凡口铅锌矿床海底热泉喷溢成矿的物理化学环境

凡口铅锌矿是发育于碳酸盐岩建造中的海底喷溢沉积矿床 ,以“一大二富三集中”的特点和典型的地质地球化学特征吸引着中外矿床地质工作者。叠层状矿体发育于同沉积断裂的旁侧 ,矿层与灰岩呈沉积接触关系。矿石具沉积碎屑组构 ,黄铁矿、闪锌矿具外生特征。稀土元素组成和硫同位素组成反映矿床与同生作用有关。铅同位素组成具有壳源和下地壳来源铅的特征。矿区主要矿层经历海底热泉喷溢沉积—成岩的演化     

中国太古宙

根据最近10多年来中国太古宙岩石同位素地质年代学新数据和中国太古宙岩石三个主要分布地区冀东、辽东和吉林南部、太行山-五台山的时间-地层图及其对比情况,认为尚无足够的证据支持中国太古宙四分,三分方案更适合于中国太古宙的情况：约2．9Ga可以作为晚、中太古代的界线,而3.5Ga作为中、早太古代界线尚不很明晰。     

Silicon Isotope Geochemistry of Micro—Fine Disseminated Gold Deposits in SW Guizhou and NW Guangxi,China

Quartz was studied with respect to its silicon isotopic composition and cathodoluminescence in micro-fine disseminated gold deposits in SW Guizhou and NW Guangxi.The results showed that quartz in wall rocks.ores and that in association with hydrothermal silicification are distinctive in silicon isotopes and cathodoluminescence characters.Quartz in association with primary silicification is non-luminescent while that in wall rocks and associated with secondary silicification exhibits striking luminescence.Based on the dynamic fractionation of silicon isotopes,it is suggested that the mineralization was accompanied by rapid transport of aprimary siliceous fluid along the major deep fault system into subordinate faults before ore components deposited in favorable strata via penetration and metasomatism.Therefore,a deep origin is implicit for gold deposits of this type.     

Post-collision neogene volcanism of the Eastern Rif (Morocco): magmatic evolution through time

Neogene volcanism in the Eastern Rif (Morocco) comprises a series of calc-alkaline, potassic calc-alkaline, shoshonitic and alkaline volcanic rocks. According to new stratigraphical, along with new and previous chronological and geochemical data, the orogenic volcanism was successively (1) calc-alkaline (basaltic andesites and andesites: 13.1 to 12.5 Ma, rhyolites: 9.8 Ma), (2) K-calc-alkaline (basaltic andesitic to rhyolitic lavas and granodiorites: 9.0 to 6.6 Ma), and (3) shoshonitic (absarokites, shoshonites, latites, trachytes: 7.0 to 5.4 Ma). The later Pliocene volcanism was basaltic and alkaline (5.6 to 1.5 Ma). The calc-alkaline and K-calc-alkaline series exhibit lower K₂O (0.7–5.3 wt.%), Nb (8–19 ppm) contents and higher ⁸⁷Sr/⁸⁶Sr (0.70773–0.71016) than the shoshonitic series (K₂O: 2.4–7.2 wt.%, Nb: 21–38 ppm, ⁸⁷Sr/⁸⁶Sr: 0.70404–0.70778). Pliocene alkaline basalts have a sodic tendency (Na₂O/K₂O: 1.7–3.5), high Nb content (up to 52 ppm), and low ⁸⁷Sr/⁸⁶Sr ratio (0.70360–0.70413). The variations through time of K₂O, Nb and Sr isotopic ratio reflect different mantle sources: (i) calc-alkaline, potassic calc-alkaline and shoshonitic series are derived from a mantle source modified by older subduction, (ii) alkaline basalts are derived mainly from an enriched mantle source. Through time, incompatible elements such as Nb increased while ⁸⁷Sr/⁸⁶Sr decreased, suggesting a decreasing influence of metasomatized mantle (inherited subduction). Such evolution is related to the post-collision regimes operating in this area, and could be linked to the succession of extensional, compressional and strike-slip fault tectonics.     

川西孔玉——会理金矿带同位素特征与金矿分布

金矿带内不同金矿床氢氧和硫同位素组成,清楚地反映出各金矿产出地质背景的差异,显示出金矿与赋矿围岩有成因联系;δ＾１８Ｏ石英和δ＾１８Ｏ水的变化趋势,反映出金矿空间分布规律及其成矿系列演化。     

Age of Saurashtra miliolites by U-Th decay series methods: possible implications to their origin

The miliolite deposits of Saurashtra have been dated by²³⁴U,²³⁰Th,²³¹Pa and¹⁴C methods. Concordant ages of 10⁵ years using the U decay series isotopes are obtained which agree with the ages of the coral reefs of Okha-Dwaraka coast suggesting a contemporaneous origin for both. The lower¹⁴C ages (≤40,000 years) may be due to a recent influx of seawater or ground water. Quartz and clay minerals together constitute only ≤10% by weight, as such the aeolian characteristics of quartz grains may not be relevant to the origin of the miliolites.     

Carbon isotopic fractionation by desorption of shale gases

Geochemical studies of shale gas and conventional reservoirs within the Triassic Yanchang Formation of Xiasiwan and Yongning Field, Ordos Basin show that methane is isotopically depleted in ¹³C as compared to δ¹³C₁ calculated by the Ro based on the relationship between δ¹³C₁ and Ro. Geochemical fractionation during the adsorption/desorption process of shale system may play a significant part in influencing δ¹³C₁ values of shale gas. Two shale core samples from confined coring of the Yanchang Formation were adopted segmented desorption experiments to examine this phenomenon. The results show that the δ¹³C₁ of desorbed gas changes little in the first few phases of the experiments at low desorption levels, but become less negative rapidly when the fraction of desorbed methane exceeds 85%. The desorption process for the last 15% fraction of the methane from the shale samples shows a wide variation in δ¹³C₁ from −49‰ to −33.9‰. Moreover, δ¹³C₁ of all desorbed methane from the shale samples is substantially depleted in ¹³C than that calculated by Ro, according to Stahl and Carey's δ¹³C₁–Ro equation for natural gas generated from sapropelic organic matter. This shows some gases with isotopically enriched in ¹³C cannot be desorbed under the temperature and pressure conditions of the desorption experiments. This observation may be the real reason for the δ¹³C₁ of shale gases and conventional reservoirs becomes more negative in Xiasiwan and Yongning Fields, Ordos Basin. The magnitude of the deviation between the δ¹³C₁ of shale gas and that calculated by Ro may be related to the adsorption capacity of shale or the proportion of absorbed gases. In this way, we may be able to evaluate the relative adsorption capacity of shale in geological conditions by δ¹³C₁ of the shale gas, or by δ¹³C₁ of conventional gas which generated by the shale with certainty. The δ¹³C₁ of conventional gas in Dingbian and Yingwang Fields have no deviation because the TOC value of the hydrocarbon source rock is relatively low.     

巴尔喀什成矿带Cu-Mo-W矿床的辉钼矿Re-Os同位素年龄测定及其地质意义

巴尔喀什成矿带是世界著名的中亚成矿域斑岩型铜钼成矿带,产出许多斑岩型铜钼矿床和一些石英脉-云英岩型钨钼矿床。中亚成矿域可能是一个多核成矿系统,具有以走滑断裂为边界构成的断裂构造体系并受之控制。本文对巴尔喀什成矿带巴尔喀什—阿克沙套地区11件辉钼矿样品进行了Re-Os同位素分析,得到博尔雷大型斑岩型铜(钼)矿床和东科翁腊德、扎涅特、阿克沙套石英脉-云英岩型钨钼矿床的辉钼矿模式年龄(平均值)分别为315.9Ma、298.0Ma、295.0Ma和289.3Ma;其中,东科温腊德、阿克沙套和扎涅特等3个矿床的Re-Os等时线年龄为297.9-+30..949Ma,MSWD值为0.97。辉钼矿Re-Os年龄说明巴尔喀什成矿带Cu-Mo-W成矿作用发生在315.9～289.3Ma期间,Cu-Mo-W矿床的形成可分为两期:一期为斑岩型铜钼矿床,约形成于315.9Ma;另一期为石英脉-云英岩型钨钼矿床,约形成于297.9Ma。根据辉钼矿模式年龄和等时线年龄,推测该地区花岗斑岩和伟晶岩的形成时代与相应的矿床基本同时,均为晚石炭世,属海西期构造岩浆活动的产物。通过与我国境内西、东准噶尔和东天山斑岩铜矿带的对比表明,巴尔喀什成矿带铜钼成矿作用的年龄介于东天山土屋—延东斑岩铜矿与西准噶尔包古图斑岩铜矿之间。分析表明,中亚成矿域大规模斑岩型铜钼成矿作用集中在晚石炭世,属海西晚期构造-岩浆活动的产物。     

山东土堆－沙旺金矿床同位素组成特征及矿床成因讨论

土堆－沙旺金矿床位于胶莱盆地东北缘, 为胶东东部牟平－即墨成矿带的重要组成部分。石英流体包裹体Rb－Sr等时线年龄为119±10 Ma,与胶东大规模成矿时间一致。矿石硫化物硫同位素组成δ34S介于8.50‰～12.72‰之间, 成矿热液δ34S∑S=10.03‰, 铅同位素组成中206Pb/204Pb＝17.12～17.86, 且具有低μ高ω特征, 指示成矿物质来源于下地壳或地幔。氢氧同位素δ18OH2O值为+1.96‰～＋7.71‰, δD为–68.64‰～–86.47‰, 显示成矿流体主体为岩浆水, 并有部分后期大气水的参与。矿石铅同位素与同期脉岩组成接近, 且具有线性特点, 指示二者可能与早白垩世华北克拉通东部构造体制转化所引起的壳幔岩浆混合作用有关。     

Moraine chronosequence of the Donnelly Dome region, Alaska

We present ¹⁰Be exposure ages from moraines in the Delta River Valley, a reference locality for Pleistocene glaciation in the northern Alaska Range. The ages are from material deposited during the Delta and Donnelly glaciations, which have been correlated with MIS 6 and 2, respectively. ¹⁰Be chronology indicates that at least part of the Delta moraine stabilized during MIS 4/3, and that the Donnelly moraine stabilized ∼ 17 ka. These ages correlate with other dates from the Alaska Range and other regions in Alaska, suggesting synchronicity across Beringia during pulses of late Pleistocene glaciation. Several sample types were collected: boulders, single clasts, and gravel samples (amalgamated small clasts) from around boulders as well as from surfaces devoid of boulders. Comparing ¹⁰Be ages of these sample types reveals the influence of pre/post-depositional processes, including boulder erosion, boulder exhumation, and moraine surface lowering. These processes occur continuously but seem to accelerate during and immediately after successive glacial episodes. The result is a multi-peak age distribution indicating that once a moraine persists through subsequent glaciations the chronological significance of cosmogenic ages derived from samples collected on that moraine diminishes significantly. The absence of Holocene ages implies relatively minor exhumation and/or weathering since 12 ka.