Chemical equilibria of thermal waters for the application of geothermometers from the Guanzhong basin, China

In this study, representative samples from thermal wells and springs were chemically analyzed and geothermometers were used to calculate the deep temperatures of geothermal reservoirs on the basis of water–mineral equilibrium. In some cases, however, the chemical components are not in equilibrium with the minerals in the reservoir. Therefore, log(Q/K) diagrams are used to study the chemical equilibrium for the minerals that are likely to participate. The Na–K–Mg triangular diagram is also applied to evaluate the equilibrium of water with reservoir rocks. Standard curves at the reference temperatures are prepared to reveal which type of silica geothermometer is appropriate for the specified condition. This study shows that water samples from geothermal wells W9 and W12 are in equilibrium with the selective minerals, and chalcedony may control the fluid–silica equilibrium. It is estimated that there is an exploitable low-temperature reservoir with possible temperatures of 80–90°C in the Guanzhong basin.     

δO of carbonate, quartz and phosphate from belemnite guards: implications for the isotopic record of old fossils and the isotopic composition of ancient seawater

Belemnite guards of Cretaceous and Jurassic age were found to contain varying amounts of quartz deposited both on the external surface and inside the rostrum. The oxygen isotopic composition of coexisting carbonate, quartz and phosphate from the same rostrum was measured according to well-established techniques. None of these compounds showed isotopic values in equilibrium with one another. Assuming δ¹⁸O values of the diagenetic water within the range of meteoric waters, the δ¹⁸O(SiO₂) yield temperatures in agreement with the apparent secondary origin of this phase. The δ¹⁸O(CO₃²⁻) range, with a certain continuity, between −10.8 and +0.97 PDB-1 with most of the intermediate values being within the range of the carbonate isotopic values of Mesozoic fossils. The most positive isotopic results obtained from phosphate are close to +23/+24‰ (V-SMOW). They can hardly be related to a secondary origin of the phosphate, or to the presence of diagenetic effects, since these results are among the most positive ever measured on phosphate. As far as we know there is no widespread diagenetic process determining an ¹⁸O enrichment of phosphate. The very low concentration of phosphate did not allow the determination of its mineralogical composition. All the available δ¹⁸O(PO₄³⁻) values from belemnite and non-belemnite fossils of marine origin of Tertiary and Mesozoic age are reported along with the newly measured belemnites. The following conclusions may be drawn from the data reported: (1) the pristine oxygen isotope composition of fossil marine organisms (either carbonate or phosphate) may easily undergo fairly large changes because of oxygen isotope exchange processes with diagenetic water; this process is apparent even in the case of geologically recent fossils; (2) the δ¹⁸O(PO₄³⁻) of belemnite rostra seems to be, at least in the case of the most positive results, in isotopic equilibrium with environmental water because of the similarity between the results from Cretaceous belemnites and the results from Cretaceous and Lower Tertiary pelecypods and fish teeth; 3) if so, the only feasible interpretation that can be suggested for the ¹⁸O enriched data is the possibility of a relatively large variation of the oxygen isotopic composition of ocean paleowater from Jurassic to recent time.     

Spatial and temporal variability of pore‐water pressures in residual soil slopes in a tropical climate

It is critical to understand and quantify the temporal and spatial variability in hillslope hydrological data in order to advance hillslope hydrological studies, evaluate distributed parameter hydrological models, analyse variability in hydrological response of slopes and design efficient field data sampling networks. The spatial and temporal variability of field‐measured pore‐water pressures in three residual soil slopes in Singapore was investigated using geostatistical methods. Parameters of the semivariograms, namely the range, sill and nugget effect, revealed interesting insights into the spatial structure of the temporal situation of pore‐water pressures in the slopes. While informative, mean estimates have been shown to be inadequate for modelling purposes, indicator semivariograms together with mean prediction by kriging provide a better form of model input. Results also indicate that significant temporal and spatial variability in pore‐water pressures exists in the slope profile and thereby induces variability in hydrological response of the slope. Spatial and temporal variability in pore‐water pressure decreases with increasing soil depth. The variability decreases during wet conditions as the slope approaches near saturation and the variability increases with high matric suction development following rainfall periods. Variability in pore‐water pressures is greatest at shallow depths and near the slope crest and is strongly influenced by the combined action of microclimate, vegetation and soil properties. Copyright © 2002 John Wiley & Sons, Ltd.     

Vegetation influences on water yields from grassland and shrubland ecosystems in the Chihuahuan Desert

This study examines runoff generated under simulated rainfall on Summerford bajada in the Jornada Basin, New Mexico, USA. Forty‐five simulation experiments were conducted on 1 m² and 2 m² runoff plots on grassland, degraded grassland, shrub and intershrub environments located in grassland and shrubland communities. Average hydrographs generated for each environment show that runoff originates earlier on the vegetated plots than on the unvegetated plots. This early generation of runoff is attributed to soil infiltration rates being overwhelmed by the rapid concentration of water at the base of plants by stemflow. Hydrographs from the degraded grassland and intershrub plots rise continuously throughout the 30 min simulation events indicating that these plots do not achieve equilibrium runoff. This continuously rising form is attributed to the progressive development of raindrop‐induced surface seals. Most grassland and shrub plots level out after the initial early rise indicating equilibrium runoff is achieved. Some shrub plots, however, display a decline in discharge after the early rise. The delayed infiltration of water into macropores beneath shrubs with vegetation in their understories is proposed to explain this declining form. Water yields predicted at the community level indicate that the shrubland sheds 150 per cent more water for a given storm event than the grassland. Copyright © 2002 John Wiley & Sons, Ltd.     

由地方台网记录确定远震信号的方位角和慢度

介绍一种新的适合于地方遥测台网数据处理的方法，估算远震信号到达台站的方位角和慢度．该方法是根据信号在各台站上的到时与台站位置矢量在信号传播方向上的投影之间的相关性的原理．实际分析结果表明，应用该方法对地方台网的记录进行处理时可以准确地计算出信号的方位角和慢度，并能准确快捷地对地方台网记录的远震信号进行解释．      

Stable isotope values of Costa Rican surface waters

Stable isotope data of surface waters from the humid tropics in general, and Costa Rica in particular, are scarce. To improve our understanding of the spatial distribution of stable isotopes in surface waters, we measured δ¹⁸O and δD in river and lake (n=63) and precipitation (n=3) samples from Costa Rica. We also present data from the IAEA/WMO isotopes in precipitation network as context for our study. Surface water isotope values do not strongly correlate with elevation, stream head elevation, stream length, distance from Caribbean Sea, or estimated mean annual precipitation for the country as a whole. However, the data show distinct regional trends. The δ¹⁸O and δD values downwind of mountain ranges are inversely related to the altitude of the ranges the air masses traverse. In the lee of the high Talamanca Range, δ¹⁸O values are 6–8‰ lower, while in the lee of the lower Tilarán Range δ¹⁸O values are 2–3‰ lower than upwind sites along the Caribbean Slope. An altitude effect of −1.4‰ δ¹⁸O/km is present on the Pacific slope of southern Costa Rica, equivalent to a temperature effect of −0.3‰/°C. The Nicoya and Osa Peninsulas have higher values than upwind sites, suggesting input of Pacific-sourced moisture, evaporative enrichment, or decreased condensation temperatures. Elevated and increasing d-excess values inland along the Nicaragua Trough suggest a recycled component may be an important contributor to the water budget. These data provide preliminary stable isotope information for Costa Rica, and will benefit paleoclimatic research in the region. More detailed studies would be beneficial to our understanding of the controls on stable isotope composition of tropical waters.     

Water availability for the greening of Kuwait

Water resources for agricultural development and landscape enhancement in Kuwait are very scarce; the quality is saline (brackish), and the soil texture is sandy, incapable of holding nutrients and moisture. Most of the rainfall in Kuwait either evaporates due to the high temperatures or percolates through the soil. The rainfall is not sufficient to recharge the underground water supply. A variety of alternative water sources have been studied, including seawater desalination and wastewater treatment. Wastewater treatment proved to be convenient due to the relatively low salinity detected in the treated water. Furthermore, the amount of wastewater is expected to increase as more residential areas are connected to the sewage system as the population increases.

The development of a greenery plan for Kuwait requires intensive water management. This goal can be achieved through manpower training in landscape development, selection of plants tolerant to arid environments, usage of appropriate irrigation and drainage systems, promotion of greenery programs within public and the governmental agencies for their direct participation in urban area beautification, and extension of wastewater treatment techniques.     

地下水潮汐现象的物理机制和统一数学方程

用新的分层承压含水层模式 ,不但考虑含水层的力学压缩性质 ,而且考虑含水层的渗流特性 ,并结合扰动信息源的频率特性 ,分别研究扰动源地球固体潮、大气潮和地表负荷潮对承压井水位和流量的影响机理 ,给出相应的偏微分方程。从方程的解释或数值解讨论扰动源与承压井含水层的力学压缩参数、渗流特性参数及与频率特性频数的关系 ,进而给出承压井水位和流量对地球固体潮、大气潮和地表负荷潮汐响应的统一数学方程及其潮汐响应函数 ,并揭示了上述几类潮汐扰动信息源对承压井水位和流量影响的物理机理     

水对断层摩擦滑动稳定性的影响

在不同含水条件下研究了光面、含脆性物质夹层和含延性物质夹层 3类断层的摩擦滑动行为 ,认为水对断层滑动稳定性和摩擦滑动的速度依赖性有重要影响。建立了含有岩性、围压 (深度 )和含水量 3因素的断层活动稳定性的模式 ,认为脆性断层更多地表现为速度弱化 ,少量水的存在易于出现黏滑 ,高孔隙压时会表现为稳滑 ;半脆性或半延性的断层在少量水或较低孔隙压的情况下会表现出速度弱化 ,也就可能出现黏滑 ,但孔隙压较高后 ,会表现出速度强化 ,滑动也就会是稳定的 ;延性断层多为速度强化 ,不出现黏滑。提出水的进入降低了系统的稳定性 ,水的存在增加了系统的稳定性。这是考虑水或一般流体对岩体或断层活动稳定性影响时需要考虑的两个方面