Mobility of heavy metals from tailings to stream waters in local zinc smelting activities contaminated site

It has been found that stream waters were severely contaminated with wastes from a long-time smelting factory in Hezhang, Guizhou, China. The main sources of contamination are the smelting wastes stored in the open air and abandoned in the vicinity of stream. A method of lead isotope was adopted in order to identify relations between tailings and water contamination. Representative samples of tailings and stream sediments were collected. Mineralogical characterizations were conducted using XRD and TEM/SEM, while acid digestion was carried out for determining metal contents. BCR sequential leaching tests were performed in order to assess metal mobility. The tremendous ‘actual＇ and ‘potential＇ mobility of heavy metals indicates that the smelting waste and stream sediments present a considerable threat to the environment. Besides the chemical remobilization of heavy metals from the sediments and the reworking of riverbed sediments act as a secondary source of pollution. Also groundwater and stream water were sampled in specific locations and were measured.     

Effects of dynamic shear strength and time-histories stress analysis on newmark sliding block analyses

A simplified procedure for evaluating aseismic stability of slope subjected to earthquake shaking, in which the effect of dynamic shear strength and time-history stress on the yielding angular acceleration of sliding block is taken into account, is presented. The fundamental feature of this procedure is the dynamic shear strength. The numerical computations are performed by using the proposed method. It is shown that the computed sliding displacement for a given core dam, with either method of dynamic shear strength properly considered, is more rational compared with the conventional computational results based on static shear strength.     

Impact of Changes in Redox Conditions on Leaching of Some Elements from MSW Fly Ash

Abstract. Oxidation and reduction processes can influence extent of leaching of elements from solid waste. Three samples of municipal solid waste combustion fly ash were subjected to oxidizing and reducing conditions in order to evaluate leaching of elements in the Milli-Q water and fly ash (liquid to solid ratio, 100) mixtures. Although the oxidizing and reducing conditions were applied for 6 hours only, elements like Cs, Li, Mg, Sb, Tl and V leached more under oxidizing condition than under reducing condition in the case of all three ash samples. Cadmium, Pb and Zn leached more from all samples under reducing condition than under oxidizing condition. Leaching of other elements like Al, Ba, Cr, Cu, Ni and Rb was inconsistent with oxidizing or reducing conditions and varied from sample to sample, suggesting that factors other than redox may be more important in controlling leaching of these elements. Strong acid neutralization capacity of the fly ash samples let the pH vary within a narrow range, and thus severely limited the extent of leaching during the course of the experiment. Lead and Zn were the most sensitive while K and Na were the least sensitive to changes in redox conditions.     

On the Importance of Geolithological Features for the Estimate of the Site Response: The Case of Catania Metropolitan Area (Italy)

The evaluation of seismic site response in the urban area of Catania was tackled by selecting test areas having peculiar lithological and structural features, potentially favourable to large local amplifications of ground motion. The two selected areas are located in the historical downtown and in the northern part of Catania where the presence of a fault is evident. Site response was evaluated using spectral ratio technique taking the horizontal- to-vertical component ratio of ambient noise. Inferences from microtremor measurements are compared with results from synthetic accelerograms and response spectra computed at all drillings available for this area. Such method is particularly suitable in urban areas where the nature of the outcropping geological units is masked by city growth and anthropic intervention on the surface geology. The microtremor H/V spectral ratios evaluated at soft sites located within the downtown profile tend to be smaller than that usually reported in the literature for such soils. A tendency for amplifications to peaks near 2 Hz is observed only in some sites located on recent alluvial deposits. Evidences for amplifications of site effects (frequency range 4–8 Hz) were observed in the sampling sites located on the fault, with a rapid decrease of spectral amplitude just a few tenths of metres away from the discontinuity. Numerical simulations evidenced the importance of geolithological features at depth levels even greater than 20–30 m. Besides this, the results strongly confirm the importance of the subsurface geological conditions, in the estimate of seismic hazard at urban scale.     

Strain softening of K0-consolidated Changi sand under plane-strain conditions

Experimental results are presented in this paper to study the strain softening behaviour of a marine dredged sand under plane-strain conditions. K₀ consolidated drained and undrained tests were conducted using a new plane-strain apparatus to characterize the strain softening behaviour of the sand under plane-strain conditions. For medium dense specimens, strain softening and shear bands were observed to occur under both drained and undrained conditions. For very loose specimens, no shear bands were observed and critical states were reached within the homogeneous deformation region in both drained and undrained tests. Strain softening was observed to occur at small strain for very loose specimens under undrained conditions. Two types of strain softening, the homogenous softening and banding softening, were identified and the conditions for strain softening were established. The results obtained from this study were compared with the studies by Han and Vardoulakis (Géotechnique 41(1):49–78, 1991), Finno et al. (J Geotech Eng ASCE 122(6):462–473, 1996, Géotechnique 47(1):149–165, 1997) and Mokni and Desrues (Mech Cohes-Frict Mat 4:419–441, 1998).     

Assessment of Marine Clay Improvement Under Reclamation Fills by in-situ Testing Methods

In ground improvement projects with prefabricated vertical drains, the duration of the preloading period is set in advance based on the predetermined time rate of consolidation of the compressible layer. If prediction is accurately done, the required degree of consolidation is met at the pre-determined preloading time. As such, there is a requirement for in-situ tests to be carried out just prior to the removal of surcharge to assess the degree of consolidation of the improved ground. In-situ tests were carried out after 23 months of surcharge loading at the In-Situ Test Site within the Changi East Reclamation Project in the Republic of Singapore. In-situ testing works in this research study comprises the use of field vane shear, piezocone, flat dilatometer and self-boring pressuremeter. The in-situ tests were carried out to determine the shear strength and degree of consolidation of the Singapore marine clay at Changi after 23 months of surcharge loading. The In-Situ Test Site consisted of a Vertical Drain Area as well as an untreated Control Area. Both areas were located adjacent to each other and were surcharged simultaneously to the same level and surcharge left in place for a period of 23 months. Comparison was made between the in-situ test results of the Vertical Drain Area and the untreated Control Area.     

Spontaneous Structural Reform in Australian Local Government: the case of the Gilgandra Co-operative Model in New South Wales

Dire financial constraints and the threats of forced structural reform have had the unforeseen effect of forcing municipal councils across Australia to reconsider their operational activities and organisational arrangements. With considerable ingenuity, numerous municipalities have proposed and sometimes adopted new structural formations that embody various forms of co-operative service provision. This remarkable development has unfortunately been largely ignored in the scholarly literature on Australian local government. In a modest effort aimed at remedying this neglect, the present paper seeks to outline the small, rural New South Wales Gilgandra Shire Council's (2004) ‘Co-operative/Local Government Service Company’ model, place it in the broader context of alternative models of local governance suitable for Australian conditions, and evaluate its characteristics.     

Compressibility and shear strength of a residual soil

A detailed study was performed to investigate the compressibility and the shear strength of a residual soil in Omdurman, Sudan. The soil resulted from weathering of sandstone and mudstone. The soil is classified as sandy clayey silt (MH-CH) and is generally partially saturated. Consolidation tests were performed to study the compressibility of the soil and UU, CIU and insitu tests (CPT and SPT) were performed to study the shear strength characteristics of the soil. The characteristics of this residual soil can generally be predicted using correlations proposed in the literature for transported soils. The soil is of low to medium compressibility and exhibits slight apparent overconsolidation behavior. The soil dilates during shear and shows no long term effective cohesion. Problems associated with open cuts in this soil are attributed to loss of strength upon saturation.     

A Solution to the Problem of Predicting the Suitability of Silty–clayey Materials for Cement-stabilization

Major geotechnical problems in construction involving silty–clayey soils are due to their low strength, durability and high compressibility of soft soils, and the swell–shrink nature of the overconsolidated swelling soils. Confronted with these problems, a suitable ground improvement technique is needed, for deep excavations in soft clays, for stability, durability and deformation control. Cement-stabilization is one of the alternatives. An increase in strength and durability, reduction in deformability are the main aims of this method. Conventional cement-stabilization methods are used mainly for surface treatment. However, the use of cement has recently been extended to a greater depth in which cement columns were installed to act as a type of soil reinforcement (deep cement–soil mixing and cement jet grouting). In situ engineering properties of these silty–clayey soils are often variable and difficult to predict. For this reason cement-stabilization methods have a basic target to control the aforementioned engineering properties of these clays so that the properties of a silty–clayey soil become more like the properties of a soft rock such as clayey shale or lightly cemented sandstone. So cement-stabilization of these soils is essential to control their engineering properties and to predict their engineering behaviour for construction. In an effort to predict, classify and study the suitability of silty–clayey soils for cement-stabilization both slaking and unconfined compressive strength tests were carried out on clayey–sand mixtures consisted of two types of clays, kaolin and bentonite. Finally diagrams were prepared to study the variation of slaking and strength due to compaction, curing time and cement percentage and also to predict areas of efficient cement-stabilization.     

岩石三轴强度试验

通过自制岩石三轴压力室和配备液压泵与现有万能材料试验机组成岩石三轴试验系统，进行岩石三轴强度试验研究，并与其它方法比对，结果相近，满足了科研和生产的需要。