Synchrotron X-ray powder diffraction study of natural P2 /n-omphacites at high-pressure conditions

 Synchrotron X-ray powder diffraction experiments at high pressure conditions (0.0001–13 GPa) were performed at ESRF (Grenoble-F), on the beamline ID9, to investigate the bulk elastic properties of natural P2/n-omphacites, with quasi-ideal composition. The monoclinic cell parameters a, b, c and β were determined as a function of pressure, and their compressibility coefficients are 0.00277(7), 0.00313(8), 0.00292(5) and 0.00116(4) GPa⁻¹, respectively. The third-order Birch-Murnaghan equation of state was used to interpolate the experimental P−V data, obtaining K ₀=116.6(±2.5) GPa and K′₀=6.03(±0.60). K ₀ was also determined by means of the axial and angular compressibilities [122.5(±1.7) GPa], and of the finite Lagrangian strain theory [121.5(±1.0) GPa]. The discrepancies on K ₀ are discussed in the light of a comparison between techniques to determine the bulk modulus of crystalline materials from static compression diffraction data. Received: 22 February 2000 / Accepted: 10 July 2000     

Application of the photoacoustic method for characterization of natural galena (PbS)

Electron transport properties of single crystal and polycrystalline natural mineral galena (PbS) samples from the Trep?a mine, Yugoslavia, were determined using the photoacoustic frequency transmission technique. Their thermal diffusivity (D _T≈0.16 × 10^?5 m² s^?1), the coefficient of diffusion (D between 0.15×10^?2 0.16×10^?2 m² s^?1) and lifetime of the excess carrier (τ≈35 μs and the front and rear recombination velocity (s _g≈65.5 m s^?1 and s _b≈66.4 m s^?1, respectively), were calculated by comparing the experimental results and the theoretical photoacoustic amplitude and phase signals. The lattice parameter obtained by X-ray work was a?=5.936?Å. The free carrier concentration of these single-crystal samples was measured using the Hall method (N?=?3×10¹⁸ cm^?3). Measurements of the optical reflectivity of the same samples, as a function of wavelength, in the infrared and far infrared ranges, were performed. In the far infrared range a free electron plasma frequency was observed and numerically analyzed, using the least-squares fitting procedure. The values of optical parameters were calculated and the value of the free carrier concentration obtained by the Hall method was confirmed.     

Soil Loss by Wind Erosion for Three Different Textured Soils Treated with Polyacrylamide and Crude Oil, Iraq

ＩＮＴＲＯＤＵＣＴＩＯＮＬａｒｇｅａｒｅａｓｏｆａｒｉｄａｎｄｓｅｍｉａｒｉｄｒｅｇｉｏｎｓｏｆｔｈｅｗｏｒｌｄａｒｅａｆ ｆｅｃｔｅｄｂｙｗｉｎｄｅｒｏｓｉｏｎ .Ａｐｐｒｏｘｉｍａｔｅｌｙ 2 8.4%ｏｆｔｈｉｓａｒｅａａｒｅａｆｆｅｃｔｅｄｂｙｓｅｖｅｒｅａｎｄｖｅｒｙｓｅｖｅｒｅｗｉｎｄｅｒｏｓｉｏｎ (Ｋａｔｅｓｅｔａｌ.,1977) .ＩｎＩｒａｑ ,ｔｈｅａｒｉｄａｎｄｓｅｍｉａｒｉｄｒｅｇｉｏｎｓｒｅｐｒｅｓｅｎｔｎｅａｒｌｙ 75%ｏｆｔｈｅｔｏｔａｌｌａｎｄ .5 0 %ｏｆｔｈｉｓｌａｎｄｉｓｓｕｂｊｅｃ…     

From surface electrical properties to spontaneous potentials in porous media

This paper deals with the electrical double layer and the related properties of porous media. In particular, the electrical conductivity, the streaming potential, and the membrane potential are described in a self-consistent set of equations. All these properties are shown to be governed by fluid-matrix interface properties, as well as four geometrical parameters.     

The manufacture of a three-dimensional transducer used in laboratory

Ｔｈｅｍａｎｕｆａｃｔｕｒｅｏｆａｔｈｒｅｅ－ｄｉｍｅｎｓｉｏｎａｌｔｒａｎｓｄｕｃｅｒｕｓｅｄｉｎｌａｂｏｒａｔｏｒｙＸＩＡＯ－ＨＯＮＧＬＩＵ（刘晓红）（ＩｎｓｔｉｔｕｔｅｏｆＧｅｏｐｈｙｓｉｃｓ，ＳｔａｔｅＳｅｉｓｍｏｌｏｇｉｃａｌＢｕｒｅａｕ，...     

EXTRACTION OF THE STANDARD ENTHALPY OF FORMATION OF MINERALS FROM REVERSED EXPERIMENTAL DATA WITH INS

An improvement on the new method of Intervalhalving-Scanning (INS) proposed by the senior author for derivation of thermodynamic properties of minerals from reversed experiment (REP) data has been made in the present work. The treatment of the REP data of 6 reactions in the system MgO-SiO_2-H_2O and the derivation of △_(?)H(?) (298. 15K) for minerals Talc,Forsterite and Anthophyllite are chosen as an example for demonstration of the application of the method.INS is quite different from all the methods for the derivation in the literature and throughout based on thermodynamic principles and equations so that its thermodynamical validity is thoroughgoing.     

An engineering geological appraisal of the sandstones of the Clarens Formation,Lesotho, in relation to tunnelling

Summary The Delivery Tunnel South forms part of a system of tunnels for conveying water from Lesotho to South Africa. The tunnel was excavated primarily by tunnel boring machine in the sandstones of the Clarens Formation. These sandstones are uniformly graded and fine grained with quartz being the most abundant mineral. They are mostly of aeolian origin. Their unconfined compressive strength varies appreciably, from moderately strong to extremely strong. The boreability of the sandstones was investigated by the Norwegian Institute of Technology tests and the total hardness. These tests showed that these sandstones would be relatively easy to bore, although moderately abrasive. The prediction proved correct. In fact, excavation of the tunnel was completed 20 months ahead of schedule, the rock conditions being better than expected. The long-term durability of these sandstones was investigated to establish criteria for concrete lining of the tunnel. A series of tests were undertaken to evaluate the durability. These included a number of soaking tests using different fluid media, wet and dry testing, erosion tests and brushing tests. This testing programme suggested that concrete lining of the intact sandstone was probably only required where the strength of the sandstone was less than 20 MPa and that therefore only a small percentage of the tunnel need be lined.     

Is the ocean floor a fractal?

The topographic structure of the ocean bottom is investigated at different scales of resolution to answer the question: Can the seafloor be described as a fractal process? Methods from geostatistics, the theory of regionalized variables, are used to analyze the spatial structure of the ocean floor at different scales of resolution. The key to the analysis is the variogram criterion: Self-similarity of a stochastic process implies self-similarity of its variogram. The criterion is derived and proved here: it also is valid for special cases of self-affinity (in a sense adequate for topography). It has been proposed that seafloor topography can be simulated as a fractal (an object of Hausdorff dimension strictly larger than its topological dimension), having scaling properties (self-similarity or self-affinity). The objective of this study is to compare the implications of these concepts with observations of the seafloor. The analyses are based on SEABEAM bathymetric data from the East Pacific Rise at 13°N/104°W and at 9°N/104°W and use tracks that run both across the ridge crest and along the ridge flank. In the geostatistical evaluation, the data are considered as a stochastic process. The spatial continuity of this process is described by variograms that are calculated for different scales and directions. Applications of the variogram criterion to scale-dependent variogram models yields the following results: Although the seafloor may be a fractal in the sense of the definition involving the Hausdorff dimension, it is not self-similar, nor self-affine (in the given sense). Mathematical models of scale-dependent spatial structures are presented, and their relationship to geologic processes such as ridge evolution, crust formation, and sedimentation is discussed.     

三相泡沫钻井液流变特性研究

三相泡沫钻进液流变模式可通过灰色关联分析法进行优选，卡森模式是描述该钻井液流变特性的主要模式，该钻井液表观粘度高，工应力较大，剪切稀释特性强，流变参数主要受气比和基浆性能影响。     

Effects of groundwater flow on mineral diagenesis, with emphasis on carbonate aquifers

 This article provides a critical synopsis of the effects of groundwater flow on mineral diagenesis. Emphasis is placed on those aspects and processes that change porosity and permeability in carbonate aquifers, because they are of particular importance to human societies as sources of supplies of water for human consumption (drinking, irrigation) and of crude oil and natural gas. Diagenetic settings in carbonates as well as clastics are generally ill defined. This paper proposes a new comprehensive classification of diagenetic settings into near-surface, shallow-, intermediate-, and deep-burial diagenetic settings; hydrocarbon-contaminated plumes; and fractures. These settings are defined on the basis of mineralogy, petroleum, hydrogeochemistry, and hydrogeology. This classification is applicable to all sedimentary basins. Diagenesis is governed by various intrinsic and extrinsic factors that include thermodynamic and kinetic constraints, as well as microstructural factors that may override the others. These factors govern diagenetic processes, such as dissolution, compaction, recrystallization, replacement, and sulfate–hydrocarbon redox-reactions. Processes such as cementation, dissolution, and dolomitization require significant flow of groundwater driven by an externally imposed hydraulic gradient. Other processes, such as stylolitization and thermochemical sulfate reduction, commonly take place without significant groundwater flow in hydrologically nearly or completely stagnant systems that are geochemically "closed." Two major effects of groundwater flow on mineral diagenesis are enhancement and reduction of porosity and permeability, although groundwater flow can also leave these rock properties essentially unchanged. In extreme cases, an aquifer or hydrocarbon reservoir rock can have highly enhanced porosity and permeability due to extensive mineral dissolution, or it can be plugged up due to extensive mineral precipitation. Received, April 1998 · Revised, July 1998 · Accepted, September 1998