西藏冈底斯南缘中新世含矿斑岩源区组成与成因

青藏高原南部中新世下地壳流动是当前大陆动力学研究的热点,关键科学问题是下地壳的流动方向。LA-ICP-MS定年结果表明冲江斑状黑云母二长花岗岩的形成时代为14.9~14.8 Ma,朱诺斑状花岗岩的形成时代为15.3~14.9 Ma。含矿埃达克质斑岩的特征如下:Si O2含量67.72%~74.49%,K2O含量2.85%~5.98%,Sr含量93~804μg/g,高Sr/Y(16~139)、(La/Yb)N(21~43)比值,Eu/Eu*值为0.6~0.91。冲江岩体锆石εHf(t)值为1.2~5.1,朱诺岩体锆石εHf(t)值为–6.9~–0.1,他们与徐旺春等报道的镁铁质麻粒岩的锆石Hf值(–2.5~4.8)具有很好的叠合性,暗示镁铁质麻粒岩(印度镁铁质下地壳)可以作为他们的岩浆源区。此外,Sr-Nd同位素表现出雅鲁藏布江蛇绿岩和拉萨地块两个端元混合的特征,Pb同位素表现出雅鲁藏布江蛇绿岩和喜马拉雅富集陆壳端元的特征。上述同位素地球化学特征表明,冈底斯中新世埃达克质斑岩的岩浆源区物质组成包括:拉萨陆壳、印度陆壳、雅鲁藏布江蛇绿岩(地幔成分),表现出加厚下地壳部分熔融特征,暗示青藏高原南部由南向北的下地壳流动方向。     

Groundwater dating with 3H and SF6 in relation to mixing patterns,transport modelling and hydrochemistry

A comprehensive study of a sandy aquifer of deltaic origin in southern Poland included water chemistry, isotopes, dissolved trace gases and transport modelling. Tritium, sulphur hexafluoride (SF₆) and freons (F‐11, F‐12 and F‐113) showed the presence of modern waters in the recharge areas and shallow confined parts of the aquifer. The presence of older Holocene waters farther from the recharge areas was indicated by lack of ³H, SF₆ contents ≤0·02 fmol l⁻¹ and relatively low ¹⁴C values. The discharge from the system is by upward seepage in the valley of a major river. Pre‐Holocene waters of a cooler climate, identified on the basis of δ¹⁸O, δ²H, ¹⁴C, Ne and Ar data, were found in some distant wells. Concentrations of N₂, Ne and Ar determined by gas chromatography were used for calculating the noble gas temperatures, air excess needed for correction of SF₆, and nitrogen content released by denitrification process. The time series of ³H content available for some wells supplied quantitative information on age distributions and the total mean ages of flow through the unsaturated and saturated zones. The derived ³H age distributions turned out to be very wide, with mean values in the range of about 30 to 160 years. For each well with determined ³H age, the SF₆ data showed either a lower age range or the possibility of a lower age as expected due to shorter travel times of SF₆ through the unsaturated zone, which most probably also resulted in different types of age distributions of these tracers. Freons appeared to be of little use for individual age determinations. A quantitative estimation of two‐component mixing from SF₆ ³H relations is not possible unless the travel time of ³H through the unsaturated zone is comparable to that of SF₆. The ratio of integrals of the response function over the age range with tracer and the whole response function yields the ratio of water with tracer to total flow of water. That ratio is a tracer‐dependent function of time. Transport modelling of SF₆ tracer done with MT3D code yielded initially large discrepancies between calculated and measured tracer concentrations. Some discrepancies remained even after calibration of the transport model with SF₆. Simulation of tritium contents with a calibrated transport model yielded reasonable agreement with measured contents in some wells and indicated a need for further investigations, particularly in the eastern part of the aquifer. The existence of distinct hydrochemical zones is consistent with the tracer data; young waters with measurable ³H and SF₆ contents are aerobic and of HCO₃ Ca or HCO₃ SO₄ Ca types. Slightly elevated Na and Cl contents, as well as the highest concentrations of SO₄ and NO₃ within this zone are due to anthropogenic influences. Anaerobic conditions prevail in the far field, under the confining cover, where pre‐bomb era Holocene waters dominate. In that zone, dissolved oxygen, NO₃ and U contents are reduced, and Fe, Mn and NH₄ contents increase. In the third zone, early Holocene and glacial waters occur. They are of HCO₃ Ca Na or HCO₃ Na types, with TDS values higher than 1 g l⁻¹ and Na content higher than 200 mg l⁻¹, due to either small admixtures of ascending or diffusing older water or freshening of marine sediments, a process that is probably occurring till the present time. Copyright © 2005 John Wiley & Sons, Ltd.     

Petrology, geochronology, and tectonics of shear zones in the Zermatt–Saas and Combin zones of the Western Alps

Metre to tens‐of‐metre wide, steeply dipping, greenschist facies shear zones that cut blueschists and eclogites of the Combin and Zermatt–Saas Zones at Täschalp and in adjacent areas of the western Alps were sites of extensive recrystallization driven by fluid flow and deformation. Rb–Sr data imply that these shear zones formed at 42–37 Ma with a systematic younging of structures northward toward, and into, the hangingwall of the Mischabel Structure. Shearing commenced at 400–475 °C and 400–500 MPa and continued as pressures and temperatures fell to 300–350 °C and 300–350 MPa. Individual shear zones were active for 2–3 Myr with later lower grade stages of shearing concentrated into narrow zones. Fluids that infiltrated the shear zones were water rich (X_H2O > 0.9). Alteration zones around albite veins and at the margins of serpentinite bodies are penecontemporaneous with these shear zones and formed at approximately the same conditions. The eclogites were exhumed from c. 64 km at 44 Ma to 14–16 km at 42–41 Ma implying exhumation rates of 2–5 cm yr^?1. Rapid exhumation was probably achieved by extension aided by buoyancy, following subduction of continental crust, and rapid erosion. The shear zones form part of a regional‐scale extensional system responsible for a significant portion of the exhumation of the subducted oceanic crust.     

Trace element and Nd isotope analyses of apatite in granitoids and metamorphosed granitoids from the eastern Central Asian Orogenic Belt: Implications for petrogenesis and post-magmatic alteration

We present in situ trace element and Nd isotopic data of apatites from metamorphosed and metasomatized (i.e., altered) and unaltered granitoids in the Songnen and Jiamusi massifs in the eastern Central Asian Orogenic Belt, with the aim of fingerprinting granitoid petrogenesis, including both the magmatic and post-magmatic evolution processes. Apatites from altered granitoids (AG) and unaltered granitoids (UG) are characterized by distinct textures and geochemical compositions. Apatites from AG have irregular rim overgrowths and complex internal textures, along with low contents of rare earth elements (REEs), suggesting the re-precipitation of apatite during epidote crystallization and/or leaching of REEs from apatite by metasomatic fluids. ε_Nd(t) values of the these apatites are decoupled from zircon ε_Hf(t) values for most samples, which can be attributed to the higher mobility of Nd as compared to Sm in certain fluids. Apatites from UG are of igneous origin based on their homogeneous or concentric zoned textures and coupled Nd-Hf isotopic compositions. Trace element variations in igneous apatite are controlled primarily by the geochemical composition of the parental melt, fractional crystallization of other REE-bearing minerals, and changes in partition coefficients. Sr contents and Eu/Eu* values of apatites from UG correlate with whole-rock Sr and SiO₂ contents, highlighting the effects of plagioclase fractionation during magma evolution. Apatites from UG can be subdivided into four groups based on REE contents. Group 1 apatites have REE patterns similar to the host granitoids, but are slightly enriched in middle REEs, reflecting the influence of the parental melt composition and REE partitioning. Group 2 apatites exhibit strong light REE depletions, whereas Group 3 apatites are depleted in middle and heavy REEs, indicative of the crystallization of epidote-group minerals and hornblende before and/or during apatite crystallization, respectively. Group 4 apatites are depleted in heavy REEs, but enriched in Sr, which are features of adakites. Some unusual geochemical features of the apatites, including the REE patterns, Sr contents, Eu anomalies, and Nd isotopic compositions, indicate that inherited apatites are likely to retain the geochemical features of their parental magmas, and thus provide a record of small-scale crustal assimilation during magma evolution that is not evident from the whole-rock geochemistry.     

华北克拉通奥陶纪岩浆活动——来自河南安阳岭头地区白垩纪闪长岩中继承锆石U- Pb年龄的证据

通过高精度的LA-ICP-MS锆石U-Pb同位素测年,在太行山南段河南安阳县岭头一带白垩纪闪长质侵入岩中获得一批443.6±6.1 Ma(MSWD=6.3)的年龄数据,相当于晚奥陶世晚期,这是在华北克拉通内部发现的首例反映加里东期岩浆侵入活动的高精度锆石U-Pb定年数据,为揭示华北克拉通早古生代构造岩浆演化提供了依据。结合区域上同期构造岩浆事件的特点,认为443.6±6.1Ma的锆石可能为华北克拉通板内裂解拉张作用的产物,它是奥陶纪晚期(440 Ma前后)古劳亚大陆分裂,华北克拉通漂离加拿大地盾和北美内陆地台,同时形成北太平洋——这一影响全球的构造地质事件在华北克拉通内部的响应。鉴于稳定克拉通地区奥陶纪岩浆侵入活动与金刚石原生矿存在极高的关联度,本次发现也为在鹤壁地区寻找金刚石原生矿提供了重要参考。     

Determination of Early Paleozoic metamorphic event in the Longshan Complex and its geological implicationSCIEI北大核心CSCD

长期以来,陇山杂岩的归属问题一直存在争议。本文对出露于秦岭-祁连山结合部位的陇山杂岩中石榴黑云斜长片麻岩和石榴斜长角闪岩进行了详细的岩石学、P-T温压计算、独居石和榍石U-Pb年代学研究。通过详细的岩相学观察,石榴黑云斜长片麻岩的变质峰期矿物组合为石榴子石+黑云母+斜长石+石英;石榴斜长角闪岩中则识别出了以石榴子石+单斜辉石+角闪石+斜长石+石英为峰期的变质矿物组合。通过传统温压计计算,石榴黑云斜长片麻岩(样品21LS40)和石榴斜长角闪岩样品(样品21LS42-1)的峰期变质P-T条件分别为700℃、0.72GPa和710℃、0.74GPa。激光剥蚀电感耦合等离子体质谱(LA-ICP-MS) U-Pb数据表明,石榴黑云斜长片麻岩中独居石的206Pb/238U的加权平均年龄为407~435Ma。石榴斜长角闪岩中榍石的下交点年龄分别为410±7Ma、409±5Ma和426±10Ma,榍石中Zr含量温度计的计算结果分别为750℃、751℃和748℃(假定压力为0.7GPa)。本文从变质作用的角度出发,将陇山杂岩与秦岭杂岩进行温压条件和变质时代对比研究,认为陇山杂岩与东秦岭杂岩高压-超高压岩石的最后一期退变质作用和西秦岭天水地区的秦岭杂岩麻粒岩相变质作用类似,可能为北秦岭造山带的西延。     

河北金厂峪金矿床辉钼矿与金矿化关系研究及意义

辉钼矿Re-Os测年方法现已广泛应用于各类金属硫化物矿床成矿年代学研究领域, 已成为石英脉型金矿床实现直接、准确定年的重要手段。然而, 正确理解辉钼矿与金成矿作用之间的确切关系, 选取具有代表性的辉钼矿样品是测年的前提。本文聚焦冀东地区规模最大的金矿床——金厂峪金矿床, 对其石英-钠长石-多金属硫化物脉中的黄铁矿和辉钼矿两者的产出状态及原位微量元素特征进行了详尽的对比, 研究探讨了金厂峪金矿床中辉钼矿与金矿化之间的关系。研究发现石英-钠长石-多金属硫化物脉含金丰富, 可见金和不可见金均大量赋存, 黄铁矿和辉钼矿均为重要的载金硫化物。镜下矿相学及原位微量元素证据表明, 早期形成的含金黄铁矿经历了再活化过程, 为稍晚形成的富金辉钼矿提供了大量的Au源, 两者可能为同一大的金成矿事件下不同成矿流体脉冲事件的产物。辉钼矿形成于金厂峪金矿的主成矿阶段, 与Au的二次浓集紧密相关, 并可作为高品位金矿体的标志性矿物之一。本文认为在准确厘定辉钼矿与金矿化关系的基础上, 辉钼矿Re-Os方法是一种可靠的石英脉型金矿直接定年手段。     

塔里木盆地西南缘叶城地区新元古代冰期事件

新元古代冰期事件记录了“雪球地球”事件重要的地质信息。塔里木盆地周缘新元古代冰碛岩地层露头发育,是研究新元古代冰期事件的理想基地。由于发育多套新元古代火山岩,盆地东北缘库鲁克塔格地区新元古代冰碛岩地层时代已获得较多年代学数据约束;但盆地周缘其他地区新元古代冰碛岩地层公开报道年代学数据较少,不能准确限定其沉积时代,导致冰期事件对比存在争论。为此,本文选择塔里木盆地研究程度较低的西南缘叶城地区新元古代冰碛岩地层,开展岩石学、同位素年代学、岩石地球化学等研究,明确其冰期沉积特征,约束其沉积时代,开展冰期事件对比,讨论古气候风化条件等。南华系波龙组和雨塘组冰碛岩地层具有较低的化学蚀变指数(CIA),分别代表新元古代2次寒冷的冰川气候记录。冰川沉积及其相邻层位的碎屑锆石U-Pb年代学数据显示,波龙冰期的起始年龄晚于(710±13) Ma,与全球Sturtian冰期对应;雨塘冰期的起始年龄不会早于(656±18) Ma,其结束年龄可被南华系顶界年龄635 Ma或上覆震旦系库尔卡克组碎屑锆石年龄(634±9) Ma限定,与全球Marinoan冰期对应。     

广西柳东地区火山岩锆石U-Pb-Hf同位素特征及其对岩浆源区的限定

【研究目的】柳东地区位于右江盆地东缘,近年来该地区早三叠世石炮组中首次发现一套火山岩夹层,为研究盆地东缘的构造演化特征提供了重要依据。【研究方法】本文以新发现的柳东地区火山岩为研究对象,通过LAICP-MS锆石U-Pb年龄及Hf同位素分析,研究右江盆地东缘火山岩的形成时代及岩浆源区特征。【研究结果】结果表明,火山岩的岩性为凝灰岩-凝灰质熔岩-凝灰质火山角砾岩组合,指示了典型的火山岩特征。其2件凝灰岩样品中锆石LA-ICP-MS U-Pb加权平均年龄分别为（244.0±1.9） Ma和（247.1±0.9） Ma,锆石微量元素（U、Th、Hf、Nb）表现出大陆岩浆弧属性特征。锆石Hf同位素结果显示ε_Hf （t）为-13.2~-1.2,二阶段模式年龄（T_DM^C）为1.35~2.06 Ga,其岩浆源区主要为地壳物质,平均地壳存留年龄为1.7~2.06 Ga。【结论】该火山岩夹层与其所出露的地层时代基本相符,属于早三叠世末期—中三叠世早期火山喷发产物,火山岩形成于火山弧-同碰撞的构造环境,代表了弧后盆地的沉积环境,与印支期古特提斯洋的闭合相关。该成果为古特提斯构造域的演化研究提供了新的基础资料,具有重要意义。创新点：柳东地区火山岩属于早三叠世末期—中三叠世早期火山喷发产物,形成于印支期古特提斯洋的闭合条件下的火山弧-同碰撞构造环境。     

西天山卡特巴阿苏金矿床成矿年代学及其地质意义-来自绢云母~(40)Ar-~(39)Ar同位素年龄证据

新疆卡特巴阿苏金矿床是近年来在西天山地区新发现的一个大型金矿床。该矿床大地构造位置处于塔里木板块和哈萨克斯坦-准噶尔板块结合部位的那拉提构造-岩浆岩带,其金矿体主要赋存于蚀变二长花岗岩内。为了确定金矿化的形成时代,对该矿床主成矿阶段与金矿化密切相关的蚀变绢云母开展了40Ar-39Ar同位素定年测试。绢云母40Ar-39Ar坪年龄为(268.56±1.8)Ma,正等时线年龄为(268.38±2.2)Ma,反等时线年龄为(268.52±2.2 Ma),三者在误差范围内一致,测试结果可信,可代表卡特巴阿苏金矿化的形成年龄,这也是首次对该矿床成矿年龄的精确限定。对比中亚造山带典型金矿床,卡特巴阿苏金矿床是西天山二叠纪后碰撞构造环境下岩浆流体活动的产物,矿床成因属与中温岩浆热液有关的构造蚀变岩型矿床。