济阳坳陷新生代主要生油岩系底界面温度分布

依据济阳坳陷千余口测温井的地温梯度数据和地层岩性描述、分层数据以及钻井资料,计算了该区各生油岩系底界面的温度。统计结果表明:济阳坳陷大部分地带沙河街组地层底界面温度介于90～150℃之间,目前仍具有大量生油的温度条件,而在一些凸起地区和斜坡地带,该地层组段温度普遍小于90℃,未能达到生油的温度指标;孔店组地层也具有一定的生油温度条件。研究表明,地层温度与地层界面埋深密切相关,温度随界面埋深的增大而升高,沉积厚度大的凹陷带界面温度大于沉积厚度小的凸起区或斜坡地带,说明地层界面埋深是决定地温高低的主要控制因素,而地温梯度对地层界面温度的影响相对较小。     

基于含气泡液体声波方程的海底冷泉数值模拟

海底冷泉羽状流与海底天然气水合物的分布密切相关,对水合物稳定带的边界具有指示作用,是未来能源勘探的重要领域.研究海底冷泉羽状流的地震响应特征,对确定天然气水合物的储集区域及成藏环境等均有重要意义.当前获得海底冷泉羽状流的地震响应主要通过数值模拟进行,然而该过程所依据的含气泡介质声速模型及随机介质理论不能完整描述海底冷泉的物理性质,采用的声波方程也不适用于高频地震波数值模拟.为了准确地实现海底冷泉羽状流地震波数值模拟,精确分析其地震响应特征,本文提出利用Keller-Miksis气泡振动模型来描述气泡在声波作用下的运动状态,同时考虑气泡间的相互作用,建立海底冷泉气泡模型.在此基础上,本文创新性地采用含气泡液体声波方程进行海底冷泉高频地震波数值模拟.数值模拟结果表明,本文提出的方法能够实现海底冷泉羽状流地震响应的高精度数值模拟.     

弹性液舱内液体晃荡实验研究

通过物理模型实验,对水平简谐激励下弹性矩形液舱内液体晃荡问题进行了研究。实验中给出了不同液深和不同激励振幅下弹性液舱内液体最低阶固有频率。采用影像采集与分析系统获得液舱内自由液面的形状和高度,通过压力采集系统得到舱壁上的压力分布。实验中分析了不同液深、不同激励频率下弹性和刚性液舱内自由液面高度和晃荡压力的变化特性。比较了弹性和刚性液舱内不同位置处自由液面高度随外界激励频率的变化规律,以及舱壁上不同位置处的压力峰值随外界激励频率的变化规律。结果表明:非共振情况下,弹性和刚性实验结果及理论值三者的波高和压力较为接近。共振情况下,弹性和刚性波高基本相等,在近舱壁处二者明显大于理论值,而在远离舱壁处二者与理论值存在一定差别;弹性压力较刚性压力略小,但二者与理论值差别较大。     

高液限土路基的沉降变形规律

高液限土具有高天然含水率、高塑性、高孔隙比和低压实度的特点。明确高液限土路基的沉降变形规律成为其科学合理利用的关键。为此,在明确高液限土路用特性的基础上,铺筑了1条26.5 m高的高液限土高填方路基试验段,并进行了长期的沉降观测。结果表明,高液限土路基填筑期间的压缩变形量很大,填筑完成后自然沉降稳定期的固结变形量较小,路面铺筑后的工后沉降量很小,约为高度的2‰;高液限土路基的沉降量与其竖向填筑厚度基本成正比。采用简化的非饱和土固结理论对高液限土路基的沉降变形进行了模拟计算,计算结果与高液限土路基的实测沉降量基本一致,说明非饱和土固结理论可用于高液限土路基的沉降计算。高液限土路基沉降变形规律的成果说明其工后沉降不会过大,为其在公路工程中的推广应用提供了技术依据。     

A Novel Method for Dye Removal: Ionic Liquid‐Based Dispersive Liquid–Liquid Extraction (IL‐DLLE)

A novel, simple, fast, and efficient ionic liquid‐based dispersive liquid–liquid extraction (IL‐DLLE) has been applied to extract and remove Congo Red (CR; a carcinogenic textile dye) from aqueous solutions. In this methodology a binary solution, containing the extraction solvent (1‐hexyl‐3‐methylimmidazolium bis(trifluormethylsulfonyl) imid) and a suitable disperser solvent, was rapidly injected into the water sample containing CR dye. Therewith, a cloudy solution was formed, and most of the dye molecules were extracted into fine IL droplets and removed from aqueous phase. The effects of pH, type, and amount of IL, initial concentration of the dye, type and volume of the dispersant, and concentrations of salt on the extraction of the dye were studied. Experimental surveys were also accomplished for recovery of the IL by applying a reverse dispersive liquid–liquid extraction using acidic stripping solutions.     

Resource recovery and remediation of highly alkaline residues: A political-industrial ecology approach to building a circular economy

Highly alkaline industrial residues (e.g., steel slag, bauxite processing residue (red mud) and ash from coal combustion) have been identified as stocks of potentially valuable metals. Technological change has created demand for metals, such as vanadium and certain rare earth elements, in electronics associated with renewable energy generation and storage. Current raw material and circular economy policy initiatives in the EU and industrial ecology research all promote resource recovery from residues, with research so far primarily from an environmental science perspective. This paper begins to address the deficit of research into the governance of resource recovery from a novel situation where re-use involves extraction of a component from a bulk residue that itself represents a risk to the environment. Taking a political industrial ecology approach, we briefly present emerging techniques for recovery and consider their regulatory implications in the light of potential environmental impacts. The paper draws on EU and UK regulatory framework for these residues along with semi-structured interviews with industry and regulatory bodies. A complex picture emerges of entwined ownerships and responsibilities for residues, with past practice and policy having a lasting impact on current possibilities for resource recovery.     

Comparison of CloudSat cloud liquid water paths in arctic summer using ground-based microwave radiometer

Arctic clouds strongly influence the regional radiation balance, temperature, melting of sea ice, and freezing of sea water. Despite their importance, there is a lack of systematic and reliable observations of Arctic clouds. The CloudSat satellite launched in 2006 with a 94 GHz Cloud Profiling Radar (CPR) may contribute to close this gap. Here we compare one of the key parameters, the cloud liquid water path (LWP) retrieved from CloudSat observations and from microwave radiometer (MWR) data taken during the ASCOS (Arctic Summer Cloud Ocean Study) cruise of the research vessel Oden from August to September 2008. Over the 45 days of the ASCOS cruise, collocations closer than 3 h and 100 km were found in only 9 d, and collocations closer than 1 h and 30 km in only 2 d. The poor correlations in the scatter plots of the two LWP retrievals can be explained by the patchiness of the cloud cover in these two days (August 5th and September 7th), as confirmed by coincident MODIS (Moderate-resolution Imaging Spectroradiometer) images. The averages of Oden-observed LWP values are systematically higher (40–70 g m⁻²) than the corresponding CloudSat observations (0–50 g m⁻²). These are cases of generally low LWP with presumably small droplets, and may be explained by the little sensitivity of the CPR to small droplets or by the surface clutter.     

高液限土路堤填筑的双指标控制方法研究

对于高液限土（包括改良的高液限土）填筑的路堤只用单一的压实度指标控制常常易导致质量隐患。通过试验研究提出一个采用空气率Va和压实度Dc双指标控制高液限土路堤填筑质量的方法,并给出了具体的控制标准。当压实度控制指标Dc≥93%时,高液限黏土和粉土空气率控制标准为4%≤Va≤8%,含砂高液限黏土和粉土空气率控制标准为6%≤Va≤13%。通过系统的试验研究,验证了双指标质量控制的可行性和有效性。研究结果表明,采用空气率和压实度双指标控制,不仅可以保证高液限土填筑路堤的强度和刚度,而且具有较好的水稳定性,为进一步充分利用高液限土作为路堤填料提供了技术支持。     

粗颗粒间液桥毛细力演化规律的动态计算方法

水力特性是非饱和土力学理论与工程的重要课题之一,土样水力特性的变化过程本质上可反映为土颗粒间毛细力的演化规律。为此,以粗颗粒为研究对象,将其简化为一对不等径球体颗粒,而其间的水分形态可视为形如圆环的液桥,不考虑颗粒重力和浮力的影响。以Young-Laplace方程为基础,先推得计算液桥毛细力的控制方程组,再结合液桥的无量纲体积最大、最小值及其外曲率半径的割线迭代算法提出求解毛细力的动态计算方法,进而研究毛细力与颗粒间距、颗粒半径比和液桥体积的无量纲关系,结果表明：当颗粒间距一定时,液桥的毛细力随其体积和颗粒半径比增大均呈递增趋势;当液桥体积一定时,其抗拉刚度随颗粒间距增大呈递减趋势。最后,利用已有文献中液桥毛细力与颗粒间距的实测关系,验证了该动态计算方法在表征液桥从形成至断裂时毛细力演化规律的有效性。     

富水破碎岩体注浆加固材料试验研究与应用

针对富水破碎地层注浆治理过程中传统水泥类材料难以实现注浆加固和堵水同步进行的难题,以硫铝酸盐水泥熟料和钢渣微粉为主要原材,成功制备了一种水泥基复合注浆材料（CGM）。通过与传统水泥材料进行性能对比试验,采用扫描电镜和X射线测试手段,分析了CGM材料制备工艺、组分含量和浆液制备条件对材料性能的作用规律,并检验了CGM材料的工程适用性。结果表明：CGM材料宜采用混合粉磨制备工艺,可显著提高其水化活性,且粉磨时间应不超过45 min。钢渣微粉含量越高,水灰比越大,结石体强度越低,凝结时间越长,水灰比超过1.2:1时,结石体后期会出现干缩。与传统水泥材料相比,CGM材料浆液凝结时间与黏度的环境敏感度低,具有显著的工程适用性和性能优越性。