微型近红外光谱仪测量北极积雪覆盖海冰内部太阳辐照度可行性研究

The extremely low temperature, high humidity and limited power supply pose considerable challenges when using spectrometers within the Arctic sea ice. The feasibility of using a miniature low-power near-infrared spectrometer module to measure solar radiation in Arctic sea ice environments was investigated in this study.Temperature and integration time dependences of the spectrometer module were examined over the entire target operating range of –50℃ to 30℃, well below the specified operating range of this spectrometer. Using these observations, a dark output prediction model was developed to represent dark output as a function of temperature and integration time. Temperature-induced biases in the saturation output and linear operating range of the spectrometer were also determined. Temperature and integration time dependences of the signal output were evaluated. Two signal output correction models were developed and compared, to convert the signal output at any temperature within the operating temperature range and integration time to that measured at the reference temperature and integration time. The overall performance of the spectrometer was evaluated by integrating it into a refined fiber optic spectrometry system and measuring solar irradiance distribution in the ice cover with thickness of 1.85 m in the Arctic during the 9th Chinese National Arctic Research Expedition. The general shape of the measured solar irradiance above the snow surface agreed well with that measured by other commercial oceanographic spectroradiometers. The measured optical properties of the sea ice were generally comparable to those of similar ice measured using other instruments. This approach provides a general framework for assessing the feasibility of using spectrometers for applications in cold environments.     

Antiangiogenic activity of low-temperature lysozyme from a marine bacterium <Emphasis Type="Italic">in vivo</Emphasis> and <Emphasis Type="Italic">in vitro</Emphasis>

We extracted marine low-temperature lysozyme (MLTL), a novel lysozyme, from a marine microorganism through fermentation. Our previous study suggested that a low molecular weight (16 kDa) may exert anti-tumor activity through antiangiogenesis. In this study, we extracted a high weight (39 kDa) and investigated its antiangiogenic activity in vivo and in vitro. Using zebrafish embryos as an in vivo study model, we found that treatment with MLTL significantly inhibited the growth of subintestinal vessels (SIVs) in a dose-dependent manner and that 400 μg/ml MLTL was sufficient to block the growth of SIVs. An in vitro study conducted using human umbilical vein endothelial cells (HUVECs) revealed that MLTL suppressed the proliferation, migration and tube formation of HUVECs in a dose-dependent manner. Interestingly, assays by flow cytometry and DNA electrophoresis indicated that MLTL was able to induce apoptosis of HUVECs. Moreover, further study demonstrated that the disruption of intracellular Ca²⁺ homeostasis may play an important role in MLTL induced apoptosis of HUVECs. Taken together, the results of this study demonstrate for the first time that MLTL inhibits angiogenesis through its pleiotropic effects on vascular endothelial cells and induces apoptosis through regulation of cellular Ca²⁺ levels. The results of this study also revealed a possible mechanism underlying the antiangiogenic effect of MLTL and suggested that MLTL may be a promising new antiangiogenic agent for use in cancer therapy.     

Metamorphism of ultrahigh‐pressure eclogites from the Kebuerte Valley,South Tianshan,NW China: phase equilibria and P–T path

Eclogites from the Kebuerte Valley, Chinese South Tianshan, consist of garnet, omphacite, phengite, paragonite, glaucophane, hornblendic amphibole, epidote, quartz and accessory rutile, titanite, apatite and carbonate minerals with occasional presence of coesite or quartz pseudomorphs after coesite. The eclogites are grouped into two: type I contains porphyroblastic garnet, epidote, paragonite and glaucophane in a matrix dominated by omphacite where the proportion of omphacite and garnet is >50 vol.%; and type II contains porphyroblastic epidote in a matrix consisting mainly of fine‐grained garnet, omphacite and glaucophane where the proportion of omphacite and garnet is <50 vol.%. Garnet in both types of eclogites mostly exhibits core–rim zoning with increasing grossular (X_gr) and pyrope (X_py) contents, but a few porphyroblastic garnet grains in type I eclogite shows core–mantle zoning with increasing X_py and a slight decrease in X_gr, and mantle–rim zoning with increases in both X_gr and X_py. Garnet rims in type I eclogite have higher X_py than in type II. Petrographic observations and phase equilibria modelling with pseudosections calculated using thermocalc in the NCKMnFMASHO system for three representative samples suggest that the eclogites have experienced four stages of metamorphism: stage I is the pre‐peak temperature prograde heating to the pressure peak (P_max) which was recognized by the garnet core–mantle zoning with increasing X_py and decreasing X_gr. The P–T conditions at P_max constrained from garnet mantle or core compositions with minimum X_gr content are 29–30 kbar at 526–540 °C for type I and 28.2 kbar at 518 °C for type II, suggesting an apparent thermal gradient of ～5.5 °C km^?1. Stage II is the post‐P_max decompression and heating to the temperature peak (T_max), which was modelled from the garnet zoning with increasing X_gr and X_py contents. The P–T conditions at T_max, defined using the garnet rim compositions with maximum X_py content and the Si content in phengite, are 24–27 kbar at 590 °C for type I and 22 kbar at 540 °C for type II. Stage III is the post‐T_max isothermal decompression characterized by the decomposition of lawsonite, which may have resulted in the release of a large amount of fluid bound in the rocks, leading to the formation of epidote, paragonite and glaucophane porphyroblasts. Stage IV is the late retrograde evolution characterized by the overprint of hornblendic amphibole in eclogite and the occurrence of epidote–amphibole facies mineral assemblages in the margins or in the strongly foliated domains of eclogite blocks due to fluid infiltration. The P–T estimates obtained from conventional garnet–clinopyroxene–phengite thermobarometry for the Tianshan eclogites are roughly consistent with the P–T conditions of stage II at T_max, but with large uncertainties in temperature. On the basis of these metamorphic stages or P–T paths, we reinterpreted that the recently reported zircon U–Pb ages for eclogite may date the T_max stage or the later decompression stage, and the widely distributed (rutile‐bearing) quartz veins in the eclogite terrane may have originated from the lawsonite decomposition during the decompression stage rather than from the transition from blueschist to eclogite as previously proposed.     

A tectonic model for the metamorphic evolution of the Basal Gneiss Complex, Western South Norway

A review of currently available information relevant to the Basal Gneiss Complex (BGC) of Western South Norway, combined with the authors'own observations, leads to the following conclusions.
1. Most of the BGC consists of Proterozoic crystalline rocks and probably subordinate Lower Palaeozoic cover.
2. The last major deformation of these rocks was during the Caledonian orogeny and involved large-scale thrusting, recumbent folding and doming. The structural development of the BGC is closely tied in with that of the Caledonian allochthon.
3. The whole eclogite-bearing part of the BGC has suffered a high pressure metamorphism with conditions of between 550°C, 12.5 kbar (Sunnfjord) and about 750°C, 20 kbar (Møre og Romsdal) at the metamorphic climax.
4. This metamorphism was of Caledonian age, probably rather early in the Caledonian tectonic history of the BGC and is considered to have been a rather transient event.
By setting these conclusions in a framework provided by geophysical evidence for the deep structure of the crust in southern Norway we have constructed a geotectonic model to explain the recorded metamorphic history of the BGC. It is suggested that considerable crustal thickening was caused by imbrication of the Baltic plate margin during continental collision with the Greenland plate. This resulted in high pressure metamorphism in the resulting nappe stack. Progradation of the suture caused underthrusting of the Baltic foreland below the eclogite-bearing terrain causing it to emerge at the Earth's surface, aided by tectonic stripping and erosion.
Application of isostacy equations to the model shows that eclogites can be formed by in-situ metamorphism in crustal rocks and reappear at the land surface above a normal thickness of crust in a single orogenic episode of approximately 65-70 Ma duration.     

Geodynamics of the Early Precambrian,Part 1: Volcanism and associated mantle processes

The work is dedicated to most important abiotic processes of the Early Precambrian, effect of which is recorded in continental crust, and to complementary processes in subcontinental mantle. We intend to figure out when a certain process was triggered first in the past and what indications suggest its further activity, evolution and possible cessation in subsequent geological history. Considerations are based on described natural objects characterizing particular geological events and enabling the cause-and-effect interpretation in order to understand different viewpoints known from publications. Considered in the work are the early Precambrian greenstone belts and ophiolites, island-arc systems and ecologites, magmatism unconnected with subduction zones (rifting-related, plateau basalts, dykes, kimberlites) and anorthosites representing a group of heterochronous intrusions of complicated genesis. Main considerations are premised with a brief review of the earliest geodynamic phenomena associated with meteorite impacts by termination of the planetary accretion.     

Very low-grade metamorphic study in the pre-Late Cretaceous terranes of New Caledonia (southwest Pacific Ocean)

Abstract   Pre-Late Cretaceous terranes from the central part of New Caledonia have been metamorphosed under very low-grade conditions by two high-pressure/low-temperature events. The present study investigates the metamorphic patterns with phyllosilicate crystallinities, electron microprobe analyses and petrography. The first metamorphic event is of Late Jurassic age and is characterized by very low (anchizone) to low-grade (epizone) conditions with a decrease of the illite Kübler Index (KI) and the chlorite Árkai Index (ÁI) values from northeast to southwest. This trend is also confirmed by chlorite thermometry. In the south of the area, un-metamorphosed sediments (diagenetic KI values) are observed in the Senonian 'formation à charbons', post-dating the metamorphism in this region. The second metamorphism is an Eocene high-pressure event, which overprints the Late Jurassic metamorphism in the northern part of the studied area. In this zone, the pattern of KI and ÁI indicates another gradient with increasing metamorphic conditions from southwest to northeast. Temperatures calculated by chlorite thermometry also indicate an evolution from southwest to northeast with slight increase of temperature from 298 ± 8°C to 327 ± 16°C. In both metamorphic zones, the K-white mica b cell dimension calculated on micas analyzed at electron microprobe are in good agreement with high-pressure/low-temperature metamorphic conditions (b₀ > 9.04 Å). A combination of chlorite thermometry and K-white mica b cell dimension allows estimation of a minimum pressure of 1.3 GPa in the Eocene zone (in excellent agreement with the 1.5 GPa registered in the northern part of New Caledonia) and a minimum of 1.1 GPa in the Late Jurassic metamorphic part.     

Geodynamic significance of ophiolites within the Calabrian Arc

Abstract Slices of oceanic lithosphere belonging to the neo‐Tethys realm crop out discontinuously in the northern Calabrian Arc, Southern Apennines. They consist of high‐pressure–low‐temperature metamorphic ophiolitic sequences formed from metaultramafics, metabasites and alternating metapelites, metarenites, marbles and calcschist. Ophiolites occupy an intermediate position in the northern Calabrian Arc nappe pile, situated between overlying Hercynian continental crust and the underlying Apenninic limestone units. In the literature, these ophiolitic sequences are subdivided into several tectonometamorphic units. Geochemical characteristics indicate that metabasites were derived from subalkaline basalts with tholeiitic affinity (transitional mid‐oceanic ridge basalt type), and a harzburgitic‐lherzolitic protolith is suggested for the serpentinites. The pressure–temperature‐deformation paths of the metabasites from different outcrops display similar features: (i) the prograde segment follows a typical Alpine geothermal gradient up to a metamorphic climax at 350°C and 0.9 GPa and crystallization of the high‐pressure mineral assemblage occurs along a pervasive foliation developed during a compressive tectonic event; and (ii) the retrogression path can be subdivided in two segments, the first is characterized by nearly isothermal decompression to approximately 400°C and 0.3 GPa and the second follows a cooling trajectory. During low‐pressure conditions, a second deformation event produces millimetric to decametric scale asymmetric folds that describe west‐verging major structures. The third deformation event is characterized by brittle extensional structures. The tectonometamorphic evolution of the ophiolitic sequences from the different outcrops is similar. Both thermobarometric modeling and tectonic history indicate that the studied rocks underwent Alpine subduction and exhumation processes as tectonic slices inside a west‐verging accretionary wedge. The subduction of oceanic lithosphere was towards the present east; therefore, the Hercynian continental crust, overthrusted on the ophiolitic accretionary wedge after the neo‐Tethys closure, was part of the African paleomargin or a continental microplate between Africa and Europe.     

贵州大方煤田主采煤层的矿物学异常及其对元素地球化学的影响

运用电感耦合等离子体质谱(ICP-MS)、X射线荧光光谱(XRF)、带能谱仪的扫描电镜(SEM-EDX)、逐级化学提取(SCEP)和光学显微镜等方法,对贵州大方煤田11号煤层的地球化学和矿物学进行了研究。结果表明,大方煤田11号煤层中有高含量的脉状石英(11.4%)和脉状铁白云石(10.2%),铁白云石周边常被针铁矿所包裹,在脉状石英中发现有热液成因的黄铜矿、闪锌矿和硒方铅矿,此外,还有少量高岭石充填在脉中,这7种矿物常常同脉共存。脉状石英和脉状铁白云石分别来源于硅质和富铁的钙质低温热液流体,形成温度分别为180℃和85℃。脉状石英早于脉状铁白云石形成。根据Ca/Sr和Fe/Mn值,确定出铁白云石的形成至少经历了3个时期。这7种矿物按照从早到晚的生成顺序为硫化物、石英、高岭石、铁白云石和针铁矿。铁白云石是煤中Mn、Cu、Ni、Pb和Zn富集的主要原因,这5种微量元素的含量分别为0.09%、74.0μg/g、33.6μg/g、185μg/g和289μg/g。脉状石英是煤中铂族元素Pd、Pt和Ir的主要载体,它们在煤中的含量分别为1.57μg/g、0.15μg/g和0.007μg/g。另外,黄铜矿、闪锌矿和硒方铅矿亦是11号煤层中Cu、Zn和Pb的重要载体。     

北祁连俯冲-增生杂岩带中低温榴辉岩的地球化学特征

北祁连俯冲-增生杂岩带中的低温榴辉岩以透镜体形式产于蓝片岩和多硅白云母片岩中。根据稀土元素、微量元素及Sr-Nd同位素分析研究,可将本区低温榴辉岩分为两类:Ⅰ类榴辉岩以轻重稀土分异不明显和具有Eu正异常为特征;Ⅱ类榴辉岩的轻稀土富集,有轻微的Eu负异常。Sm-Nd同位素研究显示,I类榴辉岩样品的εNd(t)值为2.5~6.9,平均值为4.5;Ⅱ类榴辉岩εNd(t)=-3.3~1.4。这些研究成果表明,Ⅰ类榴辉岩的原岩来源于长期亏损的地幔源区,可能形成于大洋环境;而Ⅱ类榴辉岩的原岩在形成过程中很明显混入了陆壳物质,据此推断其原岩形成于大陆边缘或洋陆过渡环境。