The Use of Waste Materials in the Passive Remediation of Mine Water Polution

The contamination and resulting degradation of water coursesby effluents from abandoned and active mines is a world-wideproblem. Traditional methods of remediating the dischargesfrom mines involve the addition of chemicals and the utilisationof artificial energy sources. Over the last 15–20 years passivetreatment systems have been developed that harness naturalchemical and biological processes to ameliorate the potentiallytoxic effects of such discharges. There are many different typesof passive system, including compost wetlands, reducing andalkalinity producing systems (RAPS), permeable reactive barriersand inorganic media passive systems. Different waste materialscan be utilised as reactive media within each of these systems,dependent upon the type of mine water and treatment technology.In many cases the reactivity of these recycled waste materialsis key to the remedial performance of these systems. The materialsused may be organic (e.g., composts) or inorganic (e.g., blast furnaceslag) and where possible are sourced locally in order to minimisetransport costs. The remediation of mine waters in itself canproduce large quantities of waste products in the form of ironoxide sludge. Potential uses of this material in the productionof pigments and in the treatment of phosphate contaminatedwaters is also currently under investigation.The exploitation of what are traditionallythought of as waste materials within treatmentsystems for polluted waters is an expandingtechnology which provides great scope for recycling.     

岩石中金和铅在热液流体中的浸出实验研究

我国北方金矿主要受变质岩,花岗岩和构造条件控制,即一般公认的“三位一体”的成矿模式,但成矿元素是由花岗岩还是变质岩提供的则是值得进一步研究的问题。此外,各金矿通常伴有铝的分散晕,且铅同位素组成在区域上多成线性展布。研究后认为:花岗岩和变质岩均可作为金矿的矿源岩石。铅同位素的线性展布不能用铅演化的二阶段模型加以解释,而应作为混合线来说明。     

利用深液TLD装置减小结构振动的研究

本文通过分析ＴＬＤ装置对结构的作功及其与结构的相互作用情况，建立了描述ＴＬＤ装置对结构起减振作用的分析方法。依据本文建立的方法与概念，可将复杂的ＴＬＤ装置与结构系统的相互作用研究、分析简化为：首先孤立研究ＴＬＤ装置的性能，而后再与结构系统装配进行整体分析。最后，用试验测得的数据检验、印证了本文的分析方法     

Elevated curing temperature-associated strength and mechanisms of reactive MgO-activated industrial by-products solidified soils

Abstract

Alkali-activated industrial by-products (granulated blast furnace slag, Class F fly ash) by traditional alkali activator (such as NaOH and Na₂SiO₃) serves as a partial replacement for Portland cement in soil stabilization projects and suffers from environmental and technical problems. Reactive MgO – a greener and more practical alternative has recently emerged as a potential activator for slag and fly ash, but its micromechanisms of alkaline activation still need to be deeply investigated for strength improvement of soils. Hence, this study focuses on the strength and hydration properties of reactive MgO-slag and MgO-fly ash solidified soils, especially incorporating the impact of elevated curing temperature. Reactive MgO is proved to be excellent as a novel activator for activation of slag and fly ash, and their activating efficiency increases with elevated curing temperature that helps to remarkably enhance the compressive strength of soils. The major hydration products for reactive MgO-slag solidified soils, detected jointly by X-ray diffraction, scanning electron microscopy and thermogravimetric/differential thermogravimetric tests, are calcium silicate hydrate gels and hydrotalcite-like phases. The primary hydration products for MgO-fly ash solidified soils are magnesium silicate hydrate gels and Mg(OH)₂. That is just the intrinsic reason why the microstructure of solidified soils becomes much denser and the mechanical behavior is significantly improved. The minor carbonate phases such as magnesium carbonate and/or calcite are also observed in reactive MgO-slag and MgO-fly ash solidified soils, depending on the period of exposure to air. The curing temperature and binder amount are proved to be the two major factors governing the hydration process of reactive MgO-slag and MgO-fly ash blends. A higher curing temperature and binder amount can generate more hydration products, but their chemical compositions such as accurate element ratios need to be investigated in the future study.     

高压液相色谱分析外源类固醇在真鲷血液中的代谢

本研究利用高压液相色谱法（ＨＰＬＣ）法测定：外源睾酮（Ｔ）和甲基睾酮（ＭＴ）（１０μｇ／ｇ）腹腔注射给入真鲷（Ｐａｇｒｏｓｏｍｕｓｍａｊｏｒ）鱼体后，在血液中的代谢状况．证明，Ｔ和ＭＴ的吸收和清除很快。ＭＴ在注射１ｈ达最大吸收峰（２８３ｎｇ／ｍｌ），２４ｈ内很快降低。Ｔ的吸收和清除状况与ＭＴ相似，不同的是其吸收值（最大值为６４ｎｇ／ｍｌ）比ＭＴ低许多。随着鱼类养殖至商品规格，类固醇激素的含量将降至很低，因此，ＭＴ可做为一种生长促进因子用于水产养殖生产。     

多喷嘴结构液气混合器的仿真分析

针对自行设计的多喷嘴液气混合器的具体结构，分析研究了等直径并联管路的流量分配计算的准则，指出在计算变直径并联管路的流量分配时应注意的问题。并建立合理的数学模型，通过计算机仿真优化设计了多喷嘴混合器的尺寸配合关系，证明这种结构混合器的有效性。     

三种体系萃取分离-液闪测定海水中234Th的比较研究

本文对TOA萃取剂萃取钍适宜的操作条件及萃取溶剂进行了试验,提出了TOA/苯萃取234Th的最佳条件: 在 1cm3含 234Th的 6mol/dm3 HNO3 溶液中,用体积比为 0. 5的TOA/苯溶液 2cm3 萃取,然后用 2cm3 1. 0mol/dm3 H2SO4反萃取,最高萃取率达 94%.对TOA/苯、TBP/煤油和TTA/苯这 3种萃取体系的萃取效率及其影响因素、萃取机理、成本等做了比较,认为 3种体系各有利弊,但均可有效地应用于相关的海洋学研究中.     

On Physical and Mechanical Behavior of Natural Marine Intermediate Deposits

Coastal structures may be built on natural sedimentary intermediate grounds, which mainly consist of silty soils and fine sandy soils. In this study, extensive field and laboratory tests were performed on the nattwal marine intermediate deposits to demonstrate the difference in behavior between natural marine clayey soils and natural marine intermediate deposits. The natural intermediate deposits have almost the same miles of natural water content to liquid limit as those of the soft natural marine clays, but the former have much higher in-situ strength and sensitivity than the latter. The research results indicate that grain size distributions of soils affect significantly tip resistance obtained in field cone penetration tests. The mechanical parameters of natural marine intermediate deposits are also significantly affected by sample disturbance due to their high sensitivity and relatively large permeability. Unconfined compression shear tests largely underestimate the strength of natural marine intermediate soils. The triaxial consohdated compression shear tests with simulated insitu confined pressure give results much better than those of uncomfined compression shear tests.     

中国海域四株亚历山大藻的毒素分析

利用高效液相色谱法对4株采自中国不同海域的亚历山大藻所含有的麻痹性贝类毒素(PSP)进行了分析。结果显示,Alexandriumcatenella(东海株)的主要毒素成分为C2毒素,占其所含毒素总量的88.39%,细胞毒性大小为1.08pgSTX·eq/cell,毒力较低;Alexandriumtamarense(东海株)的毒素组成与A.catenella(东海株)的基本相同,但多含了一种膝沟藻毒素(GTX4),含毒量也比较低,细胞毒性大小为1.58pgSTX·eq/cell;Alexandriumminutum(台湾株)只检测出4种膝沟藻毒素(GTX1,2,3,4),其中GTX2,3摩尔百分比占到总量的75.42%,细胞毒性大小为21.32pgSTX·eq/cell;Alexandriumtamarense(南海株)毒素成分有9种,其中GTX4,6占据主要成分,占其所含毒素总量的54.92%,细胞毒性大小为5.01pgSTX·eq/cell。     

成矿碳酸岩的实验岩石学研究现状与展望

火成碳酸岩及其风化产物是全球战略性关键金属稀土元素(REE)和铌(Nb)的主要来源。因此,对关键金属在火成碳酸岩中的超常富集机理研究具有重要的科学意义。研究表明成矿碳酸岩常常与碱性杂岩体存在密切的时空联系,因而母岩浆应属于碳酸盐化的硅酸盐岩浆,并以霞石岩岩浆为主。针对碳酸岩关键金属矿床的成岩成矿过程,已有实验发现母岩浆在地壳内的演化过程中,既可以通过分离结晶作用,也可以通过液态不混溶作用形成碳酸岩。然而,更加接近自然样品的多组分体系的实验均表明液态不混溶作用总是先于碳酸盐矿物分离结晶作用。因此,液态不混溶作用对关键金属成矿过程有着不可忽视的作用。尽管如此,已有不混溶实验表明当碳酸盐熔体和硅酸盐熔体发生不混溶之后,关键金属REE与Nb总是优先分配到硅酸盐熔体(碱性岩)中,但是在成矿杂岩体中,REE与Nb是高度富集在碳酸岩中。虽然不混溶实验表明REE与Nb在碳酸盐-硅酸盐熔体中的分配系数与含水量有关,即与熔体的聚合程度有关,但是绝大部分成矿碳酸岩成矿过程一般并不富水,所以碳酸岩中REE和Nb等关键金属元素超常富集的机理并不明确。因此未来的研究应重点关注在碳酸岩演化的过程中,除了水以外,其他配体对于关键金属元素在不混溶硅酸盐-碳酸盐熔体之间分配系数是否有影响,从而找到控制碳酸岩中关键金属成矿的关键。