Fluid inclusions in rocks from the amphibolite-facies gneiss to charnockite progression in southern Karnataka, India: direct evidence concerning the fluids of granulite metamorphism

Abstract Fluid inclusion studies of rocks from the late Archaean amphibolite-facies to granulite-facies transition zone of southern India provide support for the hypothesis that CO₂,-rich H₂O-poor fluids were a major factor in the origin of the high-grade terrain. Charnockites, closely associated leucogranites and quartzo-feldspathic veins contain vast numbers of large CO₂-rich inclusions in planar arrays in quartz and feldspar, whereas amphibole-bearing gray gneisses of essentially the same compositions as adjacent charnockites in mixed-facies quarries contain no large fluid inclusions. Inclusions in the northernmost incipient charnockites, as at Kabbal, Karnataka, occasionally contain about 25 mol. % of immiscible H₂O lining cavity walls, whereas inclusions from the charnockite massif terrane farther south do not have visibile H₂O Microthermometry of CO₂ inclusions shows that miscible CH₄ and N₂ must be small, probably less than 10mol.%combined. Densities of CO₂ increase steadily from north to south across the transitional terrane. Entrapment pressures calculated from the CO₂ equation of state range from 5 kbar in the north to 7.5 kbar in the south at the mineralogically inferred average metamorphic temperature of 750°C, in quantitative agreement with mineralogic geobarometry. This agreement leads to the inference that the fluid inclusions were trapped at or near peak metamorphic conditions. Calculations on the stability of the charnockite assemblage biotite-orthopyroxene-K-feldspar-quartz show that an associated fluid phase must have less than 0.35 H₂O activity at the inferred P and T conditions, which agrees with the petrographic observations. High TiO₂ content of biotite stabilizes it to lower H₂O activities, and the steady increase of biotite TiO₂ southward in the area suggests progressive decrease of aH₂O with increasing grade. Oxygen fugacities calculated from orthopyroxene-magnetite-quartz are considerably higher than the graphite CO₂-O₂ buffer, which explains the absence of graphite in the charnockites. The present study quantifies the nature of the vapours in the southern India granulite metamorphism. It remains to be determined whether CO₂-flushing of the crust can, by itself, create large terranes of largeion lithophile-depleted granulites, or whether removal of H₂O-bearing anatectic melts is essential.     

Garnet-bearing Granulite Facies Rock Xenoliths from Late Mesozoic Volcaniclastic Breccia, Xinyang, Henan Province

This paper presents the primary results of petrologic, mineralogical and petrochemical studies of garnet-bearing granulite facies rock xenoliths from Xinyang, Henan Province. These xenoliths, which are found in a pipe of late Mesozoic volcaniclastic breccia, are of high density (3.13-3.30 g/cm3) and high seismic velocity (Vp = 7.04-7.31 km/s), being products of underplating of basaltic magmas and had experienced granulite facies metamorphism. The underplating and metamorphism took place before the eruption of the host rock. Petrographical studies and equilibrium T-P calculations show that these xenoliths were captured at a 49 km depth and experienced at least a 16 km uplift before they were captured. The dynamics of the uplift could be related to the continent-continent collision between the North China plate and the Yangtze plate during the Triassic.     

Metastability of granulites and processes of eclogitisation in the UHP region of western Norway

The Flatraket Complex, a granulite facies low strain enclave within the Western Gneiss Region, provides an excellent example of metastability of plagioclase‐bearing assemblages under eclogite facies conditions. Coesite eclogites are found <200 m structurally above and <1 km below the Flatraket Complex, and are separated from it by amphibolite facies gneisses related to pervasive late‐orogenic deformation and overprinting. Granulites within the Flatraket Complex equilibrated at 9–11 kbar, 700–800°C. These predate eclogite facies metamorphism and were preserved metastably in dry undeformed zones under eclogite facies conditions. Approximately 5% of the complex was transformed to eclogite in zones of fluid infiltration and deformation, which were focused along lithological contacts in the margin of the complex. Eclogitisation proceeded by domainal re‐equilibration and disequilibrium breakdown of plagioclase by predominantly hydration reactions. Both hydration and anhydrous plagioclase breakdown reactions were kinetically linked to input of fluid. More pervasive hydration of the complex occurred during exhumation, with fluid infiltration linked to dehydration of external gneisses. Eclogite facies shear zones within the complex equilibrated at 20–23 kbar, 650–800°C, consistent with the lack of coesite and with the equilibration conditions of external HP eclogites. If the complex experienced pressures equivalent to those of nearby coesite eclogites (> 28 kbar), unprecedented metastability of plagioclase and quartz is implied. Alternatively, a tectonic break exists between the Flatraket Complex and UHP eclogites, supporting the concept of a tectonic boundary to the UHP zone of the Western Gneiss Region. The distribution of eclogite and amphibolite facies metamorphic overprints demonstrates that the reactivity of the crust during deep burial and exhumation is strongly controlled by fluid availability, and is a function of the protolith.     

徐武家麻粒岩相糜棱岩

内蒙中部土贵乌拉南徐武家早前寒武纪麻粒岩地体中发育北东向韧性剪切带,其中发现有宽达5km 的麻粒岩相糜棱岩剖面,成分相当于紫苏辉长岩、钠质花岗岩和泥质岩的麻粒岩相糜棱岩出露齐全,保存完整。二辉斜长麻粒岩中紫苏辉石、斜长石、钾长石和透辉石斑晶普遍发育强烈的塑性形变;细粒重结晶相矿物组合 Hy+Di+Pl+Kf+Hb+Bi+Scap+Q 显示糜棱岩形成于麻粒岩相变质条件,二辉石矿物对给出温度 T=710℃。该糜棱岩带与麻粒岩相变辉长岩和地壳熔融型石榴子石花岗岩密切共生,这一事实既确证了韧性剪切带在麻粒岩变质过程中发育,为研究该区麻粒岩相岩带构造演化找到了一个构造标志,同时,也为深入探讨下地壳的实际构造过程,包括麻粒岩相条件下剪切形变发生的饥理以及克拉通化提供了地质实例。     

贺兰山群变质杂岩主期变质作用的温压环境研究

分布于贺兰山脉北部的贺兰山群变质杂岩的主期变质作用达角闪麻粒岩相,其矿物组合特征与低压相系麻粒岩相似、利用共生矿物组合和矿物对的温度计、压力计估算主期变质温度740—764(?),压力460—501MPa。温度压力条件与低压相系的地热梯度线较接近,变质作用强度具面型分布的特征,与东部密云、冀东等地的麻粒岩相区相似,但变质压力明显低,压力类型也不同,应属不同构造背景下的变质产物。     

Silica-undersaturated sapphirine, spinel and kornerupine granulite facies rocks, NE Strangways Range, Central Australia

Small pods of silica-undersaturated Al-rich and Mg-rich granulite facies rocks containing sapphirine, pleonastic spinel, kornerupine, cordierite, orthopyroxene, corundum, sillimanite and gedrite are scattered throughout the NE Strangways Range, Central Australia. These are divided into four distinct rock types, namely orthopyroxene-rich aluminous granofels and metapelitic gneisses containing sapphirine, spinel or kornerupine. Two granulite facies metamorphic events are recognized, of which only the first (M1) is considered in this paper. Peak metamorphic mineral parageneses indicate that the M1 thermal maximum occurred at approximately 900–950 °C and 8–9 kbar. All samples are characterized by profuse and diverse coronitic and symplectic reaction textures. These are interpreted as evidence for the sequential crossing of the following reactions in the system FMAS: cordierite + spinel + corundum = sapphirine + sillimanite, cordierite + spinel = orthopyroxene + sapphirine + sillimanite, sapphirine + spinel + sillimanite = orthopyroxene + corundum, sapphirine + sillimanite = cordierite + orthopyroxene + corundum. Phase stability relationships in FMAS and MASH indicate an anticlockwise P–T path terminated by isobaric cooling. Such a path is exemplified by early low-P mineral parageneses containing spinel, corundum and gedrite and the occurrence of both prograde and retrograde corundum. Reaction textures preserve evidence for an increase in aH₂O and aB₂O₃ with progressive isobaric cooling. This hydrous retrogression resulted from crystallization of intimately associated M1 partial melt segregations. There is no evidence for voluminous magmatic accretion giving rise to the high M1 thermal gradient. The M1 P–T path may be the result of either lithospheric thinning after both crustal thickening and burial of the supracrustal terrane, or concomitant crustal thickening and mantle lithosphere thinning.     

<Emphasis Type="Italic">In-situ</Emphasis> trace element analyses and Pb-Pb dating of zircons in granulite from Huangtuling,Dabieshan by LAM-ICP-MS

It is revealed by CL images that there are multi-stage growth internal structures of zircons in the Huangtuling granulite, including the inherited zircons, protolith zircons, sector and planar zone zircons and retrograde zircons. In-situ trace element compositions and Pb-Pb ages have been analyzed by LAM-ICP-MS. The sector and the planar zone domains show typical trace element characteristics of granulite zircon (low Th, U, Th/U, total REEs, clear negative Eu anomalies, relatively depleted HREE and small differential degree between MREE and HREE, etc.), indicating that they formed during granulite-facies metamorphism. The protolith zircons have trace element characteristics of crustal zircon (high Th, U, Th/U, total REEs and enriched HREEs, etc.). 12 analyzed spots on granulite-facies domains give a weighted mean ²⁰⁷Pb/²⁰⁶Pb age of (2154±26) Ma (MSWD = 3.8), which is the best estimated age of granulite-facies metamorphism of this sample. The weighted mean ²⁰⁷Pb/²⁰⁶Pb age of 5 analyzed spots on protolith zircon domains is (2714 ± 22) Ma (MSWD = 1.4), which represents the protolith forming time. The discovery of ca. 3.4 Ga inherited zircon indicates that there are Palaeoarchean continental materials in this area. The interpretation of formation conditions and the ages of zircons can be constrained by simultaneous in-situ analysis of trace elements and ages.     

中国与蒙古之地质

东昆仑中部缝合带清水泉一带发育石榴斜长紫苏麻粒岩、紫苏辉石黑云母石榴子石麻粒岩、石榴二辉斜长麻粒岩和石榴单斜辉石麻粒岩,它们与混合岩化黑云母石榴子石变粒岩、黑云母辉石变粒岩、石墨大理岩、含透辉石透闪石大理岩、透辉石大理岩、黑云斜长角闪岩和片麻岩等高级变质岩系以及纯橄岩、辉橄岩、橄长岩、辉长岩、辉绿岩和玄武岩等共同构成蛇绿混杂岩。麻粒岩相变质作用的温压条件为T=760~880℃,p=830~1200MPa,为高温中高压麻粒岩相变质作用,估算其形成深度为40~45km。麻粒岩相变质作用的SHRIMP锆石U-Pb年龄为(507·7±8·3)Ma。清水泉地区蛇绿岩形成于~520Ma,到~508Ma时俯冲至地下40~45km深处而发生中高压麻粒岩相变质作用,然后发生构造折返而剥露至地表。证实了清水泉高级变质岩和基性—超基性岩片是形成于早—中寒武世的蛇绿混杂岩,标志一个古生代早期的非常重要的板块汇聚边界,这对于进一步研究东昆仑造山带构造演化、乃至中国西部大地构造格局具有非常重要的意义。     

Mineralogical and geochemical study of a newly discovered mafic granulite, northwest China: Implications for tectonic evolution of the Altay Orogenic Belt

Abstract A mafic granulite body was newly discovered in the Altay Orogenic Belt, northwest China. The rocks comprise a suite of coarse‐grained and fine‐grained granulites. Orthopyroxenes (hypersthenes) in the rocks have high X_Mg and low Al₂O₃ contents, whereas clinopyroxenes have low TiO₂ and Al₂O₃ contents. Amphiboles and biotites have a high Mg/(Mg + Fe²⁺) ratio and low contents of F and Cl. The peak metamorphic pressure–temperature (P–T) conditions are estimated as 750–780°C and 6–7 kbar, and retrograde P–T conditions are in the range of 590–620°C and 2.3–3.7 kbar, indicating significant decompression. Metamorphic reactions and P–T estimates define a clockwise P–T path. Geochemically, the rocks are high in Mg/(Mg + Fe) and Al₂O₃, depleted in U, Th, K and Rb, and characterized by light rare earth element enrichment and a weak positive Eu anomaly. The Altay mafic granulite shows depleted Nb, P and Ti contents in the mid‐oceanic ridge basalt normalized spider diagram. The geochemical characteristics suggest that the protolith of the Altay mafic granulite was calc‐alkaline basalt and andesite with an island‐arc affinity. The rock has a high ¹⁴³Nd/¹⁴⁴Nd ratio with ?Nd(0) > 0, indicating derivation from a mantle‐depleted source. In the present study, a two‐stage model for the evolution of the Altay mafic granulite is proposed: an early stage in which calc‐alkaline basalt and andesite with island‐arc affinity were subducted into a deeper level of the crust and subjected to granulite‐facies metamorphism generating the mafic granulite, followed by the later stage exhumation of the system into the upper crust by the late Paleozoic thrusting.     

青藏高原北羌塘新生代火山岩中的麻粒岩捕虏体

北羌塘枕头崖地区新生代火山岩主要岩石类型为安山岩和英安岩类。其中,安山岩在一定程度上显示了埃达克质火山岩的特征,如高Sr(>1000×10-6)、Sr/Y>50以及低Yb(<2×10-6),表明其应源于榴辉岩相的青藏高原加厚陆壳中下部(>45km深度)。而英安岩类富集LILE,如Rb、Ba、Th、U和K等,亏损HFSE,如Ti、Nb、Ta和Sr等,尤其是Sr显著亏损,表明其应源于斜长石稳定的麻粒岩相源区。该区新生代安山岩和英安岩中麻粒岩捕虏体可分为两种类型,即二辉石麻粒岩和单斜辉石麻粒岩。二辉石麻粒岩平衡温度为783~818℃,单斜辉石麻粒岩形成压力在0·845~0·858GPa之间,来源深度约为27·9~28·3km,表明它们是来自青藏高原加厚陆壳中部的岩石样品,代表了本区英安岩类火山岩的源区物质组成。