塔里木盆地早二叠世岩浆特征及其对油气成藏关系初探

塔里木盆地早二叠世裂谷盆地阶段有一次强烈的岩浆活动,主要为玄武岩—中酸性凝灰岩喷发和大规模基性岩墙群的侵入,玄武岩K-Ar法同位素年龄为241~278Ma,而辉长岩的Sm-Nd法年龄为259Ma。火山活动产生的能量使得塔里木盆地内的寒武系—奥陶系烃源岩大量生烃并运移,自生伊利石K-Ar年龄测定数据显示哈得4石炭系油藏、塔中4CⅢ油藏油气充注时间为224~275Ma,与上述火成岩的活动时间相当。东河砂岩,一套深埋的优质储层,其形成的原因可能是二叠纪末油气的注入并导致其后期深埋时只有机械压实而无其他成岩作用的缘故。     

赣南天门山-红桃岭钨锡矿田成岩成矿时代精细测定及其地质意义

素有“世界钨都”美誉的赣南产有密集的与花岗岩类侵入体密切相关的钨锡多金属矿床,然而,目前对钨锡成矿和花岗岩成岩年龄还缺乏很好的约束。本文以天门山-红桃岭钨锡矿田为对象,在详细的矿田地质调查和典型矿床解剖基础之上,采用高精度测年技术开展了成岩成矿年代学研究。利用锆石SHRIMPU-Pb法,分别获得天门山似斑状黑云母二长花岗岩体和红桃岭黑云母花岗岩体成岩年龄分别为151.8±2.9Ma(n=14,MSWD=1.3)和151.4±3.1Ma(n=11,MSWD=0.34);利用辉钼矿Re-Os等时线法,分别获得牛岭内带石英脉型和樟斗外带石英脉型钨矿成矿年龄分别为154.9±4.1~154.6±9.7Ma和149.1±7.1Ma(n=6,MSWD=1.3)。可见,本区钨矿床成矿和与之有密切成因关系的花岗岩成岩年龄限定在晚侏罗世,对应于区域华南中生代第二次大规模成矿作用,钨成矿与花岗岩成岩基本不存在时差。     

多接收器等离子体质谱(MC-ICPMS)高精度测定Nd同位素方法

多接收器等离子体质谱是近年发展起来的高精度同位素分析手段之一,通过用等离子体质谱测量Nd国际标准材料La Jolla和JMC Nd203以及实际样品GBW04419,研究MC-ICPMS测量Nd的质量分馏特点,解决MC-ICPMS测量的关键所在质量分馏校正.通过修正分馏系数,可以实现理想的分馏校正.结果显示出所得到的分析精度达到热电离质谱的测量水平.具有实际地质样品代表性的实验室内部标准CAGS-Nd-1重现性长期分析结果为:143Nd/144Nd=0.512072±0.000008(2σ,n=140).     

硅岩的Rb-Sr同位素组成特点及其地质意义

通过对扬子地台和东昆仑山地区的不同时代、不同成因、成分上差异较大的硅岩Rb-Sr同位素组成的对比研究，探讨其物源和形成环境，利用所测Rb-Sr等时线年龄，有效的解决硅岩的地层年代，开创硅岩测年的应用前景。     

江西周潭群同位素年龄特征及其地质意义

通过对江西弋阳、余江两地周潭群变质岩系中斜长角闪的Ｓｍ－Ｎｄ、锆石同位素研究,确认周潭群的形成时代为１１００～１２００Ｍａ,属中元古代地层,而不是晚元古代地层,该岩系形成后经受了晋宁（９００Ｍａ左右）和印支运动（２００Ｍａ左右）的区域构造作用影响。     

碱性玄武岩形成的时限及其地质意义

中国华北克拉通及邻区的早前寒武纪不存在碱性玄武岩。全球范围内碱性玄武岩的形成也存在时限性，它们在中新生代以来相对大量的出现。碱性玄武岩可划分为钾质碱性玄武岩和钠质碱性玄武岩两大类，后者还可作进一步划分。它们在同位素组成和元素组成上存在相互过渡的变化，这与地幔源区外来加入物质的种类和比例不同有关。高压和低程度熔融是所有碱性玄武岩形成的必要条件。研究表明，碱性玄武岩形成具时限性主要与地球热状态从热向冷的历史演化有关。碱性玄武岩的形成需要地幔俯冲作用，可达到相当深度的地幔俯冲作用只是到了太古宙以后才发生，并在中新生代以来达到高潮。     

吐哈盆地砂岩型铀矿U-Pb同位素地质特征

吐哈盆地十红滩砂岩型铀矿主要成矿年龄为48±2Ma、28±4Ma。盆地西南部蚀源区觉罗塔格山片麻状花岗岩的形成年龄为422±5Ma、斑状花岗岩的形成年龄为268±23Ma。赋矿地层西山窑组(J2x)砂体碎屑锆石U Pb等时线年龄为283±67Ma ,证实花岗岩侵入体是含矿砂体的主要物质来源。含矿层位的富铀沉积砂体及蚀源区富铀的岩体、石炭系碎屑岩以及火山碎屑岩等 ,构成铀成矿铀源。     

登封群的定年及其划分问题的探讨

对登封群人们先后采用过K—Ar、Rb-Sr、U—Pb、单颗粒锆石Pb-Pb、Sm—Nd等多种同位素定年方法。由于不同方法得到的结果差别很大,直接影响了对登封群的认识,因而对登封群出现了多种划分方案。本文综合分析后认为,登封群花岗-绿岩地体形成于新太古宙末期(2500～2600Ma),难以划分出元古代的地层单元。另外,对已有的同位素测年成果使用上要结合样品的地质、地球化学特征进行具体分析,才能得出合理的解释。     

Molecular and isotopic compositions of bitumens in Silurian tar sands from the Tarim Basin,NW China: Characterizing biodegradation and hydrocarbon charging in an old composite basin

Biodegradation and oil mixing in Silurian sandstone reservoirs of the Tarim Basin, one of the largest composite basins in China, were investigated by analyzing the molecular characteristics and stable carbon isotopic signatures of low-molecular-weight (LMW) saturated hydrocarbons and high-molecular-weight (HMW) asphaltenes. Detection of 25-norhopanes and 17-nortricyclic terpanes in most Silurian tar sands from the Tabei Uplift in the Tarim Basin suggests a much greater degree of biodegradation here than in the Tazhong Uplift. This explains the relatively more abundant tricyclic terpanes, gammacerane, pregnane and diasteranes in tar sands from the Tabei Uplift than in those from the Tazhong Uplift. Hence, care must be taken when assigning oil source correlations using biomarkers in tar sands because of the biodegradation and mixing of oils derived from multiple sources in such an old composite basin. Asphaltenes in the tar sands seem to be part of the oil charge before biodegradation, depending on the relative anti-biodegradation characteristics of asphaltenes, the similarity in carbon isotopic signatures for asphaltenes and their pyrolysates, and the consistent product distribution for flash pyrolysis and for regular steranes in asphaltene pyrolysates, regardless of whether the tar sands were charged with fresh oil. According to the relative distributions of regular steranes and the relatively abundant 1,2,3,4-tetramethylbenzene significantly enriched in ¹³C, the oil sources for asphaltenes in the tar sands might be related to lower Paleozoic marine source rocks formed in euxinic conditions. Nevertheless, the relatively low abundance of gammacerane and C₂₈ regular steranes observed in asphaltene pyrolysates and residual hydrocarbons, within limited samples investigated in this work, made a direct correlation of oils originally charged into Silurian tar sands with those Cambrian source rocks, reported so far, seem not to be possible. Comparison of carbon isotopic signatures of n-alkanes in asphaltene pyrolysates with those of LMW saturated hydrocarbons is helpful in determining if the abundant n-alkanes in tar sands are derived from fresh oil charges after biodegradation. The limited carbon isotopic data for n-alkanes in LMW saturated hydrocarbons from the tar sands can be used to classify oils charged after biodegradation in the composite basin into four distinct groups.     

Campanian Climatic Change: Isotopic Evidence from Far East, North America, North Atlantic and Western Europe

Paleoclimatic settings have been reconstructed for the Campanian using original oxygen-isotopic analyses of well-preserved molluskan and foraminifera shells from Russian Far East, Hokkaido, USA, Belgium and some DSDP holes (95, 98, 102, 390A, and 392A) in North Atlantic. Early Early Campanian climatic optimum has been recognized from data on high bottom shelf water paleotemperatures in middle latitudes of both the western circum-Pacific (to 24.2°C) and the eastern circum-Pacific (to 26.4°C) areas and high bottom shallow water paleotemperatures in high latitudes of the Koryak Upland (22.4–25.5°C), which agrees with the data on the Campanian Barykovskaya flora in high latitudes (Golovneva and Herman, 1998) and Jonker flora and its equivalents in middle latitudes. Judging from the data on comparatively high bottom shallow water paleotemperature values in high latitudes, South Alaska (19.4°C) and the Koryak Upland (22.4–25.5°C), we also expect Latest Campanian temperature maximum, which has not been confirmed, however, for low and middle latitudes by neither of isotopic nor paleobotanic data now. Main climatic tendency during the Campanian (with the exception of Latest Campanian) has been learned from isotopic composition of Campanian aragonitic ammonoid shells from the Hokkaido-South Sakhalin (Krilyon) marine basin. In contrary to Huber’s et al. (2002) assumption, we expect warm greenhouse conditions during the most part of the Campanian.