阿拉善宗乃山岩体东南缘花岗岩LA-ICP-MS锆石U-Pb年龄与地球化学特征

阿拉善宗乃山岩体东南缘分布多种类型的花岗岩,本文主要采用岩相学、激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)锆石U-Pb定年、岩石地球化学等技术手段,对宗乃山岩体东南缘岩石类型、年代学、源岩特征以及构造背景进行了研究。结果表明:岩石类型主要为碱性-钙碱性准铝质花岗岩和闪长岩;单颗粒锆石分析获得黑云母斜长花岗岩年龄为236.8±1.9 Ma~249.7±2.6 Ma,片麻状花岗岩年龄为268.1±1.1 Ma,岩体成岩时期主要为华力西晚期和印支期早期,具有多期侵入的特征。该岩体岩石源岩为I型花岗岩,源于地壳火山弧区和同碰撞区,表明由于洋壳俯冲作用,在宗乃山东南缘形成了岛弧花岗岩侵入体。LA-ICP-MS锆石U-Pb定年技术为洋壳俯冲提供了年代学约束,确定了研究区碰撞时间为早于236.8±1.9 Ma。     

Stable isotopic compositions and controlling factors of precipitation and atmospheric vapour in the headwaters of the Shule River

Stable isotopic compositions of precipitation (δ¹⁸O_p, δ²H_p and d-excess_p) and atmospheric vapour (δ¹⁸O_v, δ²H_v and d-excess_v) with high spatial–temporal resolution are crucial in revealing hydrologic cycle. Based on the variation characteristics of δ¹⁸O_p/δ¹⁸O_v, δ²H_p/δ²H_v and d-excess_p/d-excess_v in the headwaters of the Shule River (HSR) on hourly and daily scales from June to September 2018, this study analysed the relationships between δ¹⁸O_p/δ²H_p and δ¹⁸O_v/δ²H_v combined with the equilibrium fractionation model, as well as δ¹⁸O_p/δ¹⁸O_v and meteorological factors. The slopes of local meteoric water line (LMWL) and the δ²H_v-δ¹⁸O_v fitting equation were similar (7.96 and 7.94) with both intercepts exceeding 10, reflecting the great contribution of recycling moisture. The values of δ¹⁸O_v/δ²H_v were lower than δ¹⁸O_p/δ²H_p but with consistent variation patterns throughout the period. The equilibrium simulation results suggested that precipitation and atmospheric vapour almost approached isotopic equilibrium state, especially during monsoon intrusion period. Affected by monsoon intrusion, the slopes and intercepts of the LMWLs and the δ²H_v-δ¹⁸O_v fitting equations were smaller than those during non-monsoon period and d-excess and δ¹⁸O were negatively correlated. Relative humidity had significant negative correlations with δ¹⁸O_p and δ¹⁸O_v in the whole period, however, the positive correlations between δ¹⁸O_p/δ¹⁸O_v and temperature were observed during non-monsoon and monsoon intrusion period, respectively. Our results demonstrated that precipitation and atmospheric vapour isotopic compositions exhibited consistency under the influence of diverse moisture sources, while more complex relationships were found between δ¹⁸O_p/δ¹⁸O_v and meteorological factors. This research provided evidence for using the isotopic compositions of atmospheric vapour to indicate moisture sources, and can improve understanding of the water cycle and eco-hydrological process from the perspective of the interaction between water and gas phases of the inland river basin in northwest China.     

同位素填图与深部物质探测(Ⅱ)：揭示地壳三维架构与区域成矿规律

地球深部是大规模成矿作用的“驱动机”、“供应源”和“传输带”。深入揭示深部物质组成与分布、物质循环与能量转换、三维架构与动力过程,对理解成矿作用至关重要。岩浆岩“探针”及区域同位素(如全岩Nd、锆石Hf)填图是探索深部物质组成与演化过程的主要手段,可以探测地壳深部物质组成的三维架构,揭示新生地壳/古老地壳/再造地壳的空间分布与时空演变,从而为提升区域成矿规律认识提供深部物质制约证据,有助于成矿潜力的定量半定量评价及其区域成矿预测。文章重点总结和探讨了岩浆岩全岩Nd同位素和锆石Hf同位素区域填图在解决地壳三维架构与成矿规律方面的应用成果,深入探讨了巨量岩浆岩发育的深部驱动机制及其成矿制约,对比总结了不同类型造山带(如中亚增生造山带、青藏高原碰撞造山带、秦岭复合造山带等)和不同克拉通的地壳深部组成结构与成矿制约特色。研究显示：不论是什么造山带和克拉通,深部年轻地壳分布区制约了铜金、铜镍等矿床的形成分布;古老地壳控制了大型钼矿、铅锌矿、稀有金属等矿产;两者过渡地带常常发育铁矿等。这些研究不仅揭示了区域成矿规律,而且对成矿预测与成矿潜力评价有潜在的应用价值,有可能成为成矿规律研究特别是深部物质探测及成矿背景研究的新方向。     

渤海及北黄海河流悬浮颗粒碳氮同位素时空分布及源解析

选择流入渤海和北黄海的36条主要河流为研究对象,对比了平水期、丰水期和枯水期水体中悬浮颗粒物和河流表层沉积物的碳和氮稳定同位素的地球化学特征,并对颗粒物有机质碳和氮来源进行分析。结果表明,水体悬浮有机质碳同位素总体上表现为δ13C平水期δ13C丰水期δ13C枯水期的特点,δ15N值呈δ15N丰水期δ15N平水期δ15N枯水期的特点。渤海和北黄海的主要入海河流悬浮颗粒物有机质的来源具有明显的季节性差异,悬浮颗粒有机质碳平水期(春秋季)来源以C3植物、土壤有机质和水生藻类为主,丰水期(夏季)碳的各来源中浮游植物的贡献率明显增大,枯水期(冬季)则表现为陆源C3植物分解和水源性有机质的混合来源;悬浮颗粒态氮的来源与季节性降水量、生活污水、合成化肥及河流内源性水生植物密切相关。     

中亚造山带东部岩浆热液矿床时空分布特征及其构造背景

中亚造山带东部是古亚洲洋构造域、鄂霍茨克洋构造域和古太平洋构造域复合叠加区域,矿产资源丰富。本文收集2000—2014年公开发表文献中岩浆热液矿床约1 200个同位素年龄数据,整理出201个较为可靠的年龄数据,通过数字化编图,揭示成矿的时空分布特征及形成背景。结果显示:中亚造山带东部成矿作用始于寒武纪,出现6个重要成矿期:510~473、373~330、320~253、250~210、210~167、155~100 Ma。510~473 Ma(峰值507 Ma),矿床主要分布在大兴安岭—小兴安岭—张广才岭和北山地区,零星发育热液脉型和斑岩型铁铜金钨矿床,与古亚洲洋开始俯冲及微陆块碰撞拼合有关。373~330 Ma(峰值372Ma),矿床主要分布在南蒙古奥尤陶勒盖地区,发育超大型斑岩型铜金矿床,形成于古亚洲洋俯冲环境。320~253 Ma,矿床主要分布在大兴安岭南段,发育少量斑岩型铜矿床和造山型金矿床;其中,298 Ma在大兴安岭南段首次出现以钼为主的斑岩型矿床,指示该区板块俯冲增生向拼贴转变逐渐过渡。250~210 Ma(峰值244 Ma),在蒙古—鄂霍茨克造山带东侧额尔古纳—中蒙古地块主要形成斑岩型铜矿床,可能与蒙古—鄂霍茨克洋俯冲有关;以东地区,主要在大兴安岭南段和辽远地块形成斑岩型钼矿床,在张广才岭发育岩浆熔离型铜镍矿床,反映了古亚洲洋闭合后伸展环境。210~167 Ma(峰值170 Ma),在蒙古—鄂霍茨克造山带西侧乌兰巴托西北部发育造山型-斑岩型金矿床,其东侧额尔古纳地区形成斑岩型铜钼矿床,可能与蒙古—鄂霍茨克洋俯冲碰撞有关;在吉黑东部—张广才岭—小兴安岭—大兴安岭,发育斑岩型钼铜矿床和矽卡岩型铅锌钨金矿床组合,可能属于古太平洋板块向西俯冲成矿体系。155~100 Ma(峰值136 Ma),中亚造山带东部整体处于伸展环境;其中,155~120 Ma在额尔古纳地区主要发育浅成低温热液型银铅锌矿床和造山型金矿床,大兴安岭北段发育斑岩型钼矿床,可能反映了额尔古纳地区和大兴安岭北段受蒙古—鄂霍茨克洋碰撞后伸展环境控制,而在吉黑东部形成浅成低温热液型金矿床,大兴安岭南段发育热液脉型-矽卡岩型锡矿床,可能受古太平洋板块向北俯冲弧后伸展的控制;120~100 Ma沿着华北克拉通和佳蒙陆块边缘发育浅成低温热液型-斑岩型金钼矿床。本研究综合岩浆热液矿床时空分布和矿床类型,进一步揭示了古亚洲洋构造域控制中亚造山带东部古生代成矿作用持续到晚二叠世(到早三叠世),并在晚三叠世叠加古太平洋构造域成矿体系,而额尔古纳—中蒙古地块成矿作用在三叠纪开始主要受蒙古—鄂霍茨克洋构造域限定,并持续到早白垩世早期。     

中天山科克苏河地区隆升剥蚀历史——来自(U-Th)/He年龄的制约

天山是中亚造山带重要组成部分,其中-新生代构造热演化及隆升剥露史研究是认识中亚造山带构造变形过程与机制的关键.本文应用磷灰石(U-Th)/He技术重建中天山南缘科克苏河地区中-新生代构造热演化及隆升剥蚀过程.磷灰石(U-Th)/He数据综合解释及热演化史模拟表明该地区至少存在晚白垩世、早中新世、晚中新世3期快速隆升剥蚀事件,起始时间分别为~90Ma、~13Ma及~5Ma,且这3期隆升剥蚀事件在整个天山地区具有广泛的可对比性.相对于磷灰石裂变径迹,磷灰石(U-Th)/He年龄记录了中天山南缘地质演化史中更新和更近的热信息,即中天山在晚中新世(~5 Ma)快速隆升剥蚀,其剥蚀速率为~0.47mm·a~(-1),剥蚀厚度为~2300m.总体上,中天山科克苏地区隆升剥蚀起始时间从天山造山带向昭苏盆地(由南向北)逐渐变老,表明了中天山南缘隆升剥蚀存在不均一性,并发生了多期揭顶剥蚀事件.     

柴北缘胜利口东地区白云母二长花岗岩锆石U-Pb年代学、地球化学及Hf同位素

[研究目的]柴北缘地区分布着大量早古生代花岗岩,是否存在与大陆深俯冲和早期碰撞阶段的岩浆活动,截至目前研究资料较少,制约了对柴北缘地区大地构造背景演化的认识.[研究方法]本文对胜利口东地区白云母二长花岗岩进行锆石U-Pb年代学、岩石地球化学及Hf同位素研究.[研究结果]通过LA-ICP-MS锆石U-Pb同位素测年,获得...     

Chronology and petrogenesis of the Hejiazhuang granitoid pluton and its constraints on the Early Triassic tectonic evolution of the South Qinling Belt

The Hejiazhuang pluton is located in the South Qinling Tectonic Belt(SQTB)in the north side of the Mianxian-Lueyang Suture Zone,and consists dominantly of granodiorites.LA-ICP-MS zircon U-Pb dating and Lu-Hf isotopic analyses reveal that these granodiorites of the Hejiazhaung pluton emplaced at~248 Ma,and show a large variation in zirconεHf(t)values from4.8 to 8.8.These granodiorite samples are attributed to high-K to mid-K calc-alkaline series,and characterized by high SiO2(66.6%–70.0%),Al2O3(15.04%–16.10%)and Na2O(3.74%–4.33%)concentrations,with high Mg#(54.2–61.7).All samples have high Sr(627–751 ppm),Cr(55–373 ppm)and Ni(17.2–182 ppm),but low Y(5.42–8.41 ppm)and Yb(0.59–0.74 ppm)concentrations with high Sr/Y ratios(84.90–120.66).They also display highly fractionated REE patterns with(La/Yb)N ratios of 18.9–34.0 and positive Eu anomalies(δEu=1.10–2.22)in the chondrite-normalized REE patterns.In the primitive mantle normalized spidergrams,these samples exhibit enrichment in LILEs but depletion in Nb,Ta,P and Ti.These geochemical features indicate that the granodioritic magma of the Hejiazhuang pluton was derived from the partial melting of hybrid sources comprising the subducted oceanic slab and sediments,and the melts were polluted by the mantle wedge materials during their ascent.The emplacement ages and petrogenesis of the Hejiazhuang pluton prove that the initial subduction of the Mianlue oceanic crust occurred at~248 Ma ago,and the SQTB was still under subduction tectonic setting in the Early Triassic.     

茶叶中铅同位素比值的测定方法

为了给铅同位素示踪技术在研究茶叶中重金属铅来源的应用奠定基础,通过大量的茶叶炭化、灰化条件试验和铅的分离、纯化、富集与质谱测定试验,拟定了一套茶叶中铅同位素比值的测定方法:将称好的茶叶置于瓷坩埚中,在电热板上小火炭化完全后,移入马弗炉中灰化,用盐酸溶解灰分,转化为混合酸介质,然后上柱分离解吸,蒸干并上质谱测定.该法打破传统,改用盐酸溶解灰分,克服了用硝酸溶样总是有棕色沉淀物的难点.利用这一流程测得的茶叶样品的 207Pb/206Pb的精度( 2σ)优于± 0.05%. 208Pb强度一般均在 1 V以上.监控分析流程的国际标准物质 NBS 981的 207Pb/206Pb为 0.914 49± 0.000 04(其证书值为 0.914 64± 0.000 33),全流程本底铅为 1.6× 10-8量级.     

吉林中部晚三叠世和早侏罗世两期铝质A型花岗岩的厘定及对吉黑东部构造格局的制约

高精度同位素年代学和岩石学、元素地球化学研究结果表明,吉林省中部地区存在晚三叠世和早侏罗世两期铝质A型花岗岩。其中三道河正长花岗岩的锆石LA ICPMS年龄为(216±3) Ma,形成于晚三叠世,受控于华北板块和其北侧板块在晚二叠世—早三叠世沿西拉木伦河—长春—延吉缝合带碰撞拼合后的岩石圈伸展作用,标志古亚洲洋构造域的演化结束。天桥岗碱长花岗岩的锆石SHRIMP和TIMS年龄分别为(182±3) Ma和(188±4) Ma,全岩Rb Sr等时线年龄为(185±4) Ma,形成于早侏罗世,可能是与佳木斯板块和松嫩—张广才岭板块在早侏罗世早期沿嘉荫—牡丹江缝合带碰撞拼合有关的伸展作用的产物。这次板块碰撞作用很有可能标志着东北地区东部此时已经开始进入滨太平洋构造域的演化阶段。更详细的研究显示,两期A型花岗岩岩浆都来源于年轻的基性玄武质下地壳的部分熔融,岩浆经历了分离结晶作用。