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91.
A method was developed for the determination of organic halogens in water samples with the aim of minimizing matrix effects and simplifying the sample preparation technique commonly used. The method is based on the adsorption of organic halogens in modified hydrophilic divinylbenzene polymer columns and their elution with methanol. The adsorbent used enables rapid adsorption and desorption due to comparatively high operating flow rates and minimized solvent amounts. Furthermore, no additional reconcentration steps are needed. The methanol extract obtained is combusted with a standard EOX (extractable organic halogen) analyzer and the concentration of organically bound halogens is determined by microcoulometric analysis. The matrix effects are considerably reduced compared to the standard procedure (EN 1485) commonly used. A detection limit of 13 μg/L was established. 相似文献
92.
93.
Migration characteristics of dense non-aqueous phase liquids (DNAPLs) in the subsurface can be expressed as a water–DNAPL two-phase system based on mainly the k–S–p relations, which describe the relations among relative permeability (k), degree of water saturation (S), and capillary pressure head (p). The aims of this research are to develop an experimental system with new type of probes, such as the electrical conductivity probe for measuring the degree of water saturation and the hydrophilic and hydrophobic tensiometer for measuring the pore water and DNAPL pressures, and also to estimate the results obtained from the developed experimental system. From these tests, the excellent k–S–p relations were obtained and the efficiency and validity of this developed experimental system have been confirmed in terms of the concept of the scaling coefficient calculated by interfacial tensions. 相似文献
94.
Predictions from dynamic modelling of the lithospheric deformation are presented for Northern Europe, where several basins underwent inversion during the Late Cretaceous and Early Cenozoic and contemporary uplift and erosion of sediments occurred. In order to analyse the evolution of the continental lithosphere, the equations for the deformation of a continuum are solved numerically under thin sheet assumption for the lithosphere. The most important stress sources are assumed to be the Late Cretaceous Alpine tectonics; localized rheological heterogeneities can also affect local deformation and stress patterns. Present-day observations available in the studied region and coming from seismic structural interpretations and stress measurements have been used to constrain the model. Our modelling results show that lateral variation in lithospheric strength below the basin systems in Central Europe strongly controls the regional deformation and the stress regime. Furthermore, we have demonstrated that the geometry of the boundary between Baltica and Avalonia, together with different rheological characteristics of the two plates, had a crucial role on local crustal deformation and faulting regime resulting in the Baltica–Avalonia transition zone from the S–N Alpine convergence. 相似文献
95.
Philippe Machetel 《Comptes Rendus Geoscience》2003,335(1):91-97
The numerical models of mantle convection agree to depict avalanches behaviour according to the level of endothermicity of the spinel → perovskite phase change. Their potential effects on the global thermal and dynamical states of the mantle have been computed thanks to a numerical code, which takes into account both the 400-km exothermic and the 660-km endothermic phase changes. The cycle followed by the avalanches is: local layering, destabilization of the 660-km thermal layer, travelling and spreading on the core, and reappearing of the local layering. Therefore, mantle convection is characterized by quiet periods of partial layering embedded in catastrophic events. During the avalanche, the amplitude of the surface velocity is multiplied by two, which would imply an enhanced plate tectonic and ridge activities. The global thermal effects of the avalanche are compatible with a high mantle temperature and an acceleration of Earth's rotation during the Cretaceous. They also offer a coherent explanation to locate the origin of mantle plumes both within the CMB and just below the transition zone. 相似文献
96.
结合传输型对地观测小卫星一体化设计的特点,介绍了一种用于对地观测小卫星系统的锁相接收机的-构成及原理,并对系统的相位噪声性能进行了详尽的分析,提出了对其相位噪声进行技术控制的方法。通过文中的分析与研究,消除了由于对地观测小卫星相位噪声所引起的系统误码率的恶化,提高了系统的可靠性,为下一步对地观测小卫星的发展与应用打下了良好的技术基础。 相似文献
97.
目的:针对射线透射图像中轻物质的自动识别存在的难点问题进行研究。方法:提出了基于轮廓特征和灰度特征的识别算法,结果:详细地阐述了利用识别算法进行识别的过程;结论:给出了识别算法的实验结果。 相似文献
98.
A. Gelencsér A. Hoffer G. Kiss E. Tombácz R. Kurdi L. Bencze 《Journal of Atmospheric Chemistry》2003,45(1):25-33
Current climate models seem to underestimate the flux of solar energy absorbed by the global troposphere. All of these models are constrained with the assumption that cloud droplets consist of pure water. Here we demonstrate in a simple laboratory experiment that aromatic hydroxy-acids which are found in continental fine aerosol can react with hydroxyl radicals under typical conditions prevalent in cloud water influenced by biomass burning. The reactions yield colored organic species which do absorb solar radiation. We also suggest that the products of such reactions may be humic-like substances whose presence in continental aerosol has been confirmed but their source mechanisms are still much sought after. We also attempt to give a first order estimate of the enhancement of water absorption at a visible wavelength under atmospheric conditions. 相似文献
99.
100.
用TRMM/TMI估算HUBEX试验区的云中液态水 总被引:4,自引:3,他引:4
文中应用热带降雨测量卫星微波成像仪的微波遥感资料反演云中液态水。由于微波成像仪85.5 GHz通道对云中液态水非常敏感,通过离散纵坐标矢量辐射传输模式,运用迭代的方法可以有效地反演出陆地上空非降水云中的液态水路径。在淮河流域能量与水分循环试验中,分别运用微波成像仪85.5 GHz垂直极化单通道和微波成像仪85.5 GHz极化亮温差两种方法来估算陆地上空的云中液态水路径,反演结果与地基微波辐射计的测量结果是较为一致的。当地表比辐射率或地表温度误差较大时,用极化亮温差法估算云中液态水路径相对较好,尤其是对于低云,因为该方法对地表温度不敏感。 相似文献