A semi-empirical dilatancy model for ballast fouled with plastic fines

In the era of high speed trains, it is very important to ensure the stability of rail tracks under adverse conditions including the fouling of ballast. Fouling of ballast from unstable and saturated soft subgrade soil is one of the major reasons for track deterioration. The reported results of a number of large-scale laboratory experiments on the shear behaviour of ballast and fouled ballast are analysed, herein. It was observed that fines have a significant influence on the shear behaviour of ballast. Shear strength increases and dilatancy decreases with the addition of fines. In this paper, a semi-empirical mathematical model has been proposed to capture the dilatancy of ballast fouled with fines during shearing. The empirical constants a, b and c proposed in the model are a function of the fines content Void Contamination Index (VCI). The results of the model have been compared with the laboratory experiments and are found to be in good agreement.     

Empirical correlations of soil parameters based on Cone Penetration Tests (CPT) for Greek soils

This study presents the results of Cone Penetration Tests (CPT) and estimated correlations with the results of other in-situ tests (standard penetration test, cross-hole, seismocone) and laboratory tests (classification and undrained shear strength tests). These tests cover nearly all types of penetrable soils in Greece and, together with the formulation of empirical correlations, complement and improve on previous studies due to the significant number of CPT measurements.     

Genesis of lithium pegmatites from the leinster granite margin,southeast ireland: Geochemical constraints

Extensive and economically-important lithium pegmatites have been described from the eastern flank of the large S-type peraluminous Leinster Granite batholith in southeast Ireland. This flank area is also the locus of a major dip-slip ductile shear zone which was active during emplacement of the Tullow Lowlands pluton of the batholith. All the known bedrock occurrences of lithium pegmatite are contained within this marginal deformation zone. Most previous studies have suggested derivation of the lithium pegmatites by fractionation from the Leinster Granite itself, though none are conclusive. More recently, an anatectic model has been proposed whereby the pegmatites were derived by melting of Li-rich sediments adjacent to the batholithic contact. Our investigation has been concerned with a detailed study of the Rb-Sr isotope systematics and trace element geochemistry of the pegmatites and their host granitoids in an attempt to resolve the problem of pegmatite genesis. The results suggest a strong geochemical and temporal coherence between the Leinster Granite and the lithium pegmatites. A model is proposed in which Li enrichment in residual magmas may be linked to the development of muscovite instead of biotite in the Leinster Granite itself. The Li excluded from entry to biotite then accumulates in highly mobile, low-viscosity pegmatitic fluids which migrate into the marginal shear zone of the Tullow Lowlands pluton where they crystallize at considerably lower temperatures.     

Laboratory Simulation of the Formation Process of Surface Geochemical Anomalies Applied to Hydrocarbon Exploration

The formation mechanisms and processes of geochemical anomalies used as proxies in surface geochemistry exploration (SGE) have not been well understood. Previous studies cannot realize 3D measurement of microseeping hydrocarbons from reservoirs to the surface, which made it difficult to understand the features and pathways of deep hydrocarbon microseepages. Understanding the processes of hydrocarbon microseepages will contribute to the acceptance and effectiveness of surface geochemistry. Based on a simplified geological model of hydrocarbon microseepages, including hydrocarbon reservoir, direct caprock, overlying strata and Quaternary sediments, this work established a 3D experimental system to simulate the mechanisms and processes of deep hydrocarbon microseepes extending to the surface. The dispersive halos of microseeping hydrocarbons in the subsurface were adequately described by using this 3D experimental system. Results indicate that different migration patterns of hydrocarbons above the point gas source within the simulated caprock and overlying strata can be reflected by the ratio of i-butane to n-butane (i-C4/n-C4), which follow diffusion and infiltration (buoyancy) mechanisms. This is not the case for vertical measurement lines far from the point gas source. A vertical gas flow in the form of a plume was found during hydrocarbon microseepage. For sampling methods, the high-density grid sampling is favorable for delineating prospecting targets. Hydrocarbon infiltration or buoyancy flow occurs in the zones of infiltration clusters, coupling with a diffusion mechanism at the top of the water table and forming surface geochemical anomalies. These results are significant in understanding hydrocarbon microseepage and interpreting SGE data.     

泥质软岩地基水平抗力系数研究

通过室内水平静载试验和数值模拟对泥质软岩地基水平抗力系数的比例系数m进行研究,给出m值参考值,并讨论了影响地基岩土m值的因素,研究结果表明：试验所用的南宁盆地第三系泥岩m值取值范围为17～35 MN/m4,桩径大时取小值,埋深大时取大值;用ANSYS模拟水平静载试验,计算出的m值与室内试验值十分接近,可为今后数值计算m值提供参考。经分析m值的影响因素后认为适当增加桩的埋深、控制岩土含水率及提高混凝土的浇灌质量等可以提高m值     

Rehabilitation of industrial areas: case histories from England and Germany

 Contaminated and possibly hazardous ground represents a problem in all of the industrialized countries of the world. The investigation of a site that is suspected of being contaminated differs somewhat from a routine site investigation. Sampling of soils, groundwater and gas-producing material may be required. Various precautions may be necessary in doing this and operatives may have to wear protective clothing. Four case histories have been chosen to illustrate different aspects of the rehabilitation of abandoned contaminated land, namely, investigation, assessment, ground treatment and redevelopment. The first comes from Leeds in West Yorkshire, England, and outlines how a site investigation was undertaken and the nature of the contamination present, together with a note on the suggested redevelopment. The remaining three case histories are taken from the heavily industrialized district of the Ruhr in Germany, where extensive mining of coal and associated industries were developed from the mid-19th century onwards. The first considers the site of the former Graf Moltke mine near Essen. In this instance, the somewhat novel methods of data assessment and ground treatment are dealt with. The Mont Cenis site at Herne-Sodingen is one of the more notable old mining/industrial sites undergoing redevelopment in the state of North Rhine Westphalia. Hence, the case history concentrates of this aspect of rehabilitation. This involves not only the construction of new and interesting structures but an attempt to reduce energy consumption in an attempt to effect the concept of sustainable development of an urban area. The last example deals with the abandoned site of the Minister Achenbach mine at Lünen, where the ground conditions were further complicated by the presence of old bomb craters that had been filled with a variety of materials. In addition, because of the suspected presence of former foundation structures in the ground an electromagnetic survey was carried out across part of the site, the areas of high conductivity suggesting their presence. Received: 15 September 1999 · Accepted: 14 March 2000     

Chemical Mechanism Development: Laboratory Studies and Model Applications

Within the German Tropospheric Research Programme (TFS) numerous kinetic and mechanistic studies on the tropospheric reaction/degradation of the following reactants were carried out: oxygenated VOC, aromatic VOC, biogenic VOC, short-lived intermediates, such as alkoxy and alkylperoxy radicals.At the conception of the projects these selected groups were classes of VOC or intermediates for which the atmospheric oxidation mechanisms were either poorly characterised or totally unknown. The motivation for these studies was the attainment of significant improvements in our understanding of the atmospheric chemical oxidation processes of these compounds, particularly with respect to their involvement in photooxidant formation in the troposphere. In the present paper the types of experimental investigations performed and the results obtained within the various projects are briefly summarised. The major achievements are highlighted and discussed in terms of their contribution to improving our understanding of the chemical processes controlling photosmog formation in the troposphere.     

Use of high spectral resolution remote sensing to determine leaf palatability of eucalypt trees for folivorous marsupials

In this study we assess the feasibility of remotely measuring canopy biochemistry, and thus the potential for conducting large-scale mapping of habitat quality. A number of studies have found nutrient composition of eucalypt foliage to be a major determinant of the distribution of folivorous marsupials. More recently it has been demonstrated that a specific group of secondary plant chemicals, the diformylphloroglucinols (DFPs), are the most important feeding deterrents, and are thus vital determinants of habitat quality. We report on the use of laboratory spectroscopy to attempt to identify one such DFP, sideroxylonal-A, in the foliage of Eucalyptus melliodora, one of the few eucalypt species browsed by folivorous marsupials. Reflectance spectra were obtained for freeze-dried, ground leaves using near infrared spectroscopy (NIRS) and for both oven-dried and fresh whole leaves using a laboratory-based (FieldSpec) spectroradiometer. Modified partial least squares (MPLS) regression was used to develop calibration equations for sideroxylonal-A concentration based on the reflectance spectra transformed as both the first and second difference of absorbance (Log 1/R). The predictive ability of the calibration equations was assessed using the standard error of calibration statistic (SECV). Coefficients of determination (r²) were highest for the ground leaf spectra (0.98), followed by the fresh leaf and dry leaf spectra (0.94 and 0.87, respectively). When applied to independent validation sub-sets, sideroxylonal-A was most accurately predicted from the ground leaf spectra (r² = 0.94), followed by the dry leaf and fresh leaf spectra (0.72 and 0.53, respectively). Two spectral regions, centred on 674 nm and 1394 nm, were found to be highly correlated with sideroxylonal-A concentration for each of the three spectral data sets studied. Results from this study suggest that calibration equations derived from modified partial least squares regression may be used to predict sideroxylonal-A concentration, and hence leaf palatability, of Eucalyptus melliodora trees, thereby indicating that the remote estimation of habitat quality of eucalypt forests for marsupial folivores is feasible.     

实验室测绘教学仪器的管理

在分析了当前测绘仪器管理存在问题的基础上，从仪器在实验室的管理体制、模式方面做了有益探讨和分析，提出了测绘仪器实行动态管理和开放使用的模式。     

Organochlorine pesticide residues in sediments and biota from the coastal area of Dar es Salaam city,Tanzania

Sediment and biota samples were collected from Msimbazi and Kizinga rivers and from the coastal marine environment of Dar es Salaam during both dry and wet seasons. The samples were analyzed for various organochlorine pesticide residues using GC-ECD and GC-MS. Dieldrin, p,p^′-DDT, p,p^′-DDE, p,p^′-DDD, o,p^′-DDT and γ-HCH were detected at significantly greater concentrations above the method detection limits. Recoveries of pesticide residues ranged 86.5–120% in sediments and 62–102% in biota. The average concentrations of total DDT in sediments for the two seasons were almost the same. Biota samples showed significant difference in levels of residues depending on mode of feeding and age of analyzed biota. p,p^′-DDT to total DDT ratios in all matrices indicated recent use of DDT. The levels of residues in sediments suggest possible adverse effects to humans consuming biota that are directly exposed to the sediments. This effect, which is associated with bio-concentration of residues in the tissues of edible aquatic biota, should not affect wildlife. In spite of concern on the adverse effect to humans posed by pesticide residues in sediments, edible biota from the examined water bodies were found to be safe for human consumption.