Quantitative chemical characterization of vitrinite concentrates using pyrolysis-gas chromatography. Rank variation of pyrolysis products

A series of hand-picked vitrinite samples from the Lower Kittanning Seam, Pennsylvania have been examined using quantitative pyrolysis-gas chromatography. These vitrinites ranged in rank from 0.59 to 1.71% reflectance, a rank range from high volatile C bituminous to low volatile bituminous. High molecular weight pyrolysis products included alkyl aromatic and phenolic compounds. Attempts have been made to correlate the pyrolysis product composition to rank parameters including vitrinite reflectance, volatile matter yield, carbon content, atomic H/C ratio and Rock-Eval determined T_max. Total yield of phenols was found to be strongly and inversely rank related. A clear relationship between C₈ alkyl-benzene yield and rank was not found for the sample set.     

疏勒河断裂中段VLF响应特点及地质解释

疏勒河断裂带中段为一隐伏基底断裂。由于规模较大，并且充填了低阻的构造角砾岩，因此对ＶＬＦ有很好的响应。本文分析了该构造的ＶＬＦ响应特点，指出在本区用ＶＬＦ方法寻找隐伏构造的有效性和局限性。     

腰椎管侧隐窝分型及影响侧隐窝狭窄症诊断的几个因素（附120例CTM分析）

作者对１２０例因下腰痛手术治疗在术前进行过ＣＴＭ检查的患者作了影像学及临床分析．按形态不同，侧隐窝可分为五种类型：（１）三角型，即整个椎管呈倒三角形，其侧隐窝完全开放；（２）猫耳型，因后关节和椎体后缘轻度增生，形成底宽顶尖的侧隐窝，整个椎管形如猫头，侧脸窝为猫耳，基本开放；（３）牛角型，因关节突向椎体方向过度增生使侧隐窝呈横向伸开的带状，中央椎管不窄，横断面形如牛头，侧阴窝为牛角，严重者侧隐窝可近于闭塞；（４）三叶草型，极度增生的关节突加上向后实入的椎体后缘使整个椎管呈三叶草状，侧隐窝和中央椎管均狭窄；（５）混合型，多为上述形状的混合或两侧侧隐窝发育不对称．前二型不易形成对神经的压迫，后三型易造成压迫．但即使最狭窄的侧隐窝也不一定产生症状，因为关键在于神经根和侧隐窝的宽度的相对关系．因此作者提出单纯依靠侧隐窝的宽度不能诊断侧隐窝狭窄症，而是要判断神经是否被侧隐窝压迫．因此ＣＴＭ在侧隐窝狭窄症的诊断中有突出意义．     

Ultrahigh-pressure garnet lherzolite from Chijiadian, Rongcheng County, in the Su-Lu region of eastern China

Abstract Petrological studies of a serpentinized garnet lherzolite body in Rongcheng of the Su-Lu region of eastern China revealed unusually high pressure. Spinel lherzolite probably in a subducting slab was transformed to garnet lherzolite at mantle depth. During exhumation, they were subsequently subjected to the granulite and then amphibolite overprinting and a phase of serpentinization. The peak P–T conditions of the garnet lherzolite estimated after detailed analysis of the metamorphic texture are 4–5 GPa and 820°C or 5–6 GPa and 780°C, depending on the chosen geothermobarometers. The lower dP/dT of the garnet lherzolite can be interpreted as the results of subduction of an old (say 100 Ma older than the time of collision) and cold, slab underneath the margin of the Sino–Korean craton.     

Comparison between Pollutant Concentration in the Samples of Fog and Rime Water Collected at Mt. Milešovka

The article aims at showing the differences in concentration of pollutants that are contained in the samples of fog and/or low cloud water in comparison with the water from rime. The results follow from the fog and rime measurements made at Mt. Mileovka (eské Stedohoí Mountains). They are compared with the results of other studies that also report the differences in fog and rime chemistry.     

璜山金矿找矿模式及应用

诸暨璜山金矿是除治岭头以外浙江省第二金矿,它的找矿模式为"三高两低一复合"的找矿模式,即高金晕、高极化率、高磁场跳跃、低电阻率、低电位和北东断裂与北东东断裂复合处是成矿最有利部位.在其附近仍有类似成矿部位,有望扩大远景.     

Statistical analysis of time-dependent earthquake occurrence and its impact on hazard in the low seismicity region Lower Rhine Embayment

The time-dependence of earthquake occurrence is mostly ignored in standard seismic hazard assessment even though earthquake clustering is well known. In this work, we attempt to quantify the impact of more realistic dynamics on the seismic hazard estimations. We include the time and space dependences between earthquakes into the hazard analysis via Monte Carlo simulations. Our target region is the Lower Rhine Embayment, a low seismicity area in Germany. Including aftershock sequences by using the epidemic type aftershock-sequence (ETAS) model, we find that on average the hypothesis of uncorrelated random earthquake activity underestimates the hazard by 5–10 per cent. Furthermore, we show that aftershock activity of past large earthquakes can locally increase the hazard even centuries later. We also analyse the impact of the so-called long-term behaviour, assuming a quasi-periodic occurrence of main events on a major fault in that region. We found that a significant impact on hazard is only expected for the special case of a very regular recurrence of the main shocks.     

四川盆地东北部三叠系飞仙关组碳酸盐岩成岩作用和白云岩成因的研究现状和存在问题

四川盆地东北部三叠系飞仙关组是我国重要的天然气储集层，优质储层形成机制直接与碳酸盐岩成岩作用、尤其是白云岩化作用相关，但飞仙关组碳酸盐岩在锰含量、锶含量、阴极发光性等特征上反映其成岩过程与经典成岩理论相悖；碳酸盐岩的锶同位素组成和锰、锶含量的关系也表明与大气水有关的成岩过程和作为重要储集岩的结晶白云岩的形成机制无关，传统的白云岩化机制难以解释结晶白云岩的成因。具有海源色彩的高锶、低锰成岩流体在很大程度上控制了飞仙关组碳酸盐的成岩作用，其来源与成因值得进一步关注，控制其运移、封存和发生水—岩反应的时空机制有待回答。整个海相三叠纪时间段盆地尺度碳酸盐岩和蒸发岩的沉积地球化学研究、尤其是不同结构组分碳酸盐的锶同位素组成、锶和锰含量研究（包括碳酸盐岩中不同结构组分的阴极发光性研究），可为四川盆地东北部飞仙关组碳酸盐岩成岩作用（尤其是白云岩化作用和作为重要储集岩的结晶白云岩的成因研究），天青石矿床成因研究和四川盆地三叠系深层富钾、锶、硼、溴卤水的成因研究提供重要的线索。     

Long‐term landscape evolution: linking tectonics and surface processes

Research in landscape evolution over millions to tens of millions of years slowed considerably in the mid‐20th century, when Davisian and other approaches to geomorphology were replaced by functional, morphometric and ultimately process‐based approaches. Hack's scheme of dynamic equilibrium in landscape evolution was perhaps the major theoretical contribution to long‐term landscape evolution between the 1950s and about 1990, but it essentially ‘looked back’ to Davis for its springboard to a viewpoint contrary to that of Davis, as did less widely known schemes, such as Crickmay's hypothesis of unequal activity. Since about 1990, the field of long‐term landscape evolution has blossomed again, stimulated by the plate tectonics revolution and its re‐forging of the link between tectonics and topography, and by the development of numerical models that explore the links between tectonic processes and surface processes. This numerical modelling of landscape evolution has been built around formulation of bedrock river processes and slope processes, and has mostly focused on high‐elevation passive continental margins and convergent zones; these models now routinely include flexural and denudational isostasy. Major breakthroughs in analytical and geochronological techniques have been of profound relevance to all of the above. Low‐temperature thermochronology, and in particular apatite fission track analysis and (U–Th)/He analysis in apatite, have enabled rates of rock uplift and denudational exhumation from relatively shallow crustal depths (up to about 4 km) to be determined directly from, in effect, rock hand specimens. In a few situations, (U–Th)/He analysis has been used to determine the antiquity of major, long‐wavelength topography. Cosmogenic isotope analysis has enabled the determination of the ‘ages’ of bedrock and sedimentary surfaces, and/or the rates of denudation of these surfaces. These latter advances represent in some ways a ‘holy grail’ in geomorphology in that they enable determination of ‘dates and rates’ of geomorphological processes directly from rock surfaces. The increasing availability of analytical techniques such as cosmogenic isotope analysis should mean that much larger data sets become possible and lead to more sophisticated analyses, such as probability density functions (PDFs) of cosmogenic ages and even of cosmogenic isotope concentrations (CICs). PDFs of isotope concentrations must be a function of catchment area geomorphology (including tectonics) and it is at least theoretically possible to infer aspects of source area geomorphology and geomorphological processes from PDFs of CICs in sediments (‘detrital CICs’). Thus it may be possible to use PDFs of detrital CICs in basin sediments as a tool to infer aspects of the sediments' source area geomorphology and tectonics, complementing the standard sedimentological textural and compositional approaches to such issues. One of the most stimulating of recent conceptual advances has followed the considerations of the relationships between tectonics, climate and surface processes and especially the recognition of the importance of denudational isostasy in driving rock uplift (i.e. in driving tectonics and crustal processes). Attention has been focused very directly on surface processes and on the ways in which they may ‘drive’ rock uplift and thus even influence sub‐surface crustal conditions, such as pressure and temperature. Consequently, the broader geoscience communities are looking to geomorphologists to provide more detailed information on rates and processes of bedrock channel incision, as well as on catchment responses to such bedrock channel processes. More sophisticated numerical models of processes in bedrock channels and on their flanking hillslopes are required. In current numerical models of long‐term evolution of hillslopes and interfluves, for example, the simple dependency on slope of both the fluvial and hillslope components of these models means that a Davisian‐type of landscape evolution characterized by slope lowering is inevitably ‘confirmed’ by the models. In numerical modelling, the next advances will require better parameterized algorithms for hillslope processes, and more sophisticated formulations of bedrock channel incision processes, incorporating, for example, the effects of sediment shielding of the bed. Such increasing sophistication must be matched by careful assessment and testing of model outputs using pre‐established criteria and tests. Confirmation by these more sophisticated Davisian‐type numerical models of slope lowering under conditions of tectonic stability (no active rock uplift), and of constant slope angle and steady‐state landscape under conditions of ongoing rock uplift, will indicate that the Davis and Hack models are not mutually exclusive. A Hack‐type model (or a variant of it, incorporating slope adjustment to rock strength rather than to regolith strength) will apply to active settings where there is sufficient stream power and/or sediment flux for channels to incise at the rate of rock uplift. Post‐orogenic settings of decreased (or zero) active rock uplift would be characterized by a Davisian scheme of declining slope angles and non‐steady‐state (or transient) landscapes. Such post‐orogenic landscapes deserve much more attention than they have received of late, not least because the intriguing questions they pose about the preservation of ancient landscapes were hinted at in passing in the 1960s and have recently re‐surfaced. As we begin to ask again some of the grand questions that lay at the heart of geomorphology in its earliest days, large‐scale geomorphology is on the threshold of another ‘golden’ era to match that of the first half of the 20th century, when cyclical approaches underpinned virtually all geomorphological work. Copyright © 2007 John Wiley & Sons, Ltd.     

Energy demands for seismic design against low‐cycle fatigue

A seismic design procedure that does not take into account the maximum and cumulative plastic deformation demands that a structure is likely to undergo during severe ground motion could lead to unsatisfactory performance. In spite of this, current design procedures do not take into account explicitly the effect of low‐cycle fatigue. Based on the high correlation that exists between the strength reduction factor and the energy demand in earthquake‐resistant structures, simple procedures can be formulated to estimate the cumulative plastic deformation demands for design purposes. Several issues should be addressed during the use of plastic energy within a practical performance‐based seismic design methodology. Copyright © 2006 John Wiley & Sons, Ltd.