俄罗斯贝加尔湖北部 Yoko-Dovyren 层状纯橄岩-橄长岩-辉长岩地块: 结构、成分以及作为矿物原材料的用途

Yoko-Dovyren层状纯橄岩-橄长岩-辉长岩地块位于西伯利亚克拉通南部的一处褶皱构造框架中(俄罗斯贝加尔湖地区北部)。该地块的结构在其厚度最大的中部得到了着重研究。剖面底部主体成分为斜长橄榄岩,并依据内部的堆晶成分变化从下往上可分为五个主要的地层序列:纯橄岩→橄长岩→橄榄辉长岩→橄榄辉长苏长岩→石英辉长苏长岩以及含易变辉石的辉长岩。该地块的矿化包括铜-镍矿化、低硫型富铂族元素(PGE)矿化以及铬铁矿化等。另外,该地块也含多种非金属矿物原材料,如硼矿化、透辉石、各种镁质硅酸盐岩等。它们也包括纯橄岩、异剥橄榄岩和橄长岩,并以较高的品质产出,有望采掘加工成为建筑材料(水泥、混凝土、沥青混凝土和建筑陶瓷)。综合利用矿物原材料可增加矿床价值,并有助于建设环保型采矿工作体系。     

Zn/Cd ratios in calcsilicate-hosted sphalerite ores at Tumurtijn-ovoo, Mongolia

As other calcsilicate-hosted ore deposits the Tumurtijn-ovoo Fe–Mn–Zn deposit is subdued to the question how the ore elements took place, whether linked to epigenetic silicification of a limestone host or bound to syngenetic precipitation during the deposition of a calcareous-siliceous sediment. The comparison of high Zn/Cd ratios of ores from Tumurtijn-ovoo ranging from 514 to 724 with those of other ore deposits relates Tumurtijn-ovoo to the group of submarine hydrothermal deposits which got their ore elements from basaltic source rocks by subseafloor leaching. Hence, respecting geological and textural features of the ores, a synsedimentary precipitation of zinc and cadmium in a volcano-sedimentary environment is suggested for Tumurtijn-ovoo. A group of low Zn/Cd ratios (274–297) is correlated with processes of mobilization and redeposition of sphalerite.     

浅析贵州二叠系锰矿与峨眉山玄武岩之关系

贵州遵义-水城地区中二叠纪茅口组第二段顶部产出的原生碳酸锰和氧化锰矿床,为贵州二叠系锰矿主要矿床。贵州中西部有大量的峨眉山玄武岩分布。本文就贵州二叠系锰矿与峨眉山玄武岩之关系进行探讨。     

A Novel Approach in Hydrogeochemical Exploration for Uranium Mineralization: an Example from West Central Sinai, Egypt

Groundwater in contact with ore deposits may acquire a chemical composition that could be used as a guide for exploration. Eight well-water samples are collected from a known uranium-mineralized area near Abu Zenima, west central Sinai to examine the applicability of using the hydrogeochemical technique in the search for uranium mineralization in similar arid areas. The analytical chemical data of the ground water is compared with ground radiometric measurements. The obtained results indicate that groundwater affected by uranium mineralization has a specific relativity of major anions expressed essentially as SO4>Cl>HCO3 and to a lesser extent as Cl>SO4>HCO3, associated as a rule with low magnesium content. This association constitutes a signature of uranium mineralization on the composition of groundwater in west central Sinai and could be used as an important exploration guide in the search for uranium deposits in similar areas. Anomalies in Ni, Fe, Zn and Cr and other pathfinder elements in groundwater can furnish geochemical guides to uranium ores. The immobile trace element anomalies, including Zn, Ni and Fe are strongly distributed near the orebody; whereas the relatively mobile trace elements, including Co, U, V and Cr, constitute the dispersion haloes away from the orebody. A new hydrogeochemical discrimination diagram is constructed to be used as a quick and cost effective exploration tool in the search for uranium occurrences in environmentally similar arid areas. Based on the obtained results, a new site for uranium occurrence, west of W. Baba, is delineated and recommended for future detailed geological and geochemical surveying.     

青海大柴旦地区低品位硼矿富集加工技术创新效果分析

青海省大柴旦地区是我国硼资源主要产地之一,经数十年的开采,矿体中富矿已基本枯竭。通过对大柴旦地区硼资源的分析,重点介绍了分级富集与沉矿浮选联合流程法和直接分级法两种低品位硼矿富集技术,同时对两种技术的内容、路线以及创新效果进行了讨论,并由创新效果的比较分析,得出两种方法的优点和创新性,同时提出对未来低品位硼矿富集技术的展望。     

内蒙古中部地区中-新元古代黑色岩系中的金矿床及找矿远景

内蒙古中部地区中—新元古代黑色岩系发育,形成于渣尔泰-白云鄂博裂陷槽内,命名为渣尔泰群和白云鄂博群。目前,仅在白云鄂博群的黑色岩系中发现并勘查了一批原生金矿。矿石主要类型为细脉型和蚀变变质岩型。金矿受层位和构造破碎带控制,金平均品位低,可形成大型或超大型矿床。因此,内蒙古中部中—新元古代黑色岩系中金矿资源潜力大,找矿远景好。     

福建德化吉溪铅锌多金属矿异常区地质特征及找矿远景分析

德化吉溪铅锌多金属矿异常位于溪口组中,其Ⅳ号蚀变体(矽卡岩)、V号蚀变体(铅锌矿化脉)均分布在接触带附近.区内断裂是较好的导矿储矿构造,与Pb、Zn异常关系密切.通过对异常区地球化学特征及成矿地质条件等分析,认为该区有一定找矿远景.     

内蒙古赤峰柴胡栏子金矿及周边地区构造形迹的“米字型”分布及其控矿特征

柴胡栏子金矿位于中国东部大兴安岭北北东向构造带与华北地块北缘近东西向构造带的交汇部位。该交汇区经历了多期构造-岩浆活动,产出了柴胡栏子、莲花山、红花沟等多个大-中型金矿床。航磁和遥感资料解译结果表明,矿田内发育北北西向、北西西向、北北东向和北东东向共4个方向的构造形迹,呈现“米字型”结构的展布特点,分别控制了晚古生代岩浆岩(脉岩)和主要金矿床的展布。在柴胡栏子金矿区,4个方向的构造形迹也组成了“米字型”结构,控制了矿体(矿化带)和化探异常的展布。矿田和矿区级别的构造形迹均呈现“米字型”分布特点,是新华夏构造体系分级控岩控矿规律的具体表现。上述认识为矿床成因研究和矿田成矿预测提供了重要的依据。     

Petrological and Geochemical Constraints on the Protoliths of Serpentine‐Magnetite Ores in the Zhaoanzhuang Iron Deposit,Southern North China Craton

The uncommon Mg-rich and Ti-poor Zhaoanzhuang serpentine-magnetite ores within Taihua Group of the North China Craton(NCC) remain unclear whether the protolith was sourced from ultramafic rocks or chemical sedimentary sequences. Here we present integrated petrographic and geochemical studies to characterize the protoliths and to gain insights on the ore-forming processes. Iron ores mainly contain low-Ti magnetite(TiO_2 ~0.1 wt%) and serpentine(Mg#=92.42–96.55), as well as residual olivine(Fo=89–90), orthopyroxene(En=89–90) and hornblende. Magnetite in the iron ores shows lower Al, Sc, Ti, Cr, Zn relative to that from ultramafic Fe-Ti-V iron ores, but similar to that from metamorphic chemical sedimentary iron deposit. In addition, interstitial minerals of dolomite, calcite, apatite and anhydrite are intergrown with magnetite and serpentine, revealing they were metamorphic, but not magmatic or late hydrothermal minerals. Wall rocks principally contain magnesian silicates of olivine(Fo=83–87), orthopyroxene(En=82–86), humite(Mg#=82–84) and hornblende [XMg=0.87–0.96]. Dolomite, apatite and anhydrite together with minor magnetite, thorianite(Th-rich oxide) and monazite(LREE-rich phosphate) are often seen as relicts or inclusions within magnesian silicates in the wall rocks, revealing that they were primary or earlier metamorphic minerals than magnesian silicates. And olivine exists as subhedral interstitial texture between hornblende, which shows later formation of olivine than hornblende and does not conform with sequence of magmatic crystallization. All these mineralogical features thus bias towards their metamorphic, rather than magmatic origin. The dominant chemical components of the iron ores are SiO_2(4.77–25.23 wt%), Fe_2O_3 T(32.9–80.39 wt%) and MgO(5.72–27.17 wt%) and uniformly, those of the wall rocks are also SiO_2(16.34–48.72 wt%), Mg O(16.71–33.97 wt%) and Fe_2O_3 T(6.98–30.92 wt%). The striking high Fe-Mg-Si contents reveal that protolith of the Zhaoanzhuang iron deposit was more likely to be chemical sedimentary rocks. The distinct high-Mg feature and presence of abundant anhydrite possibly indicate it primarily precipitated in a confined seawater basin under an evaporitic environment. Besides, higher contents of Al, Ti, P, Th, U, Pb, REE relative to other Precambrian iron-rich chemical precipitates(BIF) suggest some clastic terrestrial materials were probably input. As a result, we think the Zhaoanzhuang iron deposit had experienced the initial Fe-Mg-Si marine precipitation, followed by further Mg enrichment through marine evaporated process, subsequent high-grade metamorphism and late-stage hydrothermal fluid modification.     

火焰原子吸收光谱法和电感耦合等离子体发射光谱法测定硫化矿中的银铜铅锌

过渡金属Cu、Co、Ni、Zn、Pb等及贵金属元素(铂族元素和Au、Ag)高度富集在硫化物中,尤其是富集在岩浆硫化物中,常形成具有工业开采价值的矿产,因而硫化物矿物具有重大的经济价值。而硫化物矿种类多,不同类型硫化物矿中Ag、Cu、Pb、Zn含量高低不同,有些被强酸分解不完全,产生沉淀,导致检测结果波动性较大、精密度偏低。本文针对含黄铁矿、铅和铜分别以方铅矿和黄铜矿形式存在的较难溶的硫化物矿,在矿样中先加盐酸加热除硫后,再用硝酸-氢氟酸-高氯酸三种强酸分解,以新配制的王水提取,使该类样品获得了理想的分解效果,特别是对银、铅含量较高的样品分解效果改善较显著。试液用火焰原子吸收光谱和电感耦合等离子体发射光谱都能准确测定Ag、Cu、Pb、Zn,两种方法的相对误差在±2.32%以内,测定值基本一致,相对标准偏差(RSD,n=12)均小于3.5%,四个元素的检出限均低于0.0090!g/m L,低于文献检出限。