贵州纳雍水东铅锌矿床石英包裹体特征及成矿温度研究

利用显微测温学的方法,对纳雍水东铅锌矿床中石英进行显微及包裹体测温研究。研究表明,石英的流体包裹体主要以气液相包裹体居多,纯液相次之。包裹体测温结果显示,成矿流体冰点温度为-12.5℃~0.1℃,均一温度变化范围为122.1℃~307.0℃,峰值范围为120℃~150℃,反映出中低温成矿的特征;流体盐度W(NaC leq)%变化范围为0.18%~16.43%,平均盐度7.05%;流体密度为0.8 g/cm3~1.02g/cm3,平均密度0.95 g/cm3;成矿压力为87.86×105Pa~351.94×105Pa,其对应的成矿深度为0.29 km~1.17 km之间,平均成矿深度为0.50 km。综合研究表明本区矿床为典型的中低温热液铅锌矿床,成矿流体呈现中低温、低盐度、中等密度、低压、浅成相的矿床成矿环境特征。     

Fluid Inclusion Studies of Comb Quartz and Stibnite at the Hishikari Au–Ag Epithermal Deposit,Japan

Fluid inclusion microthermometry was conducted on late‐stage barren comb quartz and the latest stibnite at the Hishikari deposit to characterize the hydrothermal activity responsible for vein formation. Eight fluid inclusion assemblages (i.e. fluid inclusions trapped at the same time, ‘FIAs’) were studied to determine the formation fluid temperatures and salinities for the comb quartz in the Shosen No. 2 vein, Sanjin ore zone, and the stibnite in the Seisen No. 1–1 vein, Yamada ore zone. The average homogenization temperatures (the formation temperatures) of the seven FIAs from the comb quartz were between 207 and 230°C, while the average homogenization temperature (the formation temperature) of an FIA from the stibnite was 113°C. The measured fluid salinities of the seven FIAs from the comb quartz were low, ranging between 0.0 and 1.1 wt% NaCl equiv., indicating that dilute fluids were responsible for the comb quartz formation. By comparison with previous microthermometric data, the formation temperatures of the studied comb quartz were higher than those of columnar adularia and comb quartz at most other veins (generally around 200°C) but were similar to those of columnar adularia at Keisen veins (230°C) in the same ore zone. The higher formation temperatures both in the Shosen and the Keisen veins in the Sanjin ore zone indicate that the fractures corresponding to the vein system at the Sanjin ore zone were main conduits for hot ascending fluids. The low formation temperature of stibnite in the latest stage (113°C) indicates that stibnite precipitation occurred during a waning stage of hydrothermal activity. Combined with previous thermodynamic data on antimony solubilities, the large discrepancy between the formation temperature of the comb quartz (200–230°C) and that of the stibnite suggests that the stibnite may have precipitated as a result of a drastic cooling of the hydrothermal system.     

大别山双河片麻状花岗岩岩体石英组构特征及应变分析

对大别山双河片麻状花岗岩岩体中的石英C轴组构、黑云母(001)解理极点和石英颗粒三维应变分别进行系统测量。结果显示,双河岩体在侵位和后期演化过程中以挤压变形为特点,岩体经过NW-SE向和NE-SW向两次挤压,NW-SE向挤压强度较大,奠定了岩体基本的构造形态。结合区域应力场特征分析得出,双河岩体在早三叠世至早侏罗世应力方位为NW-SE向挤压,中侏罗世及后期为NE-SW向挤压,应力场发生顺时针变化。      

鄂尔多斯盆地东南部延长组储层成岩体系研究

鄂尔多斯盆地东南部延长组具有丰富的油气资源,储集层为一套致密低渗透砂岩,油气的富集与致密低渗透背景下的高效储层有关。通过铸体薄片、背散射、扫描电镜及能谱分析,结合孔、渗测定,认为:①延长组高效储层的形成与绿泥石环边有密切关系,绿泥石环边的出现是三角洲前缘沉积环境、富黑云母的长石砂岩和咸—微咸水的湖泊水体在空间上耦合的产物;②绿泥石环边抵消了一部分埋藏过程中上覆地层的机械压实作用,减缓了由于压实作用而引起的原生孔隙的减低,而且有抑制石英次生加大的作用;③同生期形成的方解石可以使颗粒呈嵌晶接触,形成致密层,但是这部分方解石量小且分布不均匀;④自生石英在纵向上变化明显,封闭体系中形成的SiO2由于绿泥石环边的抑制作用,以雏晶的形式产出;而半封闭体系中形成的SiO2可向上发生运移,在绿泥石环边不连续或欠发育的层段以加大边的形式产出。通过成岩体系研究,可以明确高效储层的形成机理,指导岩性油气藏的勘探。     

广西大瑶山地区加里东期石英脉型金矿：上木水金矿白云母Ar-Ar年龄约束

石英脉型金矿是广西大瑶山地区主要的金矿床类型之一,但一直没有高精度的年龄数据约束其成矿时代。论文首次 对大瑶山南部广西苍梧县上木水石英脉型金矿中的热液白云母进行39Ar/40Ar年龄法测年,获得坪年龄为（432.6 ± 3.2）Ma,相应 的等时线年龄为（428.2 ± 7.2）Ma,反等时线年龄为（425.3 ± 6.6）Ma,表明其成矿时代为加里东期。这一数据进一步证明 大瑶山南部的古龙-夏郢环形成矿区主要以加里东期矿化为主,除了与加里东期岩浆岩有关的斑岩-矽卡岩型钨多金属矿化 外,还存在石英脉型金矿。同时,位于大瑶山中部沿区域性大黎断裂分布的六岑-桃花-古袍金矿田的石英脉型金矿时代仍 然不明确,还需要进一步的高精度测年数据来约束。     

赣中聚源大型石英脉型白钨矿床含铀富钨矿物初步研究

聚源钨矿是华南地区为数不多的大型石英脉型白钨矿矿床之一。在详细的野外地质调查基础上,本文利用α径迹蚀刻、电子显微镜、扫描电镜以及电子探针等实验手段,对该矿床含钨和含铀矿物开展了精细矿物学的研究工作,探讨了成矿过程中钨和铀的富集规律。研究显示,该矿床钨铀矿物的形成可分为四个阶段：第一阶段,钨铀主要进入富含Nb、Ti的氧化物矿物,形成铌铁矿、钇易解石等富钨矿物,另有极少量的钨进入黑钨矿和早阶段白钨矿;第二阶段,铌铁矿与钇易解石被后期流体交代,形成含钨富铀的骑田岭矿、铌锰矿以及钛-钇易解石;第三阶段,钨进入中阶段白钨矿,这一阶段也是钨最主要的矿化阶段;第四阶段,钨进入晚阶段白钨矿。最后两阶段白钨矿中铀含量不高。骑田岭矿(WO₃ 26.74%~29.68%),是聚源钨矿中除白钨矿和黑钨矿之外钨含量最高的含钨矿物。该矿易解石族矿物WO₃最高可达9.80%,极度富钨,是目前有文可查的钨含量最高的易解石。聚源钨矿中的含钨矿物大多数为白钨矿,但绝大多数的白钨矿却在骑田岭矿、易解石族矿物、铌铁矿族矿物、黑钨矿之后形成,说明成矿流体在演化过程中,绝大多数W首先进入富含Nb、Ti的含铀矿物和少量黑钨矿,之后才是白钨矿的大量结晶。

     

Une approche innovante pour modéliser la biodégradation des composés organochlorés volatils en aquifères poreux

The goal of this study was to develop an innovative chloroethene biodegradation module based on biological, thermodynamical and mechanistic concepts. The biodegradation scheme was based on the postulate that in each part of an aquifer only one degradation mechanism is dominant: the one involving the most energetic electron acceptor. Thus, the selection of the active degradation mechanism was a function of the concentration of different electron acceptors. Modified Monod-type kinetics was used in order to take into account the possible influence of some compounds on the biodegradation of a given organic compound. The numerical model developed was applied to a simple test case, whose results are presented here. To cite this article: F. Nex et al., C. R. Geoscience 338 (2006).     

成矿溶液电导度和红外光谱在金矿找矿评价中的应用

电导度是溶液导电能力的相对尺度,电导度的大小能直接反映出成矿溶液浓度的高低.实验证明,成矿溶液相对高浓度聚集区,往往也是矿床的主矿体或富矿体赋存处.石英是刺猬沟和三道湾子金矿重要的脉石矿物,也是金的主要载体.借助于成矿溶液电导度和红外光谱方法对刺猬沟和三道湾子金矿区石英进行了分析.结果表明,成矿溶液电导度和红外光谱测定的DCO2与石英中Au含量呈正相关关系.成矿溶液电导度＞40.1μS,DCO2＞0.2矿化好.上述研究获得的信息对中生代陆相火山岩区寻找和评价石英脉型矿床具有指导意义.     

中天山东部南北两缘韧性剪切带变形特征

(1)中天山北缘韧性剪切带除右旋韧剪变形之外,还发育相对较弱的左旋韧剪变形,局部残留加里东晚期的逆冲推覆韧剪变形;右旋韧剪变形的变形温度环境为中-低温,左旋韧剪变形的变形温度环境为高温、中温、中低温及低温。(2)中天山南缘韧性剪切带以右旋韧剪变形为主,兼具左旋韧剪变形;右旋韧剪变形的变形温度环境为中温、中低温、低温,左旋韧剪变形的变形温度环境为高温、中温、中低温及低温。(3)东天山存在一系列右旋韧性剪切带,中天山南北两缘韧性剪切带的构造变形与辛格尔断裂、兴地断裂等右旋韧性剪切带的变形以及塔里木北缘东部晚震旦—早古生代地层的同劈理褶皱变形、南天山泥盆纪地层的变形可能具成因联系。