深海沉积物分类与命名的参数指标和主成分分析

对于南海中部(118个表层沉积物样,水深82~4 420 m)、东部(106个表层沉积物样,水深700~4 508 m)海域的表层沉积物的粒度资料按小于200 m,200~2 000 m,大于2 000 m水深段对水深、平均粒径、黏土含量进行统计分析,结果表明从陆架到陆坡再到深海,平均粒径和黏土含量随水深增加呈非常有规律的变化;把大于2 000 m水深区域再细分为大于2 500 m,大于3 000 m,大于3 500 m,结果表明平均粒径和黏土含量随水深增加几乎无变化,在南海中部水深大于2 000 m海域平均粒径为3.39~3.54μm,黏土平均含量为54.91%~55.47%;在南海东部水深大于2 000 m海域平均粒径为3.25~3.37μm,黏土平均含量为53.91%~54.56%。研究表明2 000 m水深具有划分深海沉积物的指示意义。南海中部水深大于2 000 m海域黏土平均含量为55.19%,平均粒径为3.39μm;在南海东部水深大于2 000 m海域黏土平均含量为53.91%,平均粒径为3.37μm;在南海中部、东部水深大于2 000 m海域平均粒径均小于4μm,黏土平均含量均大于50%,表明深海沉积物粒度特征是平均粒径小于4μm和黏土平均含量大于50%。黏土含量是非生物组分的代表和划分深海沉积物类型的一个独立参数,钙质生物和硅质生物组分是另外两个独立参数。南海东部海域表层沉积物中55种元素总含量为47.50%,硅、铝、钛、钠、钾、磷、钙、镁、铁、锰十种主元素含量为47.03%,其他45种元素含量为0.47%,虽然沉积物来源复杂、成因不同,但沉积物化学主成分并不复杂,主要由前10种主元素和氧元素组成。沉积物主元素铝、钙、硅分别富集于黏土、钙质沉积、硅质沉积中。通过建立沉积物生源组分与碳酸钙、三氧化二铝、二氧化硅的量化关系,可把碳酸钙、生物二氧化硅作为钙质生物和硅质生物的两个替代参数。     

Hydrologic simulation of clay‐settling areas in the phosphate mining district,Florida

Clay‐settling areas (CSAs) are one of the most conspicuous and development‐limiting landforms remaining after phosphate mining. Many questions are asked by the mining and regulatory communities with regard to the correct modelling (predictive) methods and assumptions that should be used to yield viable hydrologic post‐reclamation landforms within CSAs. Questions as to the correct methodology to use in modelling/predicting long‐term CSA hydrologic performance have historically been difficult to answer because the data and analysis to support popular hypotheses did not exist. The goal of this paper was to substantially improve the data, analysis and predictive methodology necessary to return CSAs to viable hydrologic units, and moreover, to develop better understanding of the hydrology of CSAs and their ability to support wetlands. The study site is located at the Fort Meade Mine in Polk County, Florida. In this paper, continuous model simulation and calibration of study site were conducted for the hydrologic model, Hydrological Simulation Program – FORTRAN, which was generally selected on the basis of its popularity in predicting the hydrologic behaviour of CSAs. The objective of this study was to simulate streamflow discharges and stage to estimate runoff response from these areas on the basis of the observed rainfall within the CSA. A set of global hydrologic parameters was selected and tested during the calibration by the parameter estimation software PEST. A comparison of the simulated and observed flow data indicates that the model calibration adequately reproduces the hydrologic response of the CSAs. The estimated parameters can be used as references for future application of the model. Copyright © 2012 John Wiley & Sons, Ltd.     

游离氧化铁形态转化对红粘土工程性质的影响

本文通过模拟环境中的有机质使游离氧化铁形态转化对典型红粘土工程性质的影响试验,系统地测试了游离氧化铁的形态分布与物性指标的关系。试验结果表明,在渍水条件下,游离氧化铁的形态转化对红粘土性质的影响不显著,但在渗水条件下,由于游离氧化铁的流失使得胶结作用减弱,它对红粘土工程性质的影响逐渐明显,其潜在的危害仍然是不容忽视的。     

A constitutive law for thermo-plastic behaviour of rocks: an analogy with clays

Thermo-mechanical behaviour of rocks shows phenomenological similarities to that of clays. A visible decrease of strength and an increase in ductility at elevated temperatures are observed in drained conditions. In undrained conditions the strength decrease is even more dramatic and the ductile behaviour may turn into the brittle one, if a sufficient amount of water is present in the pores at the start of the process, or it is being released during heating by the decomposition of hydrous minerals. Applying a thermo-plasticity theory, major macroscopical characteristics of behaviour may be modelled. According to this theory, the elastic domain is postulated as temperature dependent, shrinking with temperature; heating may result in expansive or compactive volumetric irreversible strain depending on the confining stress. This theory is applied to the modelling of heat effects on local changes of permeability around a cylindrical nuclear waste container disposed off in deep clays, and in the numerical simulation of a mechanism initiating deep earthquakes.     

叶蜡石、高岭石和迪开石的吸收光谱研究

对不同地区叶蜡石、高岭石、迪开石的吸收光谱测量及其高斯谱拟合说明，三各矿物的吸收光谱均由一个吸收边和三个吸收峰叠加而成。主吸收峰在562nm左右，峰高以迪开石为最大，高岭石次之，叶蜡石最低。同一地区不同颜色的叶蜡石，其主吸收峰位置随铁含量的增加向短波方向移动，相对峰高也随之增大。叶蜡石的颜色主要取决于主吸收峰的位置、高度和吸收边位置。可以认为，此吸收边为Fe^3 →O^2-荷移谱的低能拖尾部分，吸收峰则为铁离子的晶场谱带或晶场谱与Fe^2 →Fe^3 荷移的叠加。     

长江三角洲地区晚更新世地层中的古土壤特征

通过对长江三角洲两翼第四纪地层中第一层暗绿色硬粘土的剖面描述和微观分析、作者认为该硬粘土层是一古土壤层。本文根据种种观察和分析资料,探讨该粘土层的古土壤特征。     

高岭石的结晶有序度及其对纸张涂布粘浓度的影响

粘浓度是纸张涂布的一项重要指标,测定的变化范围从46.4—72％。用Hinckley方法测定了高岭石的结晶度指数,从0.57变化至1.40。当粘浓度>67％时,结晶度指数>1。粘浓度<67％,结晶度指数<1,有序高岭石有利于粘浓度提高。随着结构无序化,晶粒变小,晶片变薄,比表面增加,晶体边缘和角易破损,使粘浓度降低。结构无序化破坏了颗粒的均匀性,使颗粒长/厚比增加,粘浓度降低。高岭石八面体中Fe~(3+)的存在一定程度上影响了有序度。     

内蒙中部玄武岩残坡积膨胀土的研究

本文是我们在内蒙中部所发现的一种新型膨胀土即玄武岩残积粘土的宏观微观综合研究结果。本文揭示了在内蒙中部异常发育的残积粘土的特殊的形成环境，并从物质成分、物理化学性质、微结构等方面探讨了不良工程特性形成的机理，并进行了膨胀土的工程评价。这类膨胀土在我国北方的发现，改变了对我国北方膨胀土形成发育规律的认识。     

中国黄土与红色粘土记录的地磁极性界限及地质意义

本文报道由蓝田、陕县、洛川、西峰、平凉、兰州及靖远等剖面获得的古地磁研究结果．主要结论为：１．中国黄土剖面记录了Ｂｒｕｎｈｅｓ正极性带与Ｍａｔｕｙａｍａ负极性带，Ｂｒｕｎｈｅｓ／Ｍａｔｕｙａｍａ极性转换过程位于第８层黄土（Ｌ８）．在段家坡黄土剖面该转换过程对应的地层厚度为０．３７５ｍ，持续时间约６０００ａ．转换过程由３次极性变化构成，每次经历的时间约为４００ａ．２．Ｊａｒａｍｉｌｌｏ正极性亚带（Ｊ）位于标志层Ｌ９至Ｌ１５之间，大约Ｓ１０－Ｓ１３位置．３．Ｏｌｄｕｖａｉ正极性亚带（Ｏ）对应的地层为Ｓ２７－Ｓ３３４．Ｒｅｕｎｉｏｎ正极性亚带（Ｒ）由两部分组成，在蓝田段家坡黄土剖面分别位于Ｌ３６和Ｓ３８５．Ｍａｔｕｙａｍａ负极性带与Ｇａｕｓｓ正极性带界限（Ｍ／Ｇａ）位于黄土和红色粘土交界处，中国黄土的底界年龄为２．４８Ｍａ左右．黄土与红色粘土为整合接触关系．６．黄土下伏的红色粘土记录了Ｇａｕｓｓ正极性带，Ｇｉｌｂｅｒｔ负极性带和古地磁年表编号５（Ｅｐｏｃｈ５）．