High-Ti type N-MORB parentage of basalts from the south Andaman ophiolite suite,India

A complete dismembered sequence of ophiolite is well exposed in the south Andaman region that mainly comprises ultramafic cumulates, serpentinite mafic plutonic and dyke rocks, pillow lava, radiolarian chert, and plagiogranite. Pillow lavas of basaltic composition occupy a major part of the Andaman ophiolite suite (AOS). These basalts are well exposed all along the east coast of southern part of the south AOS. Although these basalts are altered due to low-grade metamorphism and late hydrothermal processes, their igneous textures are still preserved. These basalts are mostly either aphyric or phyric in nature. Aphyric type exhibits intersertal or variolitic textures, whereas phyric variety shows porphyritic or sub-ophitic textures. The content of alkalies and silica classify these basalts as sub-alkaline basalts and alkaline basalts. A few samples show basaltic andesite, trachy-basalt, or basanitic chemical composition. High-field strength element (HFSE) geochemistry suggests that studied basalt samples are probably derived from similar parental magmas. Al₂O₃/TiO₂ and CaO/TiO₂ ratios classify these basalts as high-Ti type basalt. On the basis of these ratios and many discriminant functions and diagrams, it is suggested that the studied basalts, associated with Andaman ophiolite suite, were derived from magma similar to N-MORB and emplaced in the mid-oceanic ridge tectonic setting.     

East African Rift System (EARS) Plume Structure: Insights from Quaternary Mafic Lavas of Turkana, Kenya

Quaternary mafic lavas from Lake Turkana (northern Kenya) provideinformation on processes operating beneath the East AfricanRift in an area of anomalous lithospheric and crustal thinning.Inferred depths of melting beneath Turkana (15–20 km)are shallower than those recorded elsewhere along the rift,consistent with the anomalously thin crustal section. The maficlavas have elevated incompatible trace element contents whencompared with mid-ocean ridge basalts, requiring an enrichmentevent in the source region. Basalts with low Sr isotopic ratios(     

Precise/ Small Sample Size Determinations of Lithium Isotopic Compositions of Geological Reference Materials and Modern Seawater by MC-ICP-MS

The Li isotope ratios of four international rock reference materials, USGS BHVO-2, GSJ JB-2, JG-2, JA-1 and modern seawater (Mediterranean, Pacific and North Atlantic) were determined using multi-collector inductively coupled plasma-mass spectrometry (MC-ICP-MS). These reference materials of natural samples were chosen to span a considerable range in Li isotope ratios and cover several different matrices in order to provide a useful benchmark for future studies. Our new analytical technique achieves significantly higher precision and reproducibility (< ± O.3%o 2s) than previous methods, with the additional advantage of requiring very low sample masses of ca . 2 ng of Li.     

Geochemical Correlation Between Metasediments of the Mfongosi Group of the Natal Sector of the Namaqua-Natal Metamorphic Province, South Africa and the Ahlmannryggen Group of the Grunehogna Province, Antarctica

The whole-rock geochemistry of metamorphosed greywackes, arenites and arkoses within the Mesoproterozoic Namaqua-Natal-Maudheim Province is interpreted with the aim of establishing geochemical correlations and defining common sediment source terrains. Metasediments of the Mfongosi Group of the Natal Sector of the Namaqua-Natal Metamorphic Province were sampled from their type area in the Mfongosi Valley. Metagreywackes from the northern limits of the Mfongosi Valley, directly adjacent to the Kaapvaal Craton, show ocean island arc signatures while metagreywackes from the southern limits of the Mfongosi Valley, near the contact with the Madidima Thrust of the Natal nappe zone, show mainly active continental margin signatures. Interleaved, geochemically distinct low-Ca+Na, high-K metamorphosed arkoses to lithic arkoses indicate a minor passive margin sediment component. Geochemical classification of low-grade Ahlmannryggen Group greywackes, arenites and arkoses of the Grunehogna Province, Antarctica, indicates both active and passive continental margin sediment sources. An oceanic island arc signature is not evident in Ahlmannryggen Group data. The active continental margin signature in both Natal Sector and Grunehogna Province metasediments potentially provides for a common link between these terranes. Discriminant Function Analysis, using three pre-defined provenance sub-sets within the Mfongosi Group and two pre-defined provenance sub-sets within the Ahlmannryggen Group, indicate that metasediments with active continental margin signatures from both groups are geochemically identical, implying that the active continental margin of the Grunehogna Province shed immature sediments westwards (African azimuths) into the developing, narrow or restricted Mesoproterozoic ‘Mfongosi Basin.’ This was accompanied by minor sediment influx from a stable continental platform, potentially the Kaapvaal Craton. Oblique and diachronous collision, initiated in the southwestern portions of the combined Natal Sector/Grunehogna Province system produced a laterally variable Mfongosi Group, which formed in the ‘Mfongosi Basin’. Coarse-grained sediments dominated in its eastern portions while basalts with thin sapropelite units dominated in its western portions.     

Geochemistry of Early Cretaceous Alkaline Ultramafic-Mafic Complex from Jasra, Karbi Anglong, Shillong Plateau, Northeastern India

An early Cretaceous alkaline ultramafic-mafic complex is emplaced within the Proterozoic rocks of Shillong plateau at Jasra, Karbi Anglong district of Assam. It is associated to the fracture system of Barapani-Tyrsad shear zone, Kopali faults, and Um Ngot lineaments and mainly comprises pyroxenite, gabbro and nepheline syenite. Few small mafic dykes, emplaced within pyroxenitic and granitic plutons, are also reported. No such dyke is reported to cut gabbros or nepheline syenites. Nepheline syenites occur either in the form of small dykes in pyroxenites or as differentiated bodies in the gabbros. Mineralogical and chemical composition of pyroxenite and gabbro clearly indicate their affinity to the alkaline magmatism. Syenitic samples show miaskitic character (agpaitic index <1), also indicates affinity with alkaline-carbonatite magmatism. Calcite is encountered in a number of pyroxenite samples. From the presented petrological and geochemical data it is difficult to establish any significant genetic relationship through simple differentiation process between these rocks. These data probably suggest that these rocks are derived from a primary carbonatite magma, generated by the low-degree melting of a metasomatized mantle peridotite. CO₂ released by this process also progressively metasomatizes the lherzolite to an alkaline wehrlite and melts derived from alkaline wehrlite (ultrabasic alkaline silicate magma) may be responsible for crystallization of Jasra alkaline ultramafic-mafic rocks.     

合肥盆地钻井地层的同位素测年与地层划分

合肥盆地内部中、新界地层大面积被第四系覆盖，其地层的时代与划分主要依赖已有的6口深井地层资料。由于缺乏可靠的化石记录，这6口深井地层时代与划分一直存在着很大的分歧，制约了对该盆地的油气勘探与远景评价。本文利用这6口深井泥岩类岩屑中自生伊利石，在其结晶度分析基础上，进行了K-Ar同位素测年，成功地获得了不同深度上的地层形成时代。据此地层年龄，文中对这6口深井所钻遇的地层进行了重新的划分。     

Geochemical characteristics of the metapelites from the Xingxingxia group in the Eastern Segment of the Central Tianshan: Implications for the provenance and paleoweathering

Clastic sedimentary rocks record a number of in-formation about the compositions and paleoweathering conditions of the source areas, and the tectonic setting of the depositional basin[1―6]. The traditionallypetrological study commonly utilizes the major com-ponents (Quartz, Feldspar and Lithics) of the silici-clastic sedimentary rocks to investigate the source rock composition and tectonic setting[7]. However, thepetrological method is somewhat limited, because many of the mafic components f…     

Delayed geochemical hazard: Concept, digital model and case study

Delayed Geochemical Hazard (DGH briefly) presents the whole process of a kind of serious ecological and environmental hazard caused by sudden reactivation and sharp release of long-term accumulated pollutant from stable species to active ones in soil or sediment system due to the change of physical-chemical conditions (such as temperature, pH, Eh, moisture, the concentrations of organic matters, etc.) or the decrease of environment capacity. The characteristics of DGH are discussed. The process of a typical DGH can be expressed as a nonlinear polynomial. The points where the derivative functions of the first and second orders of the polynomial reach zero, minimum and maximum are keys for risk assessment and harzard pridication.The process and mechanism of the hazard is due to the transform of pollutant among different species principally. The concepts of "total releasable content of pollutant", TRCP, and "total concentration of active specie", TCAS, are necessarily defined to describe the mechanism of DGH. The possibility of the temporal and spatial propagation is discussed. Case study shows that there exists a transform mechanism of "gradual release" and "chain reaction" among the species of the exchangeable and the bounds to carbonate, iron and manganese oxides and organic matter, thus causing the delayed geochemical hazard.     

福建沿海土壤地球化学分类及基准值研究

利用多目标区域地球化学调查成果,探讨了福建沿海土壤地球化学分类的方法,提出了分类命名方案和诊断标准,将研究区土壤按SiO₂含量划分为铁铝土、硅铝土、铝硅土、硅土4个大类,其中硅铝土又分为一般硅铝土、铁质硅铝土、钾质硅铝土、硫铁质硅铝土4个亚类,铝硅土分为一般铝硅土和钾质铝硅土2个亚类;提出了在各种统计量中,中值比较客观地反映元素含量背景,适合作为基准值;给出了研究区各类土壤的分布图和52种元素及pH的基准值,分析了其成因和农业利用情况。