柴北缘鱼卡河榴辉岩围岩的变质时代及其地质意义

利用阴极发光和LA-ICP-MS原位分析方法,对柴北缘鱼卡河超高压榴辉岩的直接围岩——石榴石白云母角闪钠长片麻岩和含蓝晶石的石榴石云母片岩进行了详细的锆石微量元素和U-Th-Pb同位素分析。结果表明,石榴石白云母角闪钠长片麻岩中的锆石主体呈浑圆状形态,内部结构以扇状和冷杉树状为主,稀土总量和重稀土含量均较低,重稀土富集程度低,具明显正Eu异常,Th/U比值均小于0.1,指示其形成在与石榴石平衡共生而不含斜长石的变质条件下。而含蓝晶石的石榴石云母片岩中的锆石显示明显的核-边结构,核部显示碎屑锆石特征,边部为与石榴石共生的变质新生锆石。LA-ICP-MS原位定年获得两种围岩的峰期变质年龄分别为(431±3)Ma和(432±19)Ma。这两组年龄在误差范围内一致,而且与已获得的紧邻的两类超高压榴辉岩的变质年龄((436±3)Ma和(431±4)Ma)以及带内指示大陆深俯冲作用时代的都兰含柯石英副片麻岩锆石的柯石英微区年龄(424~432Ma)完全一致。参考这两类岩石与超高压榴辉岩的野外产状关系、含蓝晶石的石榴石云母片岩的原岩特征以及榴辉岩中超过变质年龄达300Ma的原岩残核的存在,共同表明,柴北缘鱼卡河超高压变质地体是典型的大陆深俯冲碰撞作用的产物,本区大陆深俯冲发生的时代为430~435Ma的早古生代。     

2014年夏季长江流域持续性低温的大尺度环流异常

采用中国地面站气温逐日观测资料、NOAA全球逐日海表温度资料,及NCEP/NCAR的全球日均再分析资料,研究了2014年持续性低温的三维结构及大尺度环流异常。结果表明,2014年的低温异常,除了在陆地上区域性地出现在长江流域,还以大尺度带状的形式、从陆地延伸到海洋上。这种带状异常不只出现在近地面,在大气各层（925～500 hPa）都能看到。分析指出,大气中的这个低温带主要由高纬大气环流异常造成。在位势高度场上,最重要的异常出现在高纬60°N,有呈带状的位势高度正距平,它引导（距平意义上的）偏北气流从正北和东北偏东方向侵入,在其南侧形成一带状的偏低温区。大气各层均呈现出这种在高纬有位势高度正距平、相应地在稍南的低纬（40°N）有位势高度负距平、两者之间为低温区的分布特征。从低层往上,这种配置型式整体表现出由南往北的倾斜,其垂直剖面表现为距平意义上的、大尺度、类似于锋面的倾斜结构。文中用简单的概念模型对此进行理解,认为这种结构是由大气动力异常和热力异常相互影响、共同作用而形成的。     

Metamorphism of ultrahigh‐pressure eclogites from the Kebuerte Valley,South Tianshan,NW China: phase equilibria and P–T path

Eclogites from the Kebuerte Valley, Chinese South Tianshan, consist of garnet, omphacite, phengite, paragonite, glaucophane, hornblendic amphibole, epidote, quartz and accessory rutile, titanite, apatite and carbonate minerals with occasional presence of coesite or quartz pseudomorphs after coesite. The eclogites are grouped into two: type I contains porphyroblastic garnet, epidote, paragonite and glaucophane in a matrix dominated by omphacite where the proportion of omphacite and garnet is >50 vol.%; and type II contains porphyroblastic epidote in a matrix consisting mainly of fine‐grained garnet, omphacite and glaucophane where the proportion of omphacite and garnet is <50 vol.%. Garnet in both types of eclogites mostly exhibits core–rim zoning with increasing grossular (X_gr) and pyrope (X_py) contents, but a few porphyroblastic garnet grains in type I eclogite shows core–mantle zoning with increasing X_py and a slight decrease in X_gr, and mantle–rim zoning with increases in both X_gr and X_py. Garnet rims in type I eclogite have higher X_py than in type II. Petrographic observations and phase equilibria modelling with pseudosections calculated using thermocalc in the NCKMnFMASHO system for three representative samples suggest that the eclogites have experienced four stages of metamorphism: stage I is the pre‐peak temperature prograde heating to the pressure peak (P_max) which was recognized by the garnet core–mantle zoning with increasing X_py and decreasing X_gr. The P–T conditions at P_max constrained from garnet mantle or core compositions with minimum X_gr content are 29–30 kbar at 526–540 °C for type I and 28.2 kbar at 518 °C for type II, suggesting an apparent thermal gradient of ～5.5 °C km^?1. Stage II is the post‐P_max decompression and heating to the temperature peak (T_max), which was modelled from the garnet zoning with increasing X_gr and X_py contents. The P–T conditions at T_max, defined using the garnet rim compositions with maximum X_py content and the Si content in phengite, are 24–27 kbar at 590 °C for type I and 22 kbar at 540 °C for type II. Stage III is the post‐T_max isothermal decompression characterized by the decomposition of lawsonite, which may have resulted in the release of a large amount of fluid bound in the rocks, leading to the formation of epidote, paragonite and glaucophane porphyroblasts. Stage IV is the late retrograde evolution characterized by the overprint of hornblendic amphibole in eclogite and the occurrence of epidote–amphibole facies mineral assemblages in the margins or in the strongly foliated domains of eclogite blocks due to fluid infiltration. The P–T estimates obtained from conventional garnet–clinopyroxene–phengite thermobarometry for the Tianshan eclogites are roughly consistent with the P–T conditions of stage II at T_max, but with large uncertainties in temperature. On the basis of these metamorphic stages or P–T paths, we reinterpreted that the recently reported zircon U–Pb ages for eclogite may date the T_max stage or the later decompression stage, and the widely distributed (rutile‐bearing) quartz veins in the eclogite terrane may have originated from the lawsonite decomposition during the decompression stage rather than from the transition from blueschist to eclogite as previously proposed.     

A tectonic model for the metamorphic evolution of the Basal Gneiss Complex, Western South Norway

A review of currently available information relevant to the Basal Gneiss Complex (BGC) of Western South Norway, combined with the authors'own observations, leads to the following conclusions.
1. Most of the BGC consists of Proterozoic crystalline rocks and probably subordinate Lower Palaeozoic cover.
2. The last major deformation of these rocks was during the Caledonian orogeny and involved large-scale thrusting, recumbent folding and doming. The structural development of the BGC is closely tied in with that of the Caledonian allochthon.
3. The whole eclogite-bearing part of the BGC has suffered a high pressure metamorphism with conditions of between 550°C, 12.5 kbar (Sunnfjord) and about 750°C, 20 kbar (Møre og Romsdal) at the metamorphic climax.
4. This metamorphism was of Caledonian age, probably rather early in the Caledonian tectonic history of the BGC and is considered to have been a rather transient event.
By setting these conclusions in a framework provided by geophysical evidence for the deep structure of the crust in southern Norway we have constructed a geotectonic model to explain the recorded metamorphic history of the BGC. It is suggested that considerable crustal thickening was caused by imbrication of the Baltic plate margin during continental collision with the Greenland plate. This resulted in high pressure metamorphism in the resulting nappe stack. Progradation of the suture caused underthrusting of the Baltic foreland below the eclogite-bearing terrain causing it to emerge at the Earth's surface, aided by tectonic stripping and erosion.
Application of isostacy equations to the model shows that eclogites can be formed by in-situ metamorphism in crustal rocks and reappear at the land surface above a normal thickness of crust in a single orogenic episode of approximately 65-70 Ma duration.     

Geodynamics of the Early Precambrian,Part 1: Volcanism and associated mantle processes

The work is dedicated to most important abiotic processes of the Early Precambrian, effect of which is recorded in continental crust, and to complementary processes in subcontinental mantle. We intend to figure out when a certain process was triggered first in the past and what indications suggest its further activity, evolution and possible cessation in subsequent geological history. Considerations are based on described natural objects characterizing particular geological events and enabling the cause-and-effect interpretation in order to understand different viewpoints known from publications. Considered in the work are the early Precambrian greenstone belts and ophiolites, island-arc systems and ecologites, magmatism unconnected with subduction zones (rifting-related, plateau basalts, dykes, kimberlites) and anorthosites representing a group of heterochronous intrusions of complicated genesis. Main considerations are premised with a brief review of the earliest geodynamic phenomena associated with meteorite impacts by termination of the planetary accretion.     

Very low-grade metamorphic study in the pre-Late Cretaceous terranes of New Caledonia (southwest Pacific Ocean)

Abstract   Pre-Late Cretaceous terranes from the central part of New Caledonia have been metamorphosed under very low-grade conditions by two high-pressure/low-temperature events. The present study investigates the metamorphic patterns with phyllosilicate crystallinities, electron microprobe analyses and petrography. The first metamorphic event is of Late Jurassic age and is characterized by very low (anchizone) to low-grade (epizone) conditions with a decrease of the illite Kübler Index (KI) and the chlorite Árkai Index (ÁI) values from northeast to southwest. This trend is also confirmed by chlorite thermometry. In the south of the area, un-metamorphosed sediments (diagenetic KI values) are observed in the Senonian 'formation à charbons', post-dating the metamorphism in this region. The second metamorphism is an Eocene high-pressure event, which overprints the Late Jurassic metamorphism in the northern part of the studied area. In this zone, the pattern of KI and ÁI indicates another gradient with increasing metamorphic conditions from southwest to northeast. Temperatures calculated by chlorite thermometry also indicate an evolution from southwest to northeast with slight increase of temperature from 298 ± 8°C to 327 ± 16°C. In both metamorphic zones, the K-white mica b cell dimension calculated on micas analyzed at electron microprobe are in good agreement with high-pressure/low-temperature metamorphic conditions (b₀ > 9.04 Å). A combination of chlorite thermometry and K-white mica b cell dimension allows estimation of a minimum pressure of 1.3 GPa in the Eocene zone (in excellent agreement with the 1.5 GPa registered in the northern part of New Caledonia) and a minimum of 1.1 GPa in the Late Jurassic metamorphic part.     

Geodynamic significance of ophiolites within the Calabrian Arc

Abstract Slices of oceanic lithosphere belonging to the neo‐Tethys realm crop out discontinuously in the northern Calabrian Arc, Southern Apennines. They consist of high‐pressure–low‐temperature metamorphic ophiolitic sequences formed from metaultramafics, metabasites and alternating metapelites, metarenites, marbles and calcschist. Ophiolites occupy an intermediate position in the northern Calabrian Arc nappe pile, situated between overlying Hercynian continental crust and the underlying Apenninic limestone units. In the literature, these ophiolitic sequences are subdivided into several tectonometamorphic units. Geochemical characteristics indicate that metabasites were derived from subalkaline basalts with tholeiitic affinity (transitional mid‐oceanic ridge basalt type), and a harzburgitic‐lherzolitic protolith is suggested for the serpentinites. The pressure–temperature‐deformation paths of the metabasites from different outcrops display similar features: (i) the prograde segment follows a typical Alpine geothermal gradient up to a metamorphic climax at 350°C and 0.9 GPa and crystallization of the high‐pressure mineral assemblage occurs along a pervasive foliation developed during a compressive tectonic event; and (ii) the retrogression path can be subdivided in two segments, the first is characterized by nearly isothermal decompression to approximately 400°C and 0.3 GPa and the second follows a cooling trajectory. During low‐pressure conditions, a second deformation event produces millimetric to decametric scale asymmetric folds that describe west‐verging major structures. The third deformation event is characterized by brittle extensional structures. The tectonometamorphic evolution of the ophiolitic sequences from the different outcrops is similar. Both thermobarometric modeling and tectonic history indicate that the studied rocks underwent Alpine subduction and exhumation processes as tectonic slices inside a west‐verging accretionary wedge. The subduction of oceanic lithosphere was towards the present east; therefore, the Hercynian continental crust, overthrusted on the ophiolitic accretionary wedge after the neo‐Tethys closure, was part of the African paleomargin or a continental microplate between Africa and Europe.     

贵州大方煤田主采煤层的矿物学异常及其对元素地球化学的影响

运用电感耦合等离子体质谱(ICP-MS)、X射线荧光光谱(XRF)、带能谱仪的扫描电镜(SEM-EDX)、逐级化学提取(SCEP)和光学显微镜等方法,对贵州大方煤田11号煤层的地球化学和矿物学进行了研究。结果表明,大方煤田11号煤层中有高含量的脉状石英(11.4%)和脉状铁白云石(10.2%),铁白云石周边常被针铁矿所包裹,在脉状石英中发现有热液成因的黄铜矿、闪锌矿和硒方铅矿,此外,还有少量高岭石充填在脉中,这7种矿物常常同脉共存。脉状石英和脉状铁白云石分别来源于硅质和富铁的钙质低温热液流体,形成温度分别为180℃和85℃。脉状石英早于脉状铁白云石形成。根据Ca/Sr和Fe/Mn值,确定出铁白云石的形成至少经历了3个时期。这7种矿物按照从早到晚的生成顺序为硫化物、石英、高岭石、铁白云石和针铁矿。铁白云石是煤中Mn、Cu、Ni、Pb和Zn富集的主要原因,这5种微量元素的含量分别为0.09%、74.0μg/g、33.6μg/g、185μg/g和289μg/g。脉状石英是煤中铂族元素Pd、Pt和Ir的主要载体,它们在煤中的含量分别为1.57μg/g、0.15μg/g和0.007μg/g。另外,黄铜矿、闪锌矿和硒方铅矿亦是11号煤层中Cu、Zn和Pb的重要载体。     

北祁连俯冲-增生杂岩带中低温榴辉岩的地球化学特征

北祁连俯冲-增生杂岩带中的低温榴辉岩以透镜体形式产于蓝片岩和多硅白云母片岩中。根据稀土元素、微量元素及Sr-Nd同位素分析研究,可将本区低温榴辉岩分为两类:Ⅰ类榴辉岩以轻重稀土分异不明显和具有Eu正异常为特征;Ⅱ类榴辉岩的轻稀土富集,有轻微的Eu负异常。Sm-Nd同位素研究显示,I类榴辉岩样品的εNd(t)值为2.5~6.9,平均值为4.5;Ⅱ类榴辉岩εNd(t)=-3.3~1.4。这些研究成果表明,Ⅰ类榴辉岩的原岩来源于长期亏损的地幔源区,可能形成于大洋环境;而Ⅱ类榴辉岩的原岩在形成过程中很明显混入了陆壳物质,据此推断其原岩形成于大陆边缘或洋陆过渡环境。