Laboratory sulfurisation of the marine microalga Nannochloropsis salina

To understand more fully the mode of preservation of organic matter in marine sediments, laboratory sulfurisation of intact cells of the cultured microalga Nannochloropsis salina was performed using inorganic polysulfides in seawater at 50°C. Solvent extractable and non-extractable materials were analysed by GC–MS and Py–GC–MS, respectively, to study the incorporation of sulfur into the microalgal organic matter. No GC-amenable sulfur-containing compounds were found in the extracts apart from some minor thiophenes with a phytanyl carbon skeleton. The residue after extraction and hydrolysis contained abundant macromolecular sulfur-containing moieties as revealed by the presence of dominant C₂₈–C₃₂ thiols, thiophenes, thianes and thiolanes in the flash pyrolysates. These products are thought to be formed from moieties derived from sulfurisation of C₂₈–C₃₂ diols and alkenols, characteristic lipids of N. salina. C₁–C₂ alkylated thiophenes were also found in the pyrolysates and probably result from moieties formed upon sulfurisation of carbohydrates. The highly resistant biomacromolecule (algaenan) synthesised by N. salina remains unaffected by sulfurisation. The non-hydrolysable residue isolated from the sulfurised N. salina thus comprises algaenan and (poly)sulfide-bound long alkyl chains. The sulfurisation experiments show that both selective preservation of algaenans and lipid and carbohydrate “vulcanisation” can be involved in the preservation of algal organic matter in marine environments.     

有机酸对高岭石形成影响的模拟试验研究

利用富里酸、胡敏酸和盐酸与天然矿物－长石、蒙脱石和云母在常温常压下进行反应,探讨矿物溶解及高岭石形成机理。实验表明富里酸对这些矿物具有较大的溶解能力,其原因是由于形成了具有较大溶解度和活动性的有机硅和有机铝复合体。在中性－碱性条件下有利于有机硅复合体的形成,酸性条件下有利于有机铝复合体的形成。在富里酸作用下,蒙脱石和云母分别在４个月和８个月有少量转化成高岭石,说明层状硅酸盐矿物比架状硅酸盐矿物更易     

A comparison of estimated and calculated effective porosity

 Effective porosity in solute-transport analyses is usually estimated rather than calculated from tracer tests in the field or laboratory. Calculated values of effective porosity in the laboratory on three different textured samples were compared to estimates derived from particle-size distributions and soil–water characteristic curves. The agreement was poor and it seems that no clear relationships exist between effective porosity calculated from laboratory tracer tests and effective porosity estimated from particle-size distributions and soil–water characteristic curves. A field tracer test in a sand-and-gravel aquifer produced a calculated effective porosity of approximately 0.17. By comparison, estimates of effective porosity from textural data, moisture retention, and published values were approximately 50–90% greater than the field calibrated value. Thus, estimation of effective porosity for chemical transport is highly dependent on the chosen transport model and is best obtained by laboratory or field tracer tests. Received, March 1997 · Revised, August 1997 · Accepted, August 1997     

Precise laboratory wavelengths of the Mg I and Mg II resonance transitions at 2853, 2803 and 2796 Å

Strong ultraviolet resonance transitions are observed routinely both in the Galactic interstellar medium and in quasar absorption systems. The quality of the astronomical spectroscopic data now available demands more precise laboratory rest wavelengths. Of particular interest is the accuracy with which one can constrain space–time variations in fundamental constants using quasar spectra. A recent analysis by Webb et al. of 25 quasar spectra using Mg and Fe transitions tentatively suggests that the fine-structure constant was smaller at earlier epochs. To permit a check on this result, and to allow further more extensive investigations, we have carried out a new determination of the laboratory wavelengths of Mg  i  2853 Å, Mg  II  2796 Å and Mg  II  2803 Å by high-resolution Fourier transform spectroscopy. Our results for Mg  II  2796 Å are consistent with the value measured independently by two other groups. To our knowledge, no previous measurements of comparable precision exist for Mg  I  2853 Å and Mg  II  2803 Å.     

Strain fields and mechanical response of a highly to medium fissured bentonite clay

This article presents the developments of an ongoing research aimed at modelling the influence of fissuring on the behaviour of clays. In particular, it recalls the main results of an extensive laboratory investigation on a fissured bentonite clay from the south of Italy and presents the data of a new investigation on the evolution with shearing of the strain fields developing within the clay, resulting from Digital Image Correlation (DIC). Element test results are analysed in the framework of continuum mechanics and linked to the clay fissuring features, once characterised using the Fissuring IDentity (F‐ID) chart. This article compares the bentonite behaviour with that of other fissured clays of different F‐IDs, highlighting the common behavioural features. Thereafter, the soil response at the macro level is related to the DIC‐derived strain fields evolving within the clay with loading. For this purpose, DIC was successfully used to investigate the deformation processes active in the fissured clay and the sources of the localisation phenomena. DIC is shown to provide indications of the extent to which highly to medium fissured clays element test results can be of use to model the clay behaviour according to continuum mechanics. Copyright © 2012 John Wiley & Sons, Ltd.     

Spatial distribution and temporal variation of reference evapotranspiration in arid and semi‐arid regions of Iran

Analysis of spatial and temporal variations of reference evapotranspiration (ET_o) is important in arid and semi‐arid regions where water resources are limited. The main aim of this study was to analyse the spatial distribution and the annual, seasonal and monthly trends of the Penman–Monteith ET_o for 21 stations in the arid and semi‐arid regions of Iran. Three statistical tests the Mann‐Kendall, Sen's slope estimator and linear regression were used for the analysis. The analysis revealed that ET_o increased from January to July and deceased from July to December at almost all stations. Additionally, higher annual ET_o values were found in the southeast of the study region and lower values in the northwest of the region. Although the results showed both positive and negative trends in annual ET_o series, ET_o generally increased, significantly so in six (～30%) of the stations. Analysis of the impacts of meteorological variables on the temporal trends of ET_o indicated that the increasing trend of ET_o was most likely due to a significant increase in minimum air temperature, while decreasing trend of ET_o was mainly caused by a significant decrease in wind speed. At the sites where increasing ET_o trends were statistically significant, the rate of increase varied from (+)8·36 mm/year at Mashhad station to (+)31·68 mm/year at Iranshahr station. On average, an increasing trend of (+)4·42 mm/year was obtained for the whole study area during the last four decades. Seasonal and monthly ET_o have also tended to increase at the majority of the stations. The greatest numbers of significant trends were observed in winter on the seasonal time‐scale and in September on the monthly time‐scale. Copyright © 2011 John Wiley & Sons, Ltd.     

The effects of rock fragments on hydrologic and hydraulic responses along a slope

A model describing the three‐dimensional matrix flow along a slope with rock fragments or impermeable blocks was developed. The model was combined with modified Picard's iteration to ensure mass conservation in the unsaturated flow. We found that rock fragments obstruct water flow along the slope. The groundwater table must be raised to provide a sufficient pore water pressure gradient to facilitate water flow, but higher pore water pressure may induce slope failure. We also conducted a bench‐scale laboratory flume experiment to examine the effects of impermeable blocks on downstream seepage flow. In addition, a numerical experiment was conducted to examine how different arrangements of impermeable blocks affect downstream seepage flow and pore water pressure. This research demonstrated that the hydraulic phenomena were affected when impermeable blocks were present, and pore water pressure increased as the position of impermeable blocks was lowered. Copyright © 2006 John Wiley & Sons, Ltd.     

The impact of the nitrogen carryover effect on economic activity and the environment

 The economic and environmental consequences of soil nitrogen tests can have significant impacts on agricultural production. Some of these are explored here. The pre-side-dress soil N-test is evaluated for a hypothetical farmer growing corn at the ARS Sustainable Agriculture Demonstration Farm site in southern Maryland. For a farmer not currently using a soil N-test, adoption of this technology can lead to the enhancement of net farm income and the reduction in nitrogen loss to the environment. This will transpire only if the farmer is currently underestimating nitrogen carryover by more than 25% or applying nitrogen fertilizer based solely on an expected plateau-yield goal. Received: 13 February 1997 · Accepted: 13 May 1997     

空间钟与基础物理测试

原子钟当前已经发展到很高的水平,它们在空间科学试验中发挥了重要的作用．该文介绍了世界上正在开展的高精度空间钟计划及其对科学测量的意义．对应用空间钟可能进行的某些感兴趣的基础物理测试也进行了描述。