俯冲带中石墨质碳的研究进展

自然界中,石墨质碳可以稳定存在于沉积岩、岩浆岩和变质岩中,由有机质或无机碳酸盐转变而来。随着对俯冲带碳循环研究的不断深入,通常作为副矿物产出在变质岩中的石墨质碳也引起了广泛的关注。相比于碳酸盐矿物和含碳流体,石墨质碳因其低溶解性、低移动性常作为碳汇稳定存在于俯冲带中。然而,在一些特殊的地质条件下(例如流体出现的开放体系中),石墨质碳不再稳定,它会变得活跃并发生迁移。因此,石墨质碳也是俯冲带碳循环研究中的关键载体。本文在综述前人研究成果的基础上,总结了俯冲带中石墨质碳的性质、来源、形成和分解过程,并重点介绍了俯冲带中非生物成因石墨的形成机制、石墨质碳的稳定性以及石墨质碳的释放,全面探讨了石墨质碳在俯冲带碳循环中的重要意义。俯冲带中石墨质碳的成因机制主要有3种:生物有机质石墨化、饱和含碳流体沉淀、碳酸盐矿物的还原反应。俯冲带中石墨质碳可通过分解脱气和溶解的方式释放。俯冲作用和风化侵蚀是石墨质碳全球循环的两个主要过程,其中俯冲作用对石墨质碳的地球内部循环影响较大。     

矿产资源评价中的核心问题

矿产资源评价是过去几十年里全球地质学家关注的重要领域。在过去的研究中,矿产资源评价的方法学及其相应的统计学技术在理论上取得了明显的进展,统计学技术或主观评估已经成为多元数据综合和资源潜力预测的通用方法。然而,这些方法所得出的估计结果或结论对于国家宏观政策制定、矿产资源管理、商业矿产勘探的实际效果和指导意义非常有限。影响矿产资源评价效果的很多问题还有待于进一步研究,新的基础理论问题需得到进一步解决。为此,就其中几个有关矿产资源评价的最为关键的问题进行了深入的探讨,包括矿产资源的随机性、内在的统计关系、矿产的稀有性、本征地质单元、资源经济转化等。就几个信息综合中的技术问题也做了较为系统的讨论,包括信息增强、空间连续性、数据综合及靶区圈定。最后提出了"动态模型区"的概念,试图为矿产资源评价指出一个新的思考方向。     

燃烧氧化-非分散红外吸收总有机碳分析仪测定海水DOC 的不确定度分析

采用实验测定和误差分析的方法, 对燃烧氧化-非分散红外吸收总有机碳分析仪vario TOC cube测定海水DOC 含量的不确定度进行了分析, 对导致测定结果不确定度的各分量进行了量化估算。结果表明, 其测定结果的不确定度主要来源于四个方面, 即样品重复性测量、标准曲线拟合、标准溶液配制(包括称量、定容、移液产生的不确定度, 标准物质纯度和相对原子质量产生的不确定度)及测量仪器本身, 相对标准不确定度分量分别为0.016、0.018、0.0086、0.0079。标准曲线拟合与样品重复性测量是影响海水DOC 测定不确定度的主要因素, 但标准溶液配制和测量仪器所引起的不确定度亦不可忽略。对实际海水DOC 浓度为1.20 mg/L 的样品分析,合成以上四种不确定度分量得到DOC 测定结果的标准不确定度为0.21 mg/L。按照正态分布,取扩展因子k=2, 则扩展不确定度为0.07 mg/L, 此海水样品中DOC 含量的测定结果应为(1.20±0.07) mg/L(k= 2)。     

H2O/CO2污染对煤油燃料超声速燃烧影响数值研究

在纯净空气与H₂O/ CO₂污染空气来流对比试验结果基础上,采用数值计算方法和化学动力学方法,研究了H₂O和CO₂污染组分对煤油燃料超声速燃烧的影响,获得了试验手段难以得到的燃烧室流场参数和性能数据。完成了相应的煤油燃料超声速燃烧室二维数值计算,其中匹配了进口总温、总压、马赫数、氧气摩尔分数和工作当量油气比。将数值计算结果与相应试验测量值进行了对比分析,并结合燃烧室流场数据、性能参数分析了H₂O和CO₂污染的动力学影响、以及对燃烧室性能的影响。研究表明:(1)数值计算结果与实验测量值总体上吻合,两种手段均体现了纯净空气来流时不同煤油当量油气比的燃烧室性能,并反映了一致的“污染效应”影响趋势;(2) H₂O污染、H₂O+ CO₂污染的存在降低了煤油燃料超声速燃烧室性能,体现在燃烧诱导压升、燃烧效率、流向冲量增量的下降,而且随着污染组分含量的增加,燃烧室性能下降越加显著。      

我国燃煤汞沉降的数值模拟

利用CMAQ-Hg(Community Multi-scale Air Quality-Mercury)模式模拟了我国燃煤排放的大气汞在我国区域的沉降分布状况,其中气象模式为MM5.模式中包括了三种价态汞(气态元素汞(GEM)、气态活性汞(RGM)和颗粒汞(PHg))的气相、液相、非均相化学反应过程以及输送、干湿沉降等物理过程.中国燃煤排放的大气汞中RGM所占比例较高,约为58.4%～66.8%,这导致我国汞沉降量较大.模拟结果表明,在我国的西南地区、华东地区以及京津塘地区燃煤汞的沉降较高,在这些区域的沉降通量高达2～6μg m-2mon-1.燃煤大气汞排放形态对汞的沉降有重要影响,减少燃煤汞排放中RGM的比例能够显著降低我国区域汞的沉降通量.     

Radial distribution of the integrated light and photometric colours in open star clusters

Mass segregation in the form of preferential concentration of more massive stars in the central regions of a number of open star clusters has been known for some time. In this paper, integratedUBV colours in concentric zones have been estimated for 12 nearby open clusters using the observations of individual cluster members. It is found that the clusters showing pronounced mass segregation also show significant radial variations in the integrated colours. However, the effects of stochastic fluctuations around the massive portion of the mass distribution function on the integrated colours should be taken into consideration, if they are present.     

Synthesis of accelerations of the 1976 Tangshan earthquake ( M S 7.8) in near- and far-field by using semi-empirical method

In this paper a heterogeneous fault model of the Tangshan earthquake is suggested, which consists of two southern sub-faults striking N30°E and two northern sub-faults striking N50°E. Total length of the main shock fault is 114 km and seismic moment is about 1.4 × 10²⁰ N·m. The epicentre of the main shock is located at the southern part, near the intersection of the two bands. Accelerations of two aftershocks (M _L 5.5, M _S 6.9) were used as empirical Green’s functions to synthesize the accelerations of the main shock in near and far field. A method that small events and main shock are considered not satisfying the similarity relationship in the improved empirical Green’s function is also applied in this paper. Peak values, duration and response spectra of synthesized accelerations in far field are in agreement with the observed records. The synthesized results in near field are also in agreement with the epicentral intensity distribution of the main shock. The results show that the peak acceleration of Tangshan earthquake in epicentral region exceeds 1.1 g. It is consistent with the peak accelerations recorded in some large earthquakes occurred in recent years. The research is supported by the National Science Foundation of China.     

皖东地区药用植物资源可持续利用研究

皖东地区自然条件优越，药用植物资源优势明显，不仅种类多、储量大，而且品质好、分布广。文章在对皖东地区药用植物资源全面调查研究的基础上，以药用植物的药用价值、分类学价值、特有状况、分布范围、野生资源数量、栽培状况等作为评价指标，分别对其进行相应的等级划分和等级赋值，建立了药用植物综合价值评价指标体系，并以此将皖东地区目前重点普查的218种药用植物划分为价值高的5种、价值较高的74种、价值一般的76种，价值低的63种，最后，就皖东地区药用植物资源可持续利用提出了科学规划、综合开发、规模引种、有效保护等基本对策。     

水合碱式硫酸镁晶须材料的水热合成

本文研究了水合碱式硫酸镁MgSO4·5Mg（OH）2·3H2O（以下称MOS）晶须的水热合成。良好的晶须可通过MgSO4·7H2O和Mg（OH）2间的水热反应生成。文中研究了各种合成条件对合成过程和产物品质的影响。当反应体系在温度为130℃～170℃、压力为304.0～810．4kPa的条件下，合成出的晶须具有很高的纯度，产率达90％以上，纤维长可达200μm，纤维直径为0．8～1．2μm。     

Glacial–interglacial variations in Quaternary production of marine organic matter at DSDP Site 594, Chatham Rise, southeastern New Zealand margin

CaCO₃ and total organic carbon concentrations, organic matter C/N and carbon isotope ratios, and sediment accumulation rates in late Quaternary sediments from DSDP Site 594 provide information about glacial–interglacial variations in the delivery of organic matter to the Chatham Rise offshore of southeastern New Zealand. Low C/N ratios and nearly constant organic δ¹³C values of −23‰ indicate that marine production dominates organic matter supply in both glacial and interglacial times during oxygen isotope stages 1 through 6 (0–140 ka) and 17 through 19 (660–790 ka). Increased organic carbon mass accumulation rates in isotope stages 2, 4, 6, and 18 record enhanced marine productivity during glacial maxima. Excursions of organic δ¹³C values to ca. −29‰ in portions of isotope stage 2 suggest that the local concentration of dissolved CO₂ was occasionally elevated during the last glacial maximum, probably as a result of short periods of lowered sea-surface temperature. Dilution of carbonates by clastic continental sediment generally increases at this location during glacial maxima, but enhanced delivery of land-derived organic matter does not accompany the increased accumulation of clastic sediments.