Determination of Platinum-Group Elements in Geological Reference Materials by High Resolution-ICP-MS after Nickel Sulfide Fire-Assay Collection and Te Co-Precipitation

Inductively coupled plasma-mass spectrometry (ICP-MS) after NiS fire assay-Te co-precipitation was employed in the determination of Ru, Rh, Pd, Os, Ir and Pt at ng g^-1 levels in six platinum-group element (PGE) geological reference materials. In general, the average of several results was in good agreement with the certified values taking into account respective uncertainties. High relative standard deviations were observed for the reference materials GPt-3 and GPt-4. Problems associated with the NiS fire assay procedure and PGE determination at the sub-10 ng g^-1 level are reviewed and discussed.     

Influence of gravelly exclusion on compaction of lateritic soils

This paper uses a deltaic lateritic soil sample to study the combined influence of total gravel composition and gravelly exclusion on compaction parameters MDD (or maximum dry density) and OMC (or optimum moisture content) derived from standard laboratory compaction tests. In the end, MDD was found to vary polynomially with percentage of gravelly exclusion with improved or higher values as total gravel composition increases. OMC on the other hand was found to decrease continually with increasing gravelly exclusion but independent of the total gravel composition. Also, a model was presented in form of a family of curves to predict actual or field compaction parameters (which is devoid of gravelly exclusion) and their laboratory counterparts. This revised version was published online in July 2006 with corrections to the Cover Date.     

喀拉通克铜镍矿物化探方法的应用效果

在1:20万航空磁测中仅发现小而弱的磁异常,在地表发现了铁帽,并在铁帽下发现了铜矿化的基性岩后,通过地表磁测,发现磁异常,经钻探发现了致密块状铜镍矿.选用重力、磁测、激发极化法及化探土壤测量等方法进行工作,获得明显的综合异常,指导了钻探工程的正确部署,钻到了工业矿体.     

淋溶时间对红黏土物理力学特性的影响

以湖北省鄂州市庙岭镇的红黏土为研究对象,以化学选择溶解法结合淋溶作用为处理手段,将原状土样中的游离氧化铁按梯度去除,获得连二亚硫酸钠-柠檬酸钠-碳酸氢钠(DCB)溶液淋溶时间与除铁率的关系,并分析了不同淋溶时间对红黏土物理力学特性及微观孔隙结构的影响。试验结果表明,DCB溶液淋溶时间与除铁率相关性较强,除铁率与时间呈先快速增长后逐渐稳定的关系。由于游离氧化铁在土颗粒间主要起胶结作用,故淋溶时间对红黏土的物理力学特性有较大影响。随着淋溶时间的增长,黏粒与胶粒含量逐渐增大,耐热性小幅提升,无侧限抗压强度显著减小,且无侧限抗压强度变化整体趋势为前期急剧降低至后期趋于平稳。核磁共振、差热分析和电镜扫描的结果表明,随着淋溶时间的增大,庙岭红黏土内部孔隙增大,自由水减少,结合水增多,微观形态上团粒结构遭到破坏,胶结物质明显减少,结构形式从紧凑的粒团堆叠结构逐渐转化为聚集体-松散颗粒状结构。     

基于中国需求的印度尼西亚镍资源产业投资前景分析

在分析中国的镍资源产量、消费历史、消费结构、未来需求趋势的基础上,详细介绍印尼镍资源情况,对比了印尼政府出台原矿禁止出口令前后镍矿、精炼镍、镍铁产量发生的变化状况,以及给印尼镍矿和镍铁出口和中国镍资源进口的影响。得出印尼镍资源丰富,镍矿开发活跃,原矿禁止出口政策不仅使本国镍资源出口贸易格局发生改变,也导致中国进口镍资源形势发生了变化。最后,提出中资企业在印尼投资镍资源的主要区域和领域,为企业在当地投资提供一定指导意义。     

新疆若羌坡北地区镁铁-超镁铁质侵入岩含矿特征及找矿方法探讨

新疆若羌坡北地区因发现了众多岩浆硫化物型镍矿而受到关注,坡一镍矿为近期发现评价的超大型岩浆硫化物型铜镍矿床.但未发现有规模的高品位富矿体,不能满足矿产开发的条件.文章从坡北镁铁-超镁铁岩带地质特征出发,对坡北地区已经发现的岩浆硫化物矿床含矿特征进行了归纳总结,分析岩体就位成矿有利部位,开展了富矿成矿预测.结合已经总结出的综合地质、物探、遥感、化探等的找矿方法组合,通过地质实践,取得了很好的找矿进展,首次在坡北一带发现了深熔贯入式镍矿床——坡东镍矿.     

A Preliminary Review of the Metallogenic Regularity of Nickel Deposits in China

The nickel deposits mainly distributed in 19 provinces and autonomous regions in China are 339 ore deposits/occurrences, including 4 super large-scale deposits, 14 large-scale deposits, 26 middle-scale deposits, 75 small-scale deposits, and 220 mineralized occurrences. The prediction types of mineral resources of nickel deposits are magmatic type, marine sedimentary type and regolith type. The formation age is from the Neoarchean to the Cenozoic with two peaks in the Neoproterozoic and the late Paleozoic. The nickel deposits formed in the Neoproterozoic are located on the margin of the North China Block and Yangtze Block, and those formed in the late Paleozoic are mainly distributed in the Central Asian Orogenic Belt (CAOB), Emeishan and the Tarim Large Igneous Provinces (LIPs). Magmatic nickel deposits are mainly related with broken-up continental margin, post-collision extension of the orogenic belt and mantle plume. According to different tectonic backgrounds and main characteristics of magmatism, the Ni-Cu-Co-PGE metallogenic series types of ore deposits related with mantle-derived mafic-ultramafic rocks can be divided into 4 subtypes: (1) the Ni-Cu-Co-PGE metallogenic series subtype of ore deposits related with mantle-derived mafic-ultramafic rocks in the broken-up continental margin, (2) the Ni-Cu-Co-PGE metallogenic series subtype of ore deposits related with mantle-derived mafic-ultramafic rocks in mantle plume magmatism, (3) the Ni-Cu-Co-PGE metallogenic series subtype of ore deposits related with mantle-derived mafic-ultramafic rocks in the subduction of the orogenic belt, and (4) the Ni-Cu-Co-PGE metallogenic series subtype of ore deposits related with mantle-derived mafic-ultramafic rocks in post-collision extension of the orogenic belt. We have discussed in this paper the typical characteristics and metallogenic models for Neoproterozoic Ni-Cu-(PGE) deposits related with broken-up continental margin, Cambrian marine sedimentary Ni-Mo-V deposits related with black shale, early Permian Ni-Cu deposits related with post-collision extension of the orogenic belt, late Permian Ni-Cu-(PGE) deposits related with Large Igneous Provinces (LIPs), and Cenozoic Ni-Au deposits related with regolith. The broken-up continental margin, mantle plume and post-collision extension of the orogenic belt are important ore-forming geological backgrounds, and the discordogenic fault, mafic-ultramafic intrusion, high MgO primitive magma (high-MgO basaltic magma), deep magmatism, sulfur saturation and sulfide segregation are 6 important geological conditions for the magmatic nickel deposits.     

氢氧化铁共沉淀电感耦合等离子体发射光谱法测卤水中的痕量钴镍锰

用氢氧化铁共沉淀分离卤水中的钴镍锰,用1+1的王水溶解沉淀定容,电感耦合等离子发射光谱法测定。检出限为LD(Co Mn)=0.10 mg/L,LD(Ni)=0.27 mg/L,加标回收率为95.00%～102.0%,精密度(n=12)为1.05%。结果表明,本方法快速准确,可以准确测定卤水中钴镍锰。     

旱耕赤红壤氮、磷流失污染研究

在设置可控条件下的模拟生态系统中研究了旱耕赤红壤的氮、磷流失污染特征,结果显示：旱地土壤随地表流水流失的氮量远大于磷;环境条件一致的情况下,旱地氮、磷污染物输出浓度与作物生育期及施肥时间有关。并指出旱地氮、磷流失可能是珠江广州河段氮、磷含量较高的原因之一