氢化物发生—原子荧光光谱法测定煤样中的硒

采用氢化物发生原子荧光光谱法测定了煤样中的总Se。煤样选用高压闷罐强酸消解的方法进行处理，所得消解液经6mol/L HCl将Se（Ⅵ）还原为Se（Ⅳ），然后进行测定。标准工作曲线的线性范围为0－400μg/L Se，检测限为0.4μg/L Se。用标准参考物质煤飞灰对方法进行了验证，所得总Se含量与标准值相符，对ω为10^-6级Se的4次测定，RSD≤4.5％。     

N同位素质谱分析及其数据处理

本文论述了N同位素质谱分析原理和钢瓶高纯氮标定方法。同时对影响N同位素分析分馏因素作了相应讨论，指出钢瓶子高纯氮同位素标定，要用纯化后的大气氮定值。     

SCM链路中激光器对副载波调制频率的响应特性研究

着重讨论激光器对内调制模拟信号频率的响应特性，定量分析光子密度的幅值及相位对模拟激励信号频率的依赖关系，给出特征参数和曲线，供模拟系统设计者参考。     

三维旋转扫描测量平台设计与实现

本设计主要用于360°旋转的三维扫描,实现角度数据的实时获取。设计中采用单片机控制交流伺服电机进行自定的角度、速度与方向的旋转并实时上传时间、角度数据至上位机进行处理,实现了对平台旋转精度的控制与检测,着重研究了该传感器误差源的产生,对实际应用中的误差进行了定量分析,利用偏心改正、4分频等方法减少了误差,提高了参数精度。角度范围为360°,角度分辨率为0.01°。     

常压混酸溶矿一电感耦合等离子体发射光谱法测定铌钽

混酸溶解矿石样品,在酒石酸介质中,用电感耦合等离子体发生光谱法(ICP-AES)测定溶液中的铌钽。该方法ρ(Nb₂O₅)和ρ(Ta₂O₅)在0～20 μg/mL时,铌钽原子发射光谱强度与浓度呈良好的直线关系,Nb、Ta标准曲线相关系数尺分别为0.999 9和0.999 7。检出限分别为0.023 μg/mL和0.072 μg/mL。本方法测定标准样品,测定值与认定值相符。对实际样品分析,Nh、Ta的相对标准偏差(n=6)分别为0.42％～2.3％和1.8％～3.3％,加标回收率均为97％～103％,适合地质找矿、选冶等领域的样品测试。     

2010—2020年黄河下游河南典型灌区浅层地下水中砷和氟的演化特征及变化机制

黄河下游典型灌区河南段是豫北平原重要的农业种植区。该地区浅层水质整体较差,因常用于作物灌溉或家畜饮用,会对人体健康产生风险,因此对该地区地下水中砷与氟浓度变化特征和机制的研究将有助于提高对该地区地下水污染的认识水平。本文基于2010年和2020年在灌区范围内采集的327组浅层地下水样品,研究区内地下水砷和氟分布情况,并在此基础上对比研究十年间灌区浅层地下水中砷、氟的演化特征,探索分析砷与氟浓度及空间变化机制。研究结果表明：该地区浅层地下水中存在砷与氟超标问题,2020年浅层地下水中高砷（砷浓度大于10μg/L）和高氟（氟浓度大于1mg/L）的样品数量分别占总数的26.1%和26.06%。高砷水分布在太行山前洼地与黄河冲积平原等泥沙互层结构的沉积环境中,还原性较强,同时地下水径流不畅,较强的阳离子交换作用使得其所处环境中Ca2+浓度较高。近十年间砷浓度增加的水样占总数31.8%,砷浓度减少的水样占36.7%。砷浓度的增长（减少）是地下水还原性增强（减弱）使得锰氧化物溶解释放（吸附）导致。近十年间不同地区农业灌溉和水源置换等用水方式导致水位变化是引起砷浓度变化的潜在因素。高氟水主要分布在河南新乡与濮阳的黄河沿线,氟离子浓度受到沉积物中萤石等钙质矿物溶解影响,使得高氟地下水出现在低钙环境中。近十年间研究区中氟离子浓度减少的占总数60.2%,氟离子浓度增加的占32.1%,整体变化趋势向好,但是高氟区中氟离子浓度继续增加。氟浓度的变化同样受到Ca2+变化影响,在Ca2+浓度降低（升高）时氟浓度进一步升高（降低）。地下水中氟升高地区分布在黄河沿线,因此受到黄河水补给影响较大,地下水径流条件较好,阳离子交换作用减弱,使得Ca2+浓度降低,此时地下水中砷浓度受到环境影响而降低,因此研究区氟增加地区中砷与氟的分布和演化呈现反向关系。     

Determination of the REE in Geological Reference Materials DTS-1 (Dunite) and PCC-1 (Peridotite) by Ultrasonic and Microconcentric Desolvating Nebulisation ICP-MS

Inductively coupled plasma-mass spectrometry is well suited for the precise, accurate and rapid determination of rare earth elements in most geological samples. However, determination of rare earth elements in certain mantle-derived materials, without applying preconcentration techniques, remains problematical due to low natural concentrations (generally < 1 ng g⁻¹). Consequently, USGS reference materials DTS-1 (a dunite) and PCC-1 (a partially serpentinized harzburgite) have only suggested rather than recommended values for the rare earth elements in reference material compilations. We compared results obtained using two ICP-MS instruments: a U-5000AT ultrasonic nebuliser coupled to a PQ2+ quadrupole ICP-MS and an ELEMENT sector field ICP-MS equipped with a MCN-6000 microconcentric desolvating nebuliser, with the suggested literature values for these two reference materials. Precision and accuracy of analytical methods employed by both instruments were demonstrated by excellent relative standard deviations (< 2%) and inter-laboratory agreement (< 5%) for numerous analyses of BHVO-1 and BIR-1, which are well established with rare earth elements contents at the μg g⁻¹ level. Repeat analyses of DTS-1 and PCC-1 at each laboratory indicate that each method is generally precise to better than 5% at sub-g g⁻¹ levels. Furthermore, values from both instruments generally agree to within 10%. Our DTS-1 and PCC-1 values agree reasonably well with selected data reported in the literature (except for Ce and Sm in DTS-1) but exhibit poorer agreement with reported compilation values. With the demonstrated level of precision and accuracy, we contend that these new values for DTS-1 and PCC-1, generated by two different instruments, are the best estimates of the true whole-rock composition of these samples reported to date.     

3D SLAM的室内背包移动测量系统研究

针对室内移动测图中GPS信号缺失,导致无法获取精确定位坐标与导航的问题,该文研发了一套室内背包式移动测量系统,该系统能够利用三维激光定位与测图的方法实现快速同步定位及地图创建和室内三维激光点云获取,可以应用在室内或地下的环境中进行数据采集,在不损失作业效率的前提下获取系统作业轨迹、高精度点云等多种数据结果。为了对系统的精度进行验证,使用该系统在实验室大楼走廊中进行实验获取室内三维激光点云,并将实验结果与采用常规测量手段得到的结果进行对比分析。实验表明,此系统的相对精度和绝对精度分别能够达到0.048和0.047m,在室内三维信息获取过程中相比较于传统作业方式显著提高了作业效率和数据质量,能够满足室内建模与测图要求。     

不均匀植被分布对地表面和大气边界层影响的数值试验

研究陆地与大气间相互作用的方法之一是建立联系地表面层与大气间各种过程的数值模式进行模拟。本文是建立一个陆面过程与二维大气边界层相耦合的模式,耦合模式中包含了发生在大气边界层、植被冠层和土壤表层各种动力、热力和水文过程。运用这一模式模拟了荒漠环境中一片绿洲的不均匀地表面形成的局地气候。由于绿洲植被与周围荒漠有着显著不同的水份与能量平衡关系,使绿洲表面与边界层较四周荒漠冷而湿,并形成了相应的局地环流,即所谓“绿洲效应”。试验结果表明,模拟的气候状况与观测现象是一致的。模式可以用于陆气相互作用的研究。     

Associations of decimetric type Ⅲ bursts with coronal mass ejections and Hα flares

We present a statistical study of decimetric type Ⅲ radio bursts,coronal mass ejections(CMEs),and Hα flares observed in the period from July 2000 to March2005.In total,we investigated 395 decimetric type Ⅲ radio burst events,21% of which showed apparent correlation to CMEs that were associated with Hα flares.We noticed that the Hα flares which were strongly associated with CMEs were gradual events,and82% of them took place before CMEs appeared in the field of view of LASCO C2;that most of the CME-associated radio bursts started in the frequency range around750 MHz with a frequency drifting rate of several hundred MHz s-1,of which both positive and negative ones were recognized; and that the correlation of type Ⅲ radio bursts to CMEs without associated flares is fairly vague,less than 9%.