化性质研究

由摩尔比为1∶2的Cs2CO3和H3BO3反应得到四硼酸铯样品,用FT-IR和Raman等方法对其溶液结构进行表征并分析其中的阴离子类型。同时测定了四硼酸铯溶液在298.15 K和333.15 K下的密度、电导及p H,通过298.15 K下的pH测量值和相关硼酸盐平衡常数,计算298.15 K下四硼酸铯溶液的化学物种分布,并对其相互转换反应进行推测。研究表明,298.15 K下四硼酸铯溶液中存在的主要物种有B(OH)4-、B(OH)3、B3O3(OH)4-、B3O3(OH)52-和B4O5(OH)42-,与Raman光谱所得结果基本一致。     

Thermodynamic mixing properties of olivine derived from lattice vibrations

We use a lattice vibrational technique to derive thermophysical and thermochemical properties of fayalite, Fe₂SiO₄. This semi-empirical technique is based on an extension of Kieffer’s model to incorporate details of the phonon spectrum. It includes treatment of intrinsic anharmonicity and electronic effects based on crystal field theory. We extend it to predict thermodynamic mixing properties of olivine (Mg,Fe)₂SiO₄ solid solutions by using results of our previous work on the system MgO–SiO₂. Achieving this requires a relation between phonon frequency and composition and a composition relation for the energy of the static lattice. Directed by experimental Raman spectroscopic data for specific optic modes in magnesium–iron solid solutions of olivine and pyroxene we use an empirical relation for the composition dependence for phonon frequencies. We show that lattice vibrations have a large effect on the excess entropy and that the static lattice contribution and lattice vibrations have a large impact on excess enthalpy and excess Gibbs energy. Our model indicates that compositional effects in electronic and magnetic properties are negligible. The compositional variation the Néel temperature has a large impact on excess heat capacity for temperatures below 100 K.     

锥形形状记忆合金阻尼器性能分析与试验研究

本文对一种新型形状记忆合金阻尼器——锥形形状记忆合金阻尼器的性能进行了数值分析和试验研究。基于形状记忆合金的超弹性双线型本构模型,利用非线性有限元方法分析了锥形形状记忆合金阻尼器的滞回性能,并且用大型能用程序ANSYS进行了验证,得出锥形形状记忆合金阻尼器的滞回模型可简化为分段线性滞回模型,试验包括形状记忆合金丝的本构试验、疲劳试验阳阻尼器的性能试验．试验结果与数值分析结果基本吻合,形状记忆合金表现出良好的超弹性。     

高温冻结粉土力学特性试验研究

为了探讨高温冻结粉土的力学特性,进行了一系列常规三轴压缩和三轴压缩加卸载试验。结果表明：（1）随着围压的增大,应力应变曲线先表现为应变软化,后应变硬化,最后又应变软化。（2）体积应变曲线均表现为先体缩后体胀,且围压越大,体胀越弱。（3）通过引入改进的双曲线模型,能较好地模拟应变软化和硬化特性。在q-p平面内建立了一个新的强度准则,并利用修正Mohr-Coulomb屈服准则,探讨了黏聚力c和内摩擦角φ的变化规律。根据试验结果,确定了不同围压及不同加卸载循环次数下高温冻结粉土的回弹模量及其损伤变化规律。最后,建立了塑性体积变形和塑性剪切变形之间的关系式和表达式,进一步探讨了高温冻结粉土的剪胀特性。     

微生物矿化作用改善岩土材料性能的影响因素

基于微生物诱导碳酸钙沉淀作用（MICP）的土体改性技术近年来在岩土工程领域引起了人们的广泛关注。该技术在改善岩土材料的强度、刚度、抗液化、抗侵蚀及抗渗透性等性能的同时,还能维持土体良好的透气性和透水性,改善植物的生长环境。由于微生物矿化作用涉及一系列生物化学和离子化学反应,固化过程中的反应步骤较多,因此,MICP固化效果受许多因素的制约与影响。基于大量文献资料,系统总结了细菌种类、菌液浓度、温度、pH值、胶结液配比及土的性质等关键因素对微生物改善岩土材料性能的影响,讨论了这些影响因素的优化方式和未来的研究方向,主要得到了以下几点结论：菌种类型、菌液浓度、温度、pH、胶结液性质会从微观上影响碳酸钙的晶体类型、形貌和尺寸,进而在宏观层面影响岩土体的胶结效果;菌液浓度尽可能高、温度在20～40℃间、pH值在7.0～9.5左右、胶结液浓度在1 mol/L以内的因素条件对微生物加固岩土体具有较好的效果。上述范围内的低温、较高的pH值、低浓度胶结液有助于提高土体的抗渗性,而高温、较低的pH值以及中高浓度胶结液有助于提高土体的强度;MICP加固土体的有效粒径范围为10～1 000 ?m,相对密度越大、级配越好则加固效果越好。分步灌浆法、多浓度相灌注法及电渗灌浆法有助于提高土体固化均匀性,0.042 (mol/L)/h以下的注浆速度有利于提高胶结液利用率,砂土试样的灌浆压力一般在10～30 kPa之间,粉黏土试样的灌浆压力不宜超过110 kPa,过高的灌浆压力会破坏土体结构,降低固化效果。