贵州大方煤田主采煤层的矿物学异常及其对元素地球化学的影响

运用电感耦合等离子体质谱(ICP-MS)、X射线荧光光谱(XRF)、带能谱仪的扫描电镜(SEM-EDX)、逐级化学提取(SCEP)和光学显微镜等方法,对贵州大方煤田11号煤层的地球化学和矿物学进行了研究。结果表明,大方煤田11号煤层中有高含量的脉状石英(11.4%)和脉状铁白云石(10.2%),铁白云石周边常被针铁矿所包裹,在脉状石英中发现有热液成因的黄铜矿、闪锌矿和硒方铅矿,此外,还有少量高岭石充填在脉中,这7种矿物常常同脉共存。脉状石英和脉状铁白云石分别来源于硅质和富铁的钙质低温热液流体,形成温度分别为180℃和85℃。脉状石英早于脉状铁白云石形成。根据Ca/Sr和Fe/Mn值,确定出铁白云石的形成至少经历了3个时期。这7种矿物按照从早到晚的生成顺序为硫化物、石英、高岭石、铁白云石和针铁矿。铁白云石是煤中Mn、Cu、Ni、Pb和Zn富集的主要原因,这5种微量元素的含量分别为0.09%、74.0μg/g、33.6μg/g、185μg/g和289μg/g。脉状石英是煤中铂族元素Pd、Pt和Ir的主要载体,它们在煤中的含量分别为1.57μg/g、0.15μg/g和0.007μg/g。另外,黄铜矿、闪锌矿和硒方铅矿亦是11号煤层中Cu、Zn和Pb的重要载体。     

北祁连俯冲-增生杂岩带中低温榴辉岩的地球化学特征

北祁连俯冲-增生杂岩带中的低温榴辉岩以透镜体形式产于蓝片岩和多硅白云母片岩中。根据稀土元素、微量元素及Sr-Nd同位素分析研究,可将本区低温榴辉岩分为两类:Ⅰ类榴辉岩以轻重稀土分异不明显和具有Eu正异常为特征;Ⅱ类榴辉岩的轻稀土富集,有轻微的Eu负异常。Sm-Nd同位素研究显示,I类榴辉岩样品的εNd(t)值为2.5~6.9,平均值为4.5;Ⅱ类榴辉岩εNd(t)=-3.3~1.4。这些研究成果表明,Ⅰ类榴辉岩的原岩来源于长期亏损的地幔源区,可能形成于大洋环境;而Ⅱ类榴辉岩的原岩在形成过程中很明显混入了陆壳物质,据此推断其原岩形成于大陆边缘或洋陆过渡环境。     

Synthesis, Characterization and Antibacterial Activity of New Ln（Ⅲ ） Complexes with an Unsymmetrical Schiff Base Ligand

1Introduction SomeSchiffbasecomplexesderivedfromaminoacidsareparticularlyactiveinbiologycatalysisandmaterial.Thestudyofthemisfocusofthestudyof coordinationchemistry.Recently,studiesofsuchmetalcomplexesofmono Schiffbaseshavebeenre ported(Fanetal.,2003a,b;L…     

法国高层大气所空间综合孔径项目研究进展

概述了法国高层大气所空间综合孔径项目背景、科学目标以及有效载荷,介绍了该项目演示系统的基本工作原理,探讨了该演示系统的望远子系统、指向子系统、共相子系统和成像子系统,并分别给出了该演示系统在非共相控制和共相控制情况下对半导体激光器和白光点光源的成像结果,实验结果表明演示系统不同独立望远镜之间已经基本实现了共相成像。最后对该演示系统进行了总结,并指出该系统可以进一步优化之处。该演示系统对我国综合孔径成像实验研究具有一定的借鉴意义。     

Sulfur Concentration in Geochemical Reference Materials by Solution Inductively Coupled Plasma‐Mass Spectrometry

With implications for the origin of ore deposits, redox state of the atmosphere, and effects of volcanic outgassing, understanding the sulfur cycle is vital to our investigation of Earth processes. However, the paucity of sulfur concentration measurements in silicate rocks and the lack of well‐calibrated reference materials with concentrations relevant to the rocks of interest have hindered such investigations. To aid in this endeavour, this study details a new method to determine sulfur concentration via high mass resolution solution inductively coupled plasma‐mass spectrometry (ICP‐MS). The method is based on an aqua regia leach, involving relatively rapid sample preparation and analysis, and uses small test portion masses (< 50 mg). We utilised two independently prepared standard solutions to calibrate the analyses, resulting in 4% accuracy, and applied the method to eight geochemical reference materials. Measurements were reproducible to within ~ 10%. Sulfur concentrations and isotopes of six reference materials were measured additionally by elemental analyser‐combustion‐isotope ratio mass spectrometry to independently evaluate the accuracy of the ICP‐MS method. Reference materials that yielded reproducible measurements identical to published values from other laboratories (JGb‐1, JGb‐2 and MAG‐1) are considered useful materials for the measurement of sulfur. Reference materials that varied between studies but were reproducible for a given test portion perhaps suffer from sample heterogeneity and are not recommended as sulfur reference materials.     

Forward simulation of coal fire model by transient electromagnetic method with electrical source

Uncontrolled coal fires are natural disasters that may cause mineral loss and environmental damage. The traditional loop source transient electromagnetic method can effectively detect the low-resistivity region of coal fires, but its detection efficiency is not so good for high-resistivity regions. In view of this limitation, a technique based on electrical source transient electromagnetics is proposed in this paper to detect high-resistivity regions in the spontaneous combustion process of coal. Considering the complex geometry of the coal fire area, an unstructured tetrahedral grid is used in this study to realize the spatial discretization of the model, and solve the electromagnetic field based on a vector finite element algorithm. Numerical analysis is used to investigate methods for detecting coal fires and the characteristics of effective anomalies are further examined to provide guidance for practical detection.     

Test on dynamic characteristics of subgrade of heavy-haul railway in cold regions

Dynamic characteristics of heavy-haul railway subgrade under vibratory loading in cold regions are investigated via low-temperature dynamic triaxial tests with multi-stage cyclic loading process. The relationship between dynamic shear stress and dynamic shear strain of frozen soil of subgrade under train loading and the influence of freezing temperatures on dynamic constitutive relation, dynamic shear modulus and damping ratio are observed in this study. Test results show that the dynamic constitutive relations of the frozen soils with different freezing temperatures comply with the hyperbolic model, in which model parameters a and b decrease with increasing freezing temperature. The dynamic shear modulus of the frozen soils decreases with increasing dynamic shear strains initially, followed by a relatively smooth attenuation tendency, whereas increases with decreasing freezing temperatures. The damping ratios decrease with decreasing freezing temperatures. Two linear functions are defined to express the linear relationships between dynamic shear modulus (damping ratio) and freezing temperature, respectively, in which corresponding linear coefficients are obtained through multiple regression analysis of test data.     

2013—2017年夏季东北冷涡下东北地区MCS的统计特征

利用2013—2017年6—8月FY-2E和FY-2G地球静止卫星相当黑体温度（Black Body Temperature,TBB）资料、NCEP/NCAR再分析资料,对我国夏季东北冷涡下东北地区MCS的分布和活动特征进行了统计分析,结果表明：（1） MCS的活动具有明显的月际变化和日变化特征,6月对流活动最活跃。MCS的主要移向是东、东北和东南,平均移动距离3.99个经纬距。（2） MCS成熟时刻的面积、偏心率和生命史均小于江淮地区以及中国中东部,云顶高度低于江淮地区,整个生命史表现出发展快消亡慢的特征,与江淮地区相反。（3）基于MCS的定义得到的Z标准,对2016—2017年的MCS作了统计分析并与J标准统计得到的MCS进行对比,得出,两种定义下的MCS环境场特征基本一致,主要表现为MCS多生成于500 hPa槽前和槽后,对流层高层MCS位于双急流之间靠近北支急流的辐散区,南侧急流高度在200 hPa,北侧的急流高度在250 hPa。低层,位于低空急流左侧,低涡南侧、东南侧,有较强的水汽和动量输送。槽前生成的MCS南侧中层存在垂直反环流向MCS输送干暖空气与位涡,槽后生成的MCS两侧均有大值位涡向其输送,同时北侧冷干空气的输送使锋区及上升运动加强,更有利于MCS的形成。（4）两种标准下的MCS造成的降水明显不同,在统计强降水方面Z标准要优于J标准。由于Z标准空间与时间尺度较小,统计得到的MCS较多;但同时会遗漏部分相对弱的MCS。     

基于DDS技术的Loran—C信号源的杂散信号抑制的分析与实现

采用直接数字频率合成（DDS）技术设计的Loran—C信号源,具有输出杂散多且难以预测的缺点。基于对DDS基本原理的研究分析,针对DDS输出信号存在的相位舍位杂散问题,对其关键部位的相位累加模块进行优化设计,并基于FPGA技术,在QuartusII环境下完成了对Loran．C信号源的实现与仿真验证。结果表明,通过优化的设计算法能够产生失真小,稳定度好的输出波形,从而验证了该方法抑制杂散的有效性与可行性。     

Eagle Nebula Pillars: From Models to Observations

Over the past few years, our group has been developing hydrodynamic models to simulate formation of the Eagle Nebula pillars. The true test of any model is, of course, how well it can reproduce the observations. Here, we discuss how we go about testing our models against observations. We describe the process by which we “observe” the model data to create synthetic maps. We show an example of this technique using one of our model runs and compare the resultant synthetic map to the real one.