Identification and occurrence of novel C36–C54 3,4-dialkylthiophenes with an unusual carbon skeleton in immature sediments

A series of novel long-chain 3,4-dialkylthiophenes (C₃₆–C₅₄) was identified in a number of sediments ranging from Pleistocene to Cretaceous. The identifications were based on mass spectral characterisation, desulphurisation and mass spectral data of synthesised model compounds. These organic sulphur compounds are probably formed by sulphur incorporation into mid-chain dimethylalkadienes with two methylenic double bonds. These putative precursor lipids are unprecedented and may be considered rather unusual. The distribution of 3,4-dialkylthiophenes in sediments varies considerably with the depositional palaeoenvironment, indicating that these compounds have a potential as molecular markers reflecting changes in palaeoenvironment.     

An Acetic Acid‐Based Extraction Protocol for the Recovery of U,Th and Pb from Calcium Carbonates for U‐(Th)‐Pb Geochronology

A new method for the simultaneous recovery of U, Th and Pb from ca. 0.5 g calcium carbonate samples for the purpose of U‐(Th)‐Pb geochronometry is presented. The protocol employs ion‐exchange chromatography. Standard anion exchange resin (AG 1‐X8 100–200 mesh) was used as the static phase, and 90% acetic acid was used as the mobile phase to elute the unwanted matrix components; dilute nitric acid was used to elute the U, Th and Pb. Blanks of 1.8 pg Th, 6.4 pg Pb and 8.4 pg U were obtained. The protocol was evaluated by determining the isotopic composition of U‐Th‐Pb separates obtained from an in‐house reference material (prepared from a natural speleothem) by MC‐ICP‐MS. An independently dated speleothem was also reanalysed. Based on these tests, the extraction protocol had an acceptable blank and produced a Pb separate sufficiently free of matrix‐induced instrumental biases to be appropriate for U‐Th‐Pb chronology.     

基于激光点云数据的古建筑BIM几何模型构建

针对古建筑BIM各种信息模型中几何模型构建的问题,提出应用三维激光点云数据和CloudWorx软件进行建模的方法。应用Cyclone软件对点云数据进行去噪、配准,按构件进行分割;应用CloudWorx软件进行模型的构建。研究古建筑的瓦片、柱体、梁、墙体、围栏等构件的建模方法,通过模型合并生成古建筑的整体几何模型。     

新疆伊犁尼勒克地区树轮宽度年表特征分析

通过对尼勒克地区3个树轮宽度标准化年表有关参数的对比分析,证明萨克巴依顿年表和唐布拉年表比霍仕布拉克年表包含更多的气候信息。将这3个树轮宽度标准化年表与附近的尼勒克气象站1960--2008年月平均降水组合资料进行相关分析,结果表明：尼勒克3个树轮宽度标准化年表的年轮指数与尼勒克地区上年7—8月的降水呈显著正相关,其中唐布拉年表（TBL）的年轮指数与上年7—8月降水相关最佳,相关系数为0．575,达0．00002的极显著性水平,且二者的正相关具有明确的树木生理学意义。研究还发现,尼勒克3个树轮宽度标准化年表的低频信息含量均多于高频信息的含量,在0．05显著性水平上,普遍存在2～3a的变化准周期,且平均年表存在7个高指数阶段和7个低指数阶段。     

基于EPS平台的地面三维激光扫描点云数据处理方法探讨

三维激光扫描技术是通过大量密集的扫描点,以模拟形式体现目标实体对象表面丰富的形体信息,不能获取的点云数据直接读取目标对象的矢量化信息,并进行点云数据处理。笔者在工作中,以EPS2008软件平台为基础,利用VBScript脚本进行二次开发,实现了点云数据分层提取、点云线状地物提取、点云特征轮廓提取、点云数据断面提取和点云高程提取等功能。本文针对已经实现的功能进行探讨,指出每种方法的特点和应用范围。     

Tectonic evolution of the Late Paleozoic Early Mesozoic orogenic belt in the eastern segment of the northern margin of the North China Block: Evidence from meta volcanic rocks of Jianshanzi,northern Liaoning ProvinceSCIEI北大核心CSCD

LA-ICP-MS U-Pb dating, whole -rock geochemistry and Hf isotopic analyses for the Jianshanzi volcanic rocks in the Kaiyuan area are presented to explore the Late Paleozoic -Early Mesozoic tectonic evolution history of the eastern segment of the northern margin of the North China block. The detailed research indicates that the protolith of Jianshanzi metamorphic volcanic rocks includes rhyolite, dacite and andesite, they are calc-alkaline series and metaluminous-weak peraluminous rocks. According to the zircon U-Pb dating, the metamorphic rhyolite and metamorphic andesite formed in the Late Permian (256. 1 +/- 1. 5Ma, 252.4 +/- 1. 7Ma) and the Late Triassic (222. 4 +/- 1. 8Ma, 227. 9 +/- 1. 2Ma), respectively. They are characteristized by enrichment in light rare earth elements and large ion lithophile elements, and depletion of heavy rare earth elements and high field strength elements. Metamorphic rhyolite has an obvious negative Eu anomaly with epsilon(Hf) ( t) values of 10. 83 + 8. 10 and the second -stage model are 698 similar to 1967Ma. They are mainly due to the partial melting of the juvenile basaltic lower crust and the contamination of a small amount of ancient crustal materials. Metamorphic andesite has no obvious Eu anomaly, and the epsilon(Hf)( t) value and the second -stage model are +4.54 similar to + 6. 79 and 825 similar to 968 Ma, which may be the product of partial melting of basic lower crust. There are two periods of magmatism in Jianshanzi volcanic rocks: Late Permian -Early Triassic (247 similar to 256Ma) and Late Triassic (similar to 225Ma). The material composition of the Jianshanzi volcanic rocks is characterized by different times and different tectonic backgrounds. It is comprehensively believed that the eastern segment of the northern margin of the North China block was in an active continental margin tectonic environment during the Permian, and the Palaeo-Asian Ocean subducted in both directions; Mantle -derived magma ascends and emplaces, forming a nascent crust and causing crustal thickening. The Paleo-Asian Ocean finally closed in the early Middle Triassic, and the impact of collisional orogeny may have continued until the early Late Triassic.     

新疆西准噶尔红山岩体及其中闪长质岩墙的时代——来自锆石LA-ICP-MS定年的证据

作为一种特殊产状的岩浆岩,岩墙保存有岩浆活动和地球动力学背景等方面的重要信息。为了研究和探讨西准噶尔乃至中亚地区古生代晚期的地球动力学环境,我们对西准噶尔地区侵入花岗岩的暗色岩墙开展了卫星遥感影像解译、地表地质调查和相关室内研究工作。研究发现,新疆西准噶尔红山花岗岩体中发育大量环状和非环状闪长岩岩墙。环状岩墙从中心到外围,岩墙宽度逐渐变窄,矿物粒度也逐渐变细;非环状岩墙切割环状岩墙,宽度和矿物粒度都没有明显变化。为了确定这些岩墙的形成时代,对3个环状岩墙样品、2个非环状岩墙和1个花岗岩样品进行了锆石LA-ICP-MSU-Pb定年,得到环状岩墙的年龄为:304±1Ma、302±1Ma、303±1Ma;非环状岩墙的年龄为:302±1Ma、302±1Ma;花岗岩的年龄为304±1Ma。结合不同类型岩墙及其与岩体的穿切关系,确定红山岩体的形成时代为304Ma左右,环状岩墙的形成时代为303Ma左右,非环状岩墙的形成时代为302Ma左右。这一年代学研究成果揭示出西准噶尔地区在石炭纪末期发育不同类型的岩浆活动,闪长质岩墙所占据的裂隙是在石炭纪末期形成的;为从岩浆活动和由这些岩墙所占据的裂隙研究,探讨该区古生代晚期的地球动力学环境,提供了有力的时间约束。     

基于三维激光扫描的地铁隧道连续形变监测数据处理软件系统

利用地基三维激光扫描技术所具有的“形测量”特点,结合高精度、高空间分辨率的多时相点云数据,实现地铁隧道连续形变监测数据处理的软件系统。系统的主要功能包括：点云拼接、隧道中轴线拟合、断面连续截取、形变分析以及成果输出等。结合对上海某地铁隧道的多期激光扫描数据的处理,展示软件的主要功能和技术流程,最后对系统的应用前景进行阐述。     

Decumbent development: Urban sprawl in the Guwahati Metropolitan Area,India

Urban sprawl has become a global phenomenon as an outcome of growing population and rapid urbanization. Previous studies have addressed the rising incidence of uncontrollable urban development, particularly in peri-urban areas of cities, leading to chronic urban sprawl. The city of Guwahati, a million city in north east India, has expanded significantly in recent years. In this article, the links between population and growth of built-up areas were examined using geo-spatial techniques and remotely sensed datasets. The results indicate that the sprawl has accentuated in recent years. The intensity of land use remained uneven due to marked variations in the distribution of built-up areas, plausibly an outcome of unplanned urban growth. If current trends are anything to go by, future urban sprawl could pose serious threats to the vulnerable eco-sensitive and peri-urban areas of Guwahati. Secondary cities have unfortunately received scant attention in urban policy research, and Guwahati, epitomizes urban woes in a developing country.     

1.5 μm波长n-p-n型InGaAsP-InP晶体管激光器材料外延生长

基于器件模拟仿真,设计了一种1.5 μm波长InGaAsP-InP晶体管激光器材料外延结构. 其多量子阱有源区置于基区非对称波导中. 仿真结果显示该外延结构能够获得较好的光场限制和侧向电流限制. 对该材料MOCVD生长研究表明,基极重掺杂接触层中Zn²⁺扩散将导致量子阱严重退化. 通过对其扩散过程的模拟仿真,采用平均掺杂浓度为1×10¹⁸ cm^-3的梯度掺杂,有效地抑制了Zn²⁺向量子阱区的扩散. 所获得的外延材料在