Content Variations of Rubidium and Bromide in Sylvite Derived from Carnallite by Leaching of Magnesium Chloride

正The relationship between sylvinite and carnallite is important in the potash mine body contained carnallite,especially sylvinite overlies carnallite,the reverse of a normal depositional sequence.Trace elements are more     

Phase petrology and P-T conditions of mafic blueschists from the Meliata unit, West Carpathians, Slovakia

Abstract Blueschists occurring as layers in calcite marbles of the Meliata unit occur along the so-called Roznava tectonic line situated in the southern part of the Gemericum, Slovakia. Mineral assemblages and compositions from seven blueschists localities and one occurrence of amphibolite facies rocks overprinted by blueschist metamorphism were investigated. The most common minerals in the blueschists are blue amphibole, epidote and albite. Some Fe²⁺- and Al-rich rocks also contain garnet and chloritoid, respectively. Na-pyroxene with a maximum 50% jadeite component was also found. The blue amphiboles correspond mostly to crossite and also to glaucophane and ferroglaucophane in some samples. Almandine- and spessartine-rich garnet has very low MgO content (<3 wt%). The Si content in phengite ranges between 3.3 and 3.5 pfu calculated on the basis of 11 oxygens. The zoning patterns of blue amphibole, garnet and chloritoid suggest their formation during a prograde stage of metamorphism. The P-T conditions of metamorphism are estimated to be about 380–460° C and 10–13 kbar. Pressures of 7.5–8.5 kbar and temperatures of 350–370° C were obtained for some actinolite- and aegirine-rich rocks. Apart from chlorite, other mafic minerals formed during retrograde metamorphism are biotite and occasionally also actinolite.     

Low-grade regional metamorphism in the Mesozoic-Cenozoic volcanic sequences of the Central Andes

ABSTRACT All the Mesozoic and Cenozoic volcanic rocks of the Central Andes (from southern Ecuador to central Chile), except Recent ones, have been affected by episodes of regional metamorphism, without change in texture and structure. The metamorphism, which ranges from low zeolite to greenschist facies, can be classified as burial metamorphism because there is an overall increase in metamorphic grade with stratigraphic depth in the individual volcanic sequences separated by regional unconformities. Some sequences display metamorphic patterns transitional to ocean-floor and to geothermal field types, reflecting variations along and across the Andes in tectonic setting and thermal gradients. Volcanism was closely followed by metamorphism during each cycle characterizing the geological history of the Central Andes. The episodic nature of the metamorphism has led to breaks in metamorphic grade at regional unconformities and repetition of facies series, where strata of higher grade may even overlie those of lower grade. The existence of permeability-controlled distribution patterns of secondary minerals within individual flows shows that gradients of chemical activity, rate of reaction and P_fluid were acting, in addition to temperature and P,_tot overall gradients, during the regional metamorphism. The alteration is accompanied by chemical changes and disturbances of the K-Ar and Rb-Sr isotope systems. Similarities between Mesozoic facies series in the western and eastern flanks of the Andes are consistent with a mechanism of ensialic spreading-subsidence.     

Pathways and distances of fluid flow during low-grade metamorphism: evidence from pyrite deposits of the Cameros Basin, Spain

New geochemical and sulphur isotopic data are presented for a number of pyrite deposits from the Late Jurassic–Early Cretaceous Cameros Basin, Spain. The deposits were formed at, or close to, the peak of metamorphism and are always related to sandstone units in the mainly metapelite sequence. Iron remained immobile and conservative, pyrite iron being derived by sulphidation of chlorite in the host metapelites. Reduced sulphur, however, was supplied from two external sources: thermochemical reduction of sulphate and release of S during metamorphism of sedimentary sulphides. These sources provided isotopically heavy and light S, respectively, with variation in pyrite isotopic composition between different deposits resulting from differences in their relative importance at each site. During metamorphism, the sandstone units acted as aquifers, carrying the sulphidic pore waters to locations where permeability provided by syn-depositional fractures on a scale of 0.5–5  m allowed its interaction with the metapelites. Transport distances for sulphide during metamorphism were of the order of hundreds of metres.     

苏鲁造山带浅变质岩的成因及其大地构造意义

苏鲁造山带超高压变质带内部及其北缘,出露仅经过绿片岩相变质作用的浅变质岩系。通过对该浅变质岩的区域分布、地质特征及地球化学的综合研究,表明这些浅变质岩系与大别-苏鲁造山带大陆板块俯冲存在密切的成因关系,为扬子板块俯冲过程中被刮削下来的构造残片,构成大陆板块俯冲过程中形成的构造加积杂岩。在此基础上,厘定了苏鲁造山带的构造成因模型,并对苏鲁造山带的东延问题进行了讨论。     

内蒙古锡林郭勒地区上古生界极低级变质作用:伊利石和镜质体反射率的证据

本文使用D/max-2500X射线衍射仪研究了内蒙古锡林郭勒地区上古生界泥质岩石伊利石的成因标志,讨论了有机质镜质体反射率对变质温度的表征。研究区上古生界泥质岩石伊利石的标型特征为:伊利石结晶度分布于0.28～>0.77之间,平均值0.40;伊利石(白云母)多型以2M1型为主,2M1+1Md多型和1Md多型相对较少;伊利石(白云母)b0值变化于8.983～9.046之间,平均值9.019,指示其形成于成岩-极低级变质作用。有机质镜质体反射率具有示踪变质温度的作用,应用Barker and Pawlewiez(1986,1994)、Barker and Goldsteinl(1990)和Mullis et al.(2001)建立的镜质体反射率地质温度计,对研究区上古生界泥质岩石变质温度进行了估算,揭示古地温处于136～321℃之间,温度估算值主要分布在180～260℃之间,平均值为245℃,这表明研究区上古生界遭受了成岩-极低级变质作用,变质程度属近变质带。研究区上古生界泥质岩石的Ro值主要分布在1.01%～3.67%之间,表明有机质演化处于成熟-过成熟阶段,泥质岩石具有生烃的能力,部分层位可能具有形成油气资源的潜力。     

氯化钠对钾光卤石溶解过程的影响

研究了不同温度下，不同浓度的ＮａＣｌ溶液对钾光卤石溶解转化的影响．得出ＮａＣｌ的浓度对溶解转化的影响不大，且温度对光卤石的溶解转化的影响不是简单线性关系的结论．计算了该体系光卤石的溶解动力学方程和氯化钾结晶动力学方程．     

某地低品位氧化金矿氰熔体柱浸试验

通过对某地低品位氧化金矿采用氰熔体柱浸试验研究表明 ,氰熔体浸金的技术工艺是可行的 ,浸出率高达 92 %。工艺流程简单 ,浸出时间短 ,建议推广应用     

扎仓茶卡低品位固体硼矿矿物学与地球化学特征及可选性研究

西藏自治区扎仓茶卡盐湖是我国重要的超大型固体硼镁矿产地,经多年开采,高品位硼矿资源(B_2O_3≥28%)已采掘殆尽,但矿区内仍堆有大量低品位矿石,这不仅是对环境的威胁,也是对资源的浪费。在采集样品的基础上,开展了基于X射线衍射与扫描电镜的矿物组成的鉴定和化学组分分析,为低品位矿石的综合利用提供理论依据。研究结果表明,扎仓茶卡盐湖低品位硼矿的矿物种类有库水硼镁石、柱硼镁石、石英、钠长石、微斜长石、方解石、白云母、文石、水菱镁矿、石膏和锰热臭石共11种,其中仅有库水硼镁石和柱硼镁石两种硼矿物,平均含量分别为21.14%与8.99%,且硼矿样品中B_2O_3平均含量高达13.50%,有巨大的经济利用价值。考虑到扎仓茶卡有着丰富的卤水资源,且低品位硼矿主要为库水硼镁石,可利用卤水及矿物的密度差来进行重选,该库水硼镁石为易选型。这种方法不仅能实现矿区内低品位矿的回收利用,而且生产成本低廉、绿色环保,将进一步促进区域经济发展。     

The Solid-liquid Transformation of Low-grade Solid Potash Deposit in Dalangtan Basin and the Simplification of the Liquid Phase System

正We studied the solid-liquid transformation of low-grade solid potash deposit in Dalangtan Basin and simplified the liquid phase system.We did experiments to optimize conditions of the solid-liquid transformation.The Suitable