Laser Ablation ICP-MS Developments and Trends for 2003

This annual review of laser-ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS) covers the year 2003. Significant advances were made in understanding laser-sample interactions. In particular, research defined the distribution of particle sizes produced by the interplay of laser wavelength, laser pulse width and the gas environment of ablation. A link between particle sizes and elemental and isotopic fractionation at both the ablation site and in the ICP was established. Experimental 15 7 nm and femtosecond laser systems were tested with promising results. The number of applications of LA-ICP-MS in geology and environmental Earth science continued to grow with particular interest in element concentration and isotope ratio profiling of materials, linking composition to time scales. In situ isotopic ratio measurements were increasingly made using multicollector magnetic sector ICP-MS instruments. Other applications of wide interest included bulk sampling of rocks and ores prepared as lithium borate glasses; low level analysis of platinum-group elements, rhenium and gold in sulfides, metal and silicates; in situ uranium-lead zircon geochronology; and melt and fluid inclusion analysis.     

Determination of Lithium, Beryllium and Boron at Trace Levels by Laser Ablation-Inductively Coupled Plasma-Sector Field Mass Spectrometry

The analytical capabilities of laser ablation (LA)-ICP-MS in determining Li, Be and B at trace levels in geological samples have been tested on a series of glass reference materials and natural samples. The LA-ICP-MS instrument used consisted of a sector-field ICP-MS coupled with a laser ablation microprobe operating at either 266 or 213 nm wavelength. Reference glasses from NIST (SRM 612, 614 and 616) and MPI-DING (KL2-G, ML3B-G, StHs6/80-G, GOR128-G, GOR132-G, T1-G and ATHO-G) were selected to develop the analytical method and to assess the best instrumental configuration. A series of calcic amphiboles with different Li, Be and B concentrations were also analysed using both LA-ICP-MS and SIMS to test the applicability of the method to natural minerals. Results indicated that with a spot size of 40 μm the agreement between measured and reference values of Li, Be and B is generally better than 10% for NIST SRM 612 and 20% for NIST SRM 614. Average reproducibility at the 2s level was 10% for Li, 20% for Be and 15% for B. Limits of detection were approximately 100 ng g^-1 for Be and B and 200 ng g^-1 for Li. These results were confirmed by analyses carried out on natural amphiboles and compared well in terms of precision and accuracy with those commonly achieved by SIMS.     

Preliminary Characterisation of New Glass Reference Materials (GSA-1G, GSC-1G, GSD-1G and GSE-1G) by Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry Using 193 nm, 213 nm and 266 nm Wavelengths

New glass reference materials GSA-1G, GSC-1G, GSD-1G and GSE-1G have been characterised using a prototype solid state laser ablation system capable of producing wavelengths of 193 nm, 213 nm and 266 nm. This system allowed comparison of the effects of different laser wavelengths under nearly identical ablation and ICP operating conditions. The wavelengths 213 nm and 266 nm were also used at higher energy densities to evaluate the influence of energy density on quantitative analysis. In addition, the glass reference materials were analysed using commercially available 266 nm Nd:YAG and 193 nm ArF excimer lasers. Laser ablation analysis was carried out using both single spot and scanning mode ablation. Using laser ablation ICP-MS, concentrations of fifty-eight elements were determined with external calibration to the NIST SRM 610 glass reference material. Instead of applying the more common internal standardisation procedure, the total concentration of all element oxide concentrations was normalised to 100%. Major element concentrations were compared with those determined by electron microprobe. In addition to NIST SRM 610 for external calibration, USGS BCR-2G was used as a more closely matrix-matched reference material in order to compare the effect of matrix-matched and non matrix-matched calibration on quantitative analysis. The results show that the various laser wavelengths and energy densities applied produced similar results, with the exception of scanning mode ablation at 266 nm without matrix-matched calibration where deviations up to 60% from the average were found. However, results acquired using a scanning mode with a matrix-matched calibration agreed with results obtained by spot analysis. The increased abundance of large particles produced when using a scanning ablation mode with NIST SRM 610, is responsible for elemental fractionation effects caused by incomplete vaporisation of large particles in the ICP.     

Microcrack networks in granite affected by a fault zone: Visualization by confocal laser scanning microscopy

Microcracks in the Cretaceous Ryoke-type granite in Japan were investigated by using deep drilling core samples collected in the Mizunami Underground Research Project of the Japan Nuclear Cycle Development Institute (JNC). The granite body suffered brittle deformation associated with Tertiary thrust movement. Based on core-scale and microscopic deformation features, the drill core from a depth of 300 to 700 m is divided into four domains, i.e. (A) undeformed granite, (B) granite intruded by cataclastic seams, (C) fractured granite in the fault damage zone, and (D) foliated cataclasite at the fault center. To characterize microcrack geometries in each domain, we employed the impregnation method using a low-viscous acrylic resin doped with fluorescent agents and captured the microcrack images by confocal laser scanning microscopy (CLSM). The CLSM image in the fault damage zone revealed anisotropic development of microcrack networks related to the fault movement. Both CLSM observation and porosity measurements reveal a drastic increase of micro-pores in the foliated cataclasite, possibly caused by fragmentation, and granulation and crack sealing in the fault zone.     

利用3S技术及三维激光扫描仪进行耕地损毁勘测

利用RS技术发现耕地损毁,网络RTK测量耕地损毁范围及面积,GIS提取耕地被损毁前的分类面积和等别,以及利用网络RTK配合Maptek I-Site8810三维激光扫描仪重构损毁耕地三维模型。     

地面三维激光扫描仪测量误差检定

在利用三维激光扫描仪进行测量工作前,我们首先应了解其实际测量精度是否符合标称精度,而可靠的评价方式对得到精确的数据结果至关重要。本文利用北京卓立汉光TSA50-C型电动位移台作为评价标准,通过其精确的位移功能,准确地评价了RIGEL VZ-400三维激光扫描仪在测量单点位移时的误差,从而得到了其最佳工作距离。     

三维激光扫描技术在曲面模型重建中的应用

利用地面三维激光扫描仪对目标物体表面进行多方位、多角度的扫描,可以获取其表面大量且密集的高精度点的三维坐标信息以及反射率信息,将这些信息存储到电脑中,使用专业软件进行处理,再使用建模软件生成建筑物的三维模型。本文所研究的是使用地面三维激光扫描仪,通过高速激光测量方式,快速、全面、精确地获取建筑物表面的三维信息,经过一系列的点云数据处理及模型处理,最终完成曲面模型三维重建的过程。     

浅析运营期间电力隧道自动化监测技术

针对城市电力隧道结构、走向多变、电缆设施多、电磁干扰大等因素,常规的监测方法难以顺利完成的现状,对目前先进的3种隧道结构自动化监测系统进行深入的研究比较,光纤传感自动技术解决了电力隧道结构监测点布设困难,数据受电磁干扰大的问题,能实时有效、可靠、高精度地监控电力隧道,及时掌握隧道的应力、应变及振动等主要结构参数,确保隧道结构安全。研究对类似的城市电力隧道自动化监测具有一定的参考意义。     

基于3D激光扫描的变形监测技术研究

传统基于GPS和全站仪的地表变形监测手段由于监测点少,难以对滑坡体进行整体监测,本文提出基于点云所成模型间比较的变形信息提取方法,结合试验验证了算法的效果。结果表明,地面三维激光扫描技术应用于变形监测领域是完全可行的,虽然其在测量精度上略低于GPS、全站仪等传统监测手段,但对大范围区域快速、连续、全方位监测的优势是其他监测手段所不具备的。