Fractal-like adsorption kinetics of Pb^2＋ in rocks

The adsorption kinetics of Pb^2＋ in rocks has been studied using ion selective electrodes and atomic absorption spectrophotometer. The results showed that the adsorption process is a fractal-like reaction. The adsorption rate was relatively high before 30 minutes, and then dropped. The saturated adsorption capacity （a） of Pb^2＋ and kinetic parameters （b, a, D and k） increased with increasing initial concentrations of Pb^2＋. These parameters （except a） decreased while Na^＋ was present in the solution. Furthermore, the smaller the rocks were in grain size, the bigger these kinetic parameters would be, though the parameter a was almost constant.     

陕西太白双王角砾岩型金矿的角砾岩特征

双王金矿床是秦岭泥盆系地层中一种类型独特富钠角砾岩型金矿床,在分析研究矿床赋矿地层、角砾岩带、角砾岩体的矿化及分带特征的基础上,阐述了该矿床的分带特征与金矿化的关系。     

三峡库区巫山县翠屏小区岩溶引起的地质灾害危险性研究

三峡库区移民迁建中发现的岩溶问题是一个重大工程地质问题。巫山县城翠屏小区是较早发现有确切岩溶证据的地方,研究证实小区三叠系嘉陵江组灰岩普遍遭受了强烈的岩溶作用。不同部位具有不同的岩溶特点和强度,在纵向上,从山顶到坡脚岩溶作用有增强的趋势;从地表向深部,有局部强烈岩溶层位。岩溶作用在小区产生了顺坡或顺层延伸的溶洞和深部蜂窝状溶孔。岩溶作用在小区形成了脖颈状溶蚀槽地、槽状谷地、溶蚀台地和与地貌相关的"飞雁状"褶皱、岩溶正断层及帚状密集节理带。岩溶过程中伴随着其他外营力作用,它们的相互耦合形成各种次生岩土体。岩溶轻则引起岩体质量降低,重则可能导致地面不均匀沉降、地裂缝、滑坡、崩塌、泥石流及地面塌陷地质灾害。     

内蒙古阿鲁科尔沁旗好力宝铜钼矿床地质特征及找矿方向

好力宝铜钼矿床属与燕山期隐伏的隐爆角砾状斜长花岗斑岩和碎裂次石英斑岩有关的热液脉状和斑岩型矿床.铜钼矿体受隐爆角砾岩筒和岩体控制,矿化产在蚀变隐爆角砾岩和硅化带中.今后的找矿方向应侧重于对斜长花岗斑岩与围岩接触带和碎裂次石英斑岩中化探异常和低阻高极化异常地段的探索.     

地铁施工对济南白泉泉群流量的影响

为研究地铁建设对济南白泉泉群的影响，在综合分析白泉泉域地质、水文地质条件的基础上，假定研究区岩溶强径流带位置及水力性质，利用FEFLOW软件建立地下水流数值模型。以规划地铁M1号线为研究对象，分析了济南东站、梁王站、梁王东站分别施工及3个站同时施工4种情景下，采用施工降水或施工降水+人工回灌两种施工方式对白泉泉群流量的影响。结果表明：单独采用施工降水的施工方式使得白泉泉群流量衰减，其中3个站同时施工对泉流量的影响最大，泉流量最大衰减达5.48%；各站分别施工时，济南东站对泉流量影响最大，泉流量较未施工时减少了0.043×10⁴ m³/d。采用施工降水+人工回灌的施工方式，能够有效缓解泉流量的衰减，各车站施工时的泉流量衰减由仅施工降水时的2.26%~5.48%降低至0.08%~1.21%。岩溶强径流带有利于地下水形成优势径流，促进白泉泉群补给，一定程度上缓解因地铁施工引起的泉流量衰减。     

The effect of acid deposition on base cation cycling in a karstic-forested catchment： Evidence from strontium isotopes

Bedrock weathering and atmospheric deposition are the two primary sources of base cations （K^＋, Na^＋, Ca^2＋ and Mg^2＋） to forest ecosystems. Therefore, the key problem is to understand the relative inputs from these two sources and the cycling in the ecosystem. This study focuses on the effects of acid deposition on cation cycling in a small-forested karstic catchment in Guizhou Province. Sr isotope ratios were used as a tracer for understanding the transport process between the different cation pools： rock, soil, surface water, atmospheric deposition and plant. The samples of wet deposition, total deposition, throughfall, surface and ground waters, vegetation, and soil were monthly collected. The exchangeable Sr^2＋ and Ca^2＋ in soil samples were extracted by using 1 M ammonium acetate. The leaf-tissue samples were ashed at 550℃, and the residue was digested in ultrapure HClO4 and HNO3. All water samples were filtrated through 0.45 μm aperture filter paper. Base cation concentrations and Sr isotopic composition were analyzed for all the samples. The results show that acid deposition （average pH 4.9） frequently occurred in the studied region. Cation abundance follows an increasing manner from rainwater, throughfall, to surface water or ground water samples, suggesting that acid deposition at first eiuviates Ca^2＋ , Mg^2＋ and Sr^2＋ from leaf, then the exchangeable cations from soil, and at last cations accumulate in surface water or ground water.     

Cyclic palaeokarst surfaces in Aptian peritidal carbonate successions (Taurides, southwest Turkey): internal structure and response to mid-Aptian sea-level fall

The sedimentology and cyclic stratigraphy of palaeokarst structures in Aptian peritidal carbonate successions are interpreted using field and laboratory microfacies analyses of closely spaced samples from measured outcrop stratigraphic sections in southwest Turkey. Cycles displaying shallowing-upward metre-scale cyclicity are generally composed of lime mudstones/wackestones/packestones at the bottom and stromatolites or lime mudstones with charophytes and ostracods at the top. Subaerial exposure structures such as in situ karst breccias, dissolution vugs/pipes, mud cracks and sheet cracks are encountered at the top of the cycles. The presence of limestone layers between the successive karst breccia levels indicates that they are in situ palaeokarst structures, not recent karstifications or deep penetration from the upper palaeokarst surface down to the older strata. Palaeokarst breccia deposits are interpreted as mantling breccia formed as a result of epikarstification. Three main palaeokarst levels are recorded in nearly all sections. The sedimentology of the palaeokarst breccias, their position in cyclic peritidal carbonates and the biostratigraphic framework are used to trace the record of the global mid-Aptian sea-level fall in the southwest Taurides. The successive occurrences of three karst breccia levels close to the mid-Aptian sea-level fall correspond to falling periods of high-amplitude sea-level fluctuation within a late high-stand or early fall condition of a third-order sea level.     

Hydrology and hydrogeology of Sakaryabaşı Karstic springs, Çifteler, Turkey

The Sakarya River is one of the largest rivers in Turkey and is fed mainly from Sakaryabaşı springs. The Sakaryabaşı springs are located in the Central Anatolia and issue from confined/semi-confined karst having a thermal component and therefore, having quite different hydrogeological characteristics as compared to the Taurus Karst region, a typical example of the Mediterranean type of karst. The karstic carbonate rocks that form the groundwater reservoir are overlain by a thick semi-pervious overburden of mainly clastics of Neogene age. Tectonics is the major factor controlling the occurrence of the karst springs in the area where topography is rather flat. This study aimed at explaining the occurrence and movement of the karst groundwater within the system by use of hydrogeological, chemical, and isotopic tools. Isotopic composition of the waters revealed that all waters in the region are of meteoric origin and the thermal component is due to deep circulation. The catchment area of the hydrogeological system extends to the south and groundwater movement is towards the outlets, which are in a depression along a major fault. The movement of the groundwater, based on analysis of remotely sensed images, is controlled mainly by structural elements.     

Construction Problems on the Karstified Limestone Tuffs of Condeixa, Central Portugal: A Case Study

During the excavations for the foundations of a three storey building on the limestone tuffs of Condeixa, Central Portugal, a large dissolution fissure and smaller dissolution voids were found. Since the area has never been the subject of engineering geology investigation, it was decided to evaluate the risk associated with the construction of the building. These limestone tuffs were formed in a continental environment by the precipitation of calcite carried by the water coming from the large limestone body in the east. The precipitated calcite mixed with the terrigenous materials and around trunks and leaves of plants, originating a very heterogeneous and porous ground, which is characteristic of limestone tuffs. The study started with a detailed geological survey followed by a large number of destructive drillings, located essentially under the pad foundations. The results revealed several karstic cavities with serious problems for the building foundations and the structure, and many smaller dissolution cavities, often filled with clayey soils. The ground treatment solutions used included, dental cleaning, filling with concrete or granular material the dissolution structures accessible at the level of the foundation, reinforcement of the footing and the structure of the building and adding a continuous foundation beam to hold the foundations together. The cost of the engineering geology study, site investigation, ground treatment, and the reinforcement of the foundation and building, increased the total construction cost from 2%, at the design stage, to 4.8%.     

鄂西火烧坪地区岩溶生态环境系统及生态农业模式初探

通过对鄂西火烧坪地区的自然地理、地质构造、水文地质、土壤、植被及社会经济等方面的初步研究表明，在岩溶化作用十分强烈的岩溶山区，当气候、地形地貌、地质构造等条件匹配较好时，同样存在着一些极其有利于农业、林业发展的特殊生态环境。在这些地区，结合当地植物资源特点和市场需求，通过农作物类型的调整，能够在短时间内使当地摆脱贫穷的面貌。但在发展经济的同时必须特别关注当地土地资源相对缺乏、水资源时空分布不均、生态环境脆弱等不利因素，做到适度开发，稳步发展，才能从根本上实现小康目标。