黑龙江嘉荫连珠山金矿床成岩成矿年代学及其地质意义

连珠山矿床位于小兴安岭北麓,是一个产于花岗岩内部断裂体系的蚀变岩型金矿床。为了限定其成矿时代与成矿地质背景,本文对其赋矿围岩黑云母二长花岗岩和石英闪长岩进行了岩石地球化学、锆石U-Pb和绢云母40Ar/39Ar年代学的系统研究。定年结果表明黑云母二长花岗岩形成时代为中三叠世(243.7±1.3Ma,MSWD=0.77,n=12),岩浆上侵过程中受到早古生代(474~438Ma)和中二叠世(267~261Ma)的岩浆混染,而石英闪长岩形成于晚三叠世(215.3±1.3Ma,MSWD=0.35,n=17);黄铁绢英岩化矿石中的绢云母40Ar/39Ar坪年龄为194.2±2.0Ma,指示为早侏罗世成矿;元素地球化学特征显示连珠山侵入岩为准铝质-弱过铝质、高钾钙碱性岩石系列,具有I型花岗岩的地球化学属性;轻稀土元素富集,相对亏损重稀土元素,且具有弱的负Eu异常;富集大离子亲石元素(LILE),亏损高场强元素(HFSE)。结合小兴安岭-张广才岭地区已有年代学资料和区域构造演化特征,认为其成矿地质背景为兴蒙造山晚期与古太平洋板块俯冲转换期,或成矿发生在兴蒙造山期后的伸展阶段。     

西藏拉抗俄斑岩铜钼矿床辉钼矿Re-Os同位素测年及其地质意义

西藏冈底斯成矿带拉抗俄斑岩铜钼矿床位于西藏特提斯构造域拉萨地块东段中南部,是近年来青藏高原地质大调查项目评价的重点矿床之一。本文在钻孔地质编录的基础上,采用辉钼矿Re-Os同位素测年技术,对拉抗俄铜钼矿床中8件产于花岗闪长斑岩中的辉钼矿进行定年,获得了拉抗俄矿床辉钼矿成矿年龄,辉钼矿Re-Os模式年龄为(13.20±0.20)Ma~(13.64±0.21)Ma,加权平均值为(13.38±0.15)Ma,等时线年龄为(13.12±0.44)Ma,代表了拉抗俄斑岩铜钼矿床的成矿时代,成矿作用发生于中新世。辉钼矿中Re的含量为343.6×10-6~835.7×10-6,平均557.8×10-6,指示其成矿物质中有幔源物质加入。拉抗俄斑岩铜钼矿床形成于印度—亚洲大陆碰撞造山带碰撞过程的伸展背景,其成矿年龄与冈底斯斑岩铜矿带东段中亚带众多斑岩-矽卡岩成矿系统年龄基本一致(17~12 Ma),相对于同一矿集区的驱龙、甲玛、邦铺斑岩-矽卡岩型铜多金属矿的成矿年龄小2~3 Ma,但其形成受控于相同的成矿地球动力学背景。     

浙中后山店花岗斑岩体的LA-ICP-MS锆石U-Pb定年、锆石Hf同位素及其地质意义

针对浙中地区后山店花岗斑岩体进行高精度LA-ICP-MS锆石U-Pb测年和锆石Lu-Hf同位素的测定。测年结果显示其加权平均年龄值为148.5 Ma±1.2 Ma(MSWD=1.4),说明浙中地区有晚侏罗世侵入岩的存在,属于燕山早期晚阶段岩浆活动的产物,其成岩时代可能代表了古太平洋构造域下的板内岩浆活动和陆缘弧间的过渡阶段。锆石的εHf(t)值为-10.3~-3.5,均为负值,二阶段模式年龄tHf2(Ma)变化范围主要集中于1 400 Ma~1 829 Ma之间,反映其物质来源可能为中元古代下地壳基底物质,并在成岩过程中有幔源组分的参与。     

The Paleoceanography during the Time with High δ13C of Phanerozoic marine carbonates

Carbon isotopic composition of marine carbonates is a record for various important geological events in the process of earth development and evolution. The carbonates of Carboniferous, Permian and Triassic, as the transition from Paleozoic to Mesozoic-Cenozoic have very high ¹³C value. Taking this as the main point, and combined with the oxygen, strontium isotopic composition in carbonates, distribution of carbonate basin area through geologic time, the correlation of carbon isotopic composition of marine carbonates to sea level change, organic carbon burial flux, exchange of CO₂ content in atmosphere and ocean, and long cycle evolution of the earth ecosystems were approached. The results are shown as follows: ①The interval of ¹³C >3‰ during Phanerozoic was concentrated in Carboniferous, Permian and the beginning of Triassic, but the beginning of Triassic was characterized by higher frequency and larger fluctuations in ¹³C value during a short time, whereas the Carboniferous-Permian presented a continuously stable high ¹³C value, indicating a larger amount of organic carbon accumulation in this time interval. Relatively high ¹⁸O values during this time was also observed, showing a long time of glaciations and cold climate, which suggest a connection among rapid organic carbon burial, cold climate, as well as pCO₂ and pO₂ states of atmosphere. ②The over consumption of atmosphere CO₂ by green plants during the time with high ¹³C of seawater forced CO₂ being transferred from ocean to atmosphere for the balance, but the decrease in the seawater amount and water column pressure caused by the global cooling could weaken dissolution capacity of CO₂ in seawater and carbon storage of marine carbonates, and also reduce the carbonate sedimentary rate and decrease the carbonate basin area globally from Devonian to Carboniferous and Permian. During the middle-late Permian carbonate was widely replaced by siliceous sediments even though in shallow carbonate platform, which resulted in the decrease of marine invertebrates, suggesting the Permian chert event should be global. ③The Phanerozoic ⁸⁷Sr/⁸⁶Sr trend of seawater showed a sharp fall in Permian and drop to a minimum at the end of the Permian, indicting input of strontium from the submarine hydrothermal systems (mantle flux). Such process should accompany with a supplement of CO₂ from deep earth to atmosphere and ocean system, but the process associated with widespread volcanism and rises of earth’s surface temperature pricked up the mass extinction during the time of end Permian. ④Cold climate and increase of continental icecap volume, the amalgamation of northern Africa and Laurentia continentals were the main reasons responsible for the sea level drop, but the water consumption result from the significantly increased accumulation of organic carbon should also be one of the reasons for the sea level drop on the order of tens of meters. ⑤The mass extinction at the end Permian was an inevitable event in the process of earth system adjustment. It was difficult for marine invertebrates to survive because of the continuously rapid burial of organic carbon, and of the decrease of sea water amount and its dissolution ability to CO₂. At last, at the end of Paleozoic, the supplement of CO₂ to atmosphere and ocean by widely magma activities resulted in a high temperature of earth surface and intensified mass extinction.     

五台山蒋村地区四集庄组——对滹沱群时代的再限定

滹沱群是华北最典型的古元古界地层之一,限定其时代对建立早期地层年代格架和探讨华北早前寒武纪地质演化过程意义重大。本文对五台山地区蒋村镇附近的滹沱群地层进行了详细研究,从与蒋村砾岩中石英斑岩砾石相同的基岩中选取了2件石英斑岩样品,并获得其锆石U-Pb年龄结果分别为(2166±17)Ma和(2138±17)Ma。据此,限定蒋村地区碎屑沉积岩时代应小于2138 Ma。结合四集庄组底部发育厚层的砾岩和区域内2.2~2.1 Ga岩浆事件,我们进一步认为滹沱群底界年龄为~2.2 Ga。由于滹沱群豆村亚群和东冶亚群经历了同期褶皱变形作用,而侵入于蒋村四集庄组未变形正长花岗岩脉的锆石U-Pb年龄结果为(1816±18)Ma。因此,本文限定豆村亚群、东冶亚群的时代为2.2~1.82 Ga。石英斑岩中锆石Lu-Hf同位素分析结果为176Lu/177Hf为0.000717~0.002239,176Hf/177Hf为0.281399~0.281563,其176Hf/177Hfi为0.281315~0.281496和εHf(t)为–3.37~4.11,变化范围较大,初步认为其源自于新太古代早期上地壳的部分熔融并有地幔物质添加。     

甘肃北山小西弓金矿区石英正长斑岩LA-ICP-MS锆石U-Pb年龄和地球化学特征

通过高精度的LA-ICP-MS锆石U-Pb测年,获得北山南带小西弓金矿区石英正长斑岩的形成年龄为247.5±2.2Ma,属中三叠世。地球化学分析表明,该岩体为准铝质、钾玄岩系列,主量元素高硅(Si O_2=65.8%~66.2%)、富碱(Na_2O+K_2O=8.99%~9.41%)、低钙(Ca O=1.72%~2.19%)、贫镁(Mg O=0.63%~0.70%);轻稀土元素富集,重稀土元素亏损,弱负Eu异常。大离子亲石元素Rb、Th、U、K和Pb富集,同时Ba、Sr、P、Ti和Eu亏损,并具高104*Ga/Al值和高Zr+Nb+Ce+Y含量,表现出A型花岗岩的特征。北山南带三叠纪岩浆活动强烈,高分异I型-A型花岗岩大量发育,暗示区域内三叠纪处于造山后伸展环境。     

青藏高原羌塘中部中—上奥陶统达瓦山组的建立及意义

首次在藏北羌塘中部达瓦山地区识别出一套复理石沉积,厚度大于3000m,未见顶底,岩石组合以变质砂岩、杂砂岩和千枚岩为主,夹双峰式火山岩,火山岩岩性为流纹岩和玄武岩。用LA-ICP-MS同位素测定技术对流纹岩夹层中的锆石进行了U-Pb同位素测定,获得锆石的年龄为454.0±2.0Ma和458.3±1.8Ma,时代为中晚奥陶世达瑞威尔—桑比期,代表了达瓦山组的主体形成时代。在剖面测制和区域对比的基础上建立了中—上奥陶统达瓦山组,代表冈瓦纳大陆北缘中—晚奥陶世裂谷型深水-半深水复理石沉积。中—上奥陶统达瓦山组的发现和建立完善了该区中晚奥陶世的地层系统,进一步确定该区中—晚奥陶世洋盆的存在,对冈瓦纳大陆北缘中—晚奥陶世岩相古地理研究具有重要意义。     

滇西新街岩体LA-ICP-MS锆石U-Pb年龄、Hf同位素和地球化学及其构造意义

新街岩体位于昌宁-孟连带北段,主要岩性为二长花岗岩。LA-ICP-MS锆石U-Pb定年结果表明,新街岩体侵位于约82Ma。岩体Si O2含量为74.28%~75.17%,富钾(K2O/Na2O=1.44~1.73)和较低钙Ca O(0.37%~0.41%),铝饱和指数(A/CNK)为1.121~1.156,富集Rb、Th、K、LREE等元素,相对亏损Nb、Ta、Ti、Zr、Hf等高场强元素。这些特征表明,新街岩体属于强过铝质S型花岗岩。新街岩体负且变化范围大的锆石εHf(t)值(-16.9~-0.5)和古老的Hf同位素地壳模式年龄(1.19~2.28Ga),表明其主要来源于古老地壳物质的重熔,并有不同程度的幔源物质加入。由于喜马拉雅新特提斯洋封闭发生在65Ma左右,新街岩体很可能是在喜马拉雅新特提斯洋洋壳俯冲的地球动力学背景下形成的。     

大兴安岭北段争光金矿英安斑岩地球化学特征、锆石U-Pb年龄及Hf同位素组成

争光金矿位于大兴安岭北段多宝山矿集区内,矿区内火成岩的成岩时代、岩石成因及成岩背景研究薄弱。因此,本文对矿区内英安斑岩进行了主微量元素、锆石U-Pb年龄和Hf同位素组成的系统研究,以期为探讨同时代火成岩的成因及矿床成矿背景提供帮助。锆石LA-ICP-MS U-Pb测年结果表明,争光金矿英安斑岩形成于早奥陶世(478~481Ma)。岩石地球化学特征显示,英安斑岩属准铝-过铝质高钾钙碱性系列,具有SiO_2≥56%(平均为63.91%)、高铝(Al_2O_3平均14.85%)、低镁(MgO平均2.70%)、低Y和Yb(Y=6.00×10~(-6)~7.74×10~(-6),Yb=0.70×10~(-6)~0.92×10~(-6))、高锶(平均368×10~(-6))、高Mg#(56.84~60.60)、轻重稀土分馏明显[(La/Yb)N=8.74~11.54]和Eu异常不明显的特点,类似于俯冲洋壳成因埃达克岩。锆石εHf(t)介于13.03~13.31之间,两阶段模式年龄(tDM2)为605~624Ma。综合岩石地球化学特征和锆石Hf同位素组成,我们认为争光英安斑岩由俯冲的新生洋壳发生部分熔融形成。本文研究结果也表明,早奥陶世,兴安地块和松嫩地块之间存在洋壳,并且该洋壳向兴安地块俯冲。     

青海同仁县江里沟斑岩-矽卡岩型铜钨钼矿床辉钼矿Re-Os同位素年龄及其成矿意义

西秦岭同德—泽库多金属成矿带是青海省重要的矿产集中区之一,位于西秦岭北缘斑岩-矽卡岩型铜、钼、金成矿带的最西端。江里沟矿床是该区的重要组成部分,为一个典型的斑岩型-矽卡岩型铜钨钼矿床。本文利用Re-Os同位素定年方法对江里沟铜钨钼矿床进行了成矿时代测定,获得了5件样品辉钼矿的Re-Os同位素模式年龄范围为219.5±3.1~222.2±4.0Ma,等时线年龄为224.3±7.3Ma。矿区二长花岗岩SHRIMP锆石UPb年龄测定结果表明岩石存在两个期次结晶年龄232±4Ma和214±4Ma,矿区花岗岩可能是两个期次岩浆活动的产物。根据斑岩型矿床矿化晚于成矿母岩的特征,认为江里沟矿床成矿时代属晚三叠世,与矿区232Ma期次的岩浆侵入活动关系密切,成矿晚于成岩约8Ma,成矿与成岩时代基本一致,是西秦岭印支期构造-岩浆活动的产物。本次研究可以大致确定岗察复式岩体周边矿床成矿时限为243.8~214Ma,与区域西秦岭—东昆仑三叠纪构造岩浆作用和成矿时代一致,构成西秦岭北缘斑岩-矽卡岩型铜-钼-金成矿系统的一部分。