Molecular modeling of the 10-Å phase at subduction zone conditions

Molecular dynamics (MD) modeling of the 10-Å phase, Mg₃Si₄O₁₀(OH)₂·xH₂O, with x=2/3, 1.0 and 2.0 shows complex structural changes with pressure, temperature and water content and provides new insight into the structures and stabilization of these phases under subduction zone conditions. The structure(s) of this phase and its role as a reservoir of water in the mantle have been controversial, and these calculations provide specific predictions that can be tested by in situ diffraction studies. At ambient conditions, the computed structures of talc (x=0) and the 10-Å phases with x=2/3 and 1.0 are stable over the 350-ps period of the MD simulations. Under these conditions, the 10-Å phases show phlogopite-like layer stacking in good agreement with previously published structures based on powder X-ray diffraction data for samples quenched from high-pressure and high-temperature experiments. The calculations show that the 10-Å phase with x=2.0 is unstable at ambient conditions. The computed structures at P=5.5 GPa and T=750 K, well within the known stability field of the 10-Å phase, change significantly with water content, reflecting changing H-bonding configurations. For x=2/3, the layer stacking is talc-like, and for x=1.0, it is phlogopite-like. The calculations show that transformation between these two stackings occurs readily, and that the talc-like stacking for the x=2/3 composition is unlikely to be quenchable to ambient conditions. For x=2.0, the layer stacking at P=5.5 GPa and T=750 K is different than any previously proposed structure for a 10-Å phase. In this structure, the neighboring basal oxygens of adjacent magnesium silicate layers are displaced by b/3 (about 3 Å) resulting in the Si atoms of one siloxane sheet being located above the center of the six-member ring across the interlayer. The water molecules are located 1.2 Å above the center of all six-member rings and accept H-bonds from the OH groups located below the rings. The b/3-displaced structure does not readily transform to either the talc-like or phlogopite-like structure, because neither of these stackings can accommodate two water molecules per formula unit. There is likely to be a compositional discontinuity and phase transition between the b/3-displaced phase and the phase with phlogopite-like stacking. The simulations reported here are the first to use the recently developed CLAYFF force field to calculate mineral structures at elevated pressures and temperatures.     

Method of high-density seismic imaging ex-ploration and application samples

Introduction Now, shallow seismic reflection wave technique has been used extensively in geological ex-plorations of bridge, dam, high building and so on. Since shallow seismic reflection wave tech-nique is often implemented in industrial zone or city with dense population, the background dis-turbance including industrial noise, life noise, etc is very serious. Furthermore, the disturbance of seismic source is also serious due to short array length and offset of the method. In general, shal-lo…     

Investigation of upper crust anisotropy in Ghaen-Birjand region, east-central Iran

IntroductionWhenpropagatingthroughananisotropicmedium,ashearwavesplitsintotwo(quasi)shearwaveswithdifferentpropagationspeedsandpolarizedorthogonally.Owingtotherecentdevel-opmentofseismicobservationsystem,detectionofshearwavessplittingwithverysmalldelaytimesbetweenfasterandslowershearwavesbecameavailableandprovidedpowerfulapproachfordetectionofcrustalanisotropy.Crampin(1978)emphasizedtheroleofalignedmicrocracksasacauseofcrustalanisotropyandpointedoutthatforverticallyalignedmicrocracksthedirecti…     

基于拉格朗日插值法修正地形影响的分布式降水模型研究

降水量一直是进行水文分析计算的输入项，对其分布状况的模拟直接影响水文分析成果精度。降水中心位置及其中心降水量对暴雨分析尤为重要，而目前尚未见对降水中心位置方面的模型研究。在对目前国内外降水模型分析的基础上，根据天气系统降水如不受地形影响其降水量等值线在平面上的分布近似为一组同心椭圆这一原理，建立了一种能够模拟次降水过程的降水中心位置及其中心降水量的新型分布式降水数学模型，并对其进行地形影响因素修正。由于模型建立原理简单，易于实现对流域未设站研究点的实时降水量估计，同时由于模型能够指明降水中心位置及其中心降水量，因此在流域暴雨分析和洪水预报中具有实用价值。模型经实践检验具有较高精度。     

水泥搅拌桩与锚杆组合支护结构的力学参数研究

水泥搅拌桩--锚杆组合支护结构是一种新型的组合支护结构,笔者采用有限元方法进行各相关力学参数研究,分析了该组合支护结构的受力特性及变形性态.通过计算结果与实测数据的比较,表明本文所得结论对该组合支护结构的应用有一定的指导价值.     

东吴小筑园林植物应用评价

园林植物配置是园林植物应用的重要内容，对充分发挥园林功能和观赏特性具有重要作用。通过对东吴小筑入口、前庭小院、主景区、山林区、园路、出口等6个功能区园林植物水平配置的现状调查，分析了本景区园林植物的物种多样性、水平结构、垂直结构、色彩变化等特征。结果表明：东吴小筑园林景观营造中．植物配置显示出较高水准。在树种选择、树丛组合、层次搭配、空间组织、色彩表现、季相变化等方面的设计布局十分精细，对今后园林设计及园林绿化水平的提高具有较好的指导作用。     

南方NGS200应用实践中的若干问题

对南方NGS200在工程控制测量领域应用实践中的一些问题作了阐述，提出了一些见解和措施。     

Impacts of Previous Winter Kuroshio SSTA on Summer Rainfall in China

1. IntroductionAs well known, Kuroshio is a famous and strongwest boundary current in the North Pacific. It trans-fers enormous energy from the low latitudes to themid-high latitudes and releases huge heat flux to theatmosphere above (Hsiung, 1985). The variation ofKuroshio exerts great influence on weather and cli-mate in East Asian.During 1950-60s, Lü (1950, 1964) found that thewestern North Pacific SSTA had a close relation withsummer rainfall in China. In the 1970s, evidencesshowed…     

Studies on wind environment around high buildings in urban areas

High buildings or architectural complex in urban areas remarkably distort the urban surface wind fields. As the air flow approaches,local strong wind may appear around the buildings. The strong wind makes the pedestrians on sidewalks, entrances and terrace very uncomfortable and causes the pedestrian level wind environment problem. In this studies, hot-wire wind measurement, wind scouring in wind tunnel and numerical computation were carried out to evaluate the wind environment of tall buildings in the prevailing flow conditions in Beijing areas. The results obtained by three techniques were compared and mutually verified. The conclusions drawn from three approaches agree with each other. Also the advantages and limitations of each method were analyzed. It is suggested that the combination of different techniques may produce better assessment of wind environment around high buildings.     

Model identification for hydrological forecasting under uncertainty

Methods for the identification of models for hydrological forecasting have to consider the specific nature of these models and the uncertainties present in the modeling process. Current approaches fail to fully incorporate these two aspects. In this paper we review the nature of hydrological models and the consequences of this nature for the task of model identification. We then continue to discuss the history (“The need for more POWER‘’), the current state (“Learning from other fields”) and the future (“Towards a general framework”) of model identification. The discussion closes with a list of desirable features for an identification framework under uncertainty and open research questions in need of answers before such a framework can be implemented.