大洋多金属结核同位素地球化学研究

本文对DY85-1航次采自东太平洋海盆“CC”区不同地貌区、不同类型的大洋多金属结核进行了O、C、H、Si等同位素综合研究。结果表明,O同位素变化能反映结核的生成环境、生长速率、物质来源及成矿机理;Si同位素组成特征能帮助推测结核核心物质的来源;C同位素的研究表明,多金属结核成矿作用是在古海洋水变冷的总趋势下进行的;δ13C、δ18O和δD的规律变化,反映了海洋水变冷的周期性和渐变性。     

高压超高压变泥质岩适用的地质温压计评述

高压超高压变泥质岩形成温压条件及p-T演化轨迹是高压超高压变质作用研究的重要内容。本文介绍了高压超高压变泥质岩适用的几种地质温压计,包括石榴子石-多硅白云母Fe~(2+)-Mg交换温度计、石榴子石-绿泥石Fe~(2+)-Mg交换温度计、硬绿泥石-绿泥石Fe~(2+)-Mg交换温度计、多硅白云母Si含量压力计、金红石Zr含量温度计、榍石Zr含量温压计、锆石Ti含量温度计、石英Ti含量温度计以及氧同位素温度计,并对上述温压计的适用条件及使用时的注意事项做了简要评述。     

样品前处理过程中多环芳烃的稳定碳同位素分馏

利用多环芳烃标准样品连续和穿插进样相结合的方式,检验了气相色谱-燃烧-同位素比质谱仪(GC-C-IRMS)测定多环芳烃单体碳同位素比值(δ13C)的稳定性和准确性,观察了测定过程中色谱柱的分离效果。结果表明,出峰面积和分离程度是影响化合物δ13C平行性的主要原因。通过多次实验,分析了样品前处理过程中多环芳烃各个化合物稳定碳同位素的分馏情况,包括凝胶渗透色谱(GPC)和硅胶柱等净化过程,以及旋转蒸发和氮气吹扫等浓缩过程。实验表明,各前处理过程中样品内多环芳烃的稳定碳同位素分馏均不明显,其中硅胶柱净化过程相比GPC过程对样品中多环芳烃的δ13C影响较大,但总体上仍未超过未处理标样δ13C值的2倍标准偏差范围。旋转蒸发和氮吹过程对样品中多环芳烃的δ13C影响程度相当,都位于未处理标样δ13C值1倍标准偏差以内的水平。     

海进体系域碳氧同位素地球化学响应——以黔西南地区三叠系为例

层序地层研究表明,位于扬子地块西南缘的黔西南地区在中三叠世末期(相当于Ladinian-Carnian期)出现了一次与全球同步的大规模海侵,形成了一个向上变深的碳酸盐岩台地淹没沉积层序。垄头组顶部和竹竿坡组分别是海进体系域(TST)的下、上部分。碳、氧同位素研究表明,垄头组顶部自下而上δ(18O)持续增大,而δ(13C)先逐渐增大,后在顶部界面附近快速下降,反映了垄头组顶部在暴露环境下氧化作用的结果。竹竿坡组δ(13C)自下而上逐渐增大,δ(18O)总体呈现逐渐减小趋势,反映了海平面变化特征。研究认为,海进体系域的δ(13C)和δ(18O)演化不但反映了海平面和沉积环境变化,同时对密集段(CS)、层序界面和古暴露面等也有很好的识别作用,在层序地层研究中具有重要的意义。     

Organic geochemistry of marine source rocks and pyrobitumen-containing reservoir rocks of the Sichuan Basin and neighbouring areas,SW China

Three bitumen fractions were obtained and systematically analysed for the terpane and sterane composition from 30 Paleozoic source rocks and 64 bitumen-containing reservoir rocks within the Upper Sinian, Lower Cambrian, Lower Silurian, Middle Carboniferous, Upper Permian and Lower Triassic strata in the Sichuan Basin and neighbouring areas, China. These bitumen fractions include extractable oils (bitumen I), oil-bearing fluid inclusions and/or closely associated components with the kerogen or pyrobitumen/mineral matrix, released during kerogen or pyrobitumen isolation and demineralization (bitumen II), and bound compounds within the kerogen or pyrobitumen released by confined pyrolysis (bitumen III). In addition, atomic H/C and O/C ratios and carbon isotopic compositions of kerogen and pyrobitumen from some of the samples were measured. Geochemical results and geological information suggest that: (1) in the Central Sichuan Basin, hydrocarbon gases in reservoirs within the fourth section of the Upper Sinian Dengying Formation were derived from both the Lower Cambrian and Upper Sinian source rocks; and (2) in the Eastern Sichuan Basin, hydrocarbon gases in Middle Carboniferous Huanglong Formation reservoirs were mainly derived from Lower Silurian source rocks, while those in Upper Permian and Lower Triassic reservoirs were mainly derived from both Upper Permian and Lower Silurian marine source rocks. For both the source and reservoir rocks, bitumen III fractions generally show relatively lower maturity near the peak oil generation stage, while the other two bitumen fractions show very high maturities based on terpane and sterane distributions. Tricyclic terpanes evolved from the distribution pattern C₂₀ < C₂₁ < C₂₃, through C₂₀ < C₂₁ > C₂₃, finally to C₂₀ > C₂₁ > C₂₃ during severe thermal stress. The concentration of C₃₀ diahopane in bitumen III (the bound components released from confined pyrolysis) is substantially lower than in the other two bitumen fractions for four terrigenous Upper Permian source rocks, demonstrating that this compound originated from free hopanoid precursors, rather than hopanoids bound to the kerogen.     

无人水下智能海洋测绘装备的机遇与挑战

针对海洋测绘面临的问题,分析了无人时代海洋测绘技术的发展机遇,提出了无人水下智能海洋测绘的新模式,讨论了无人水下智能海洋测绘的技术体系和无人水下智能海洋测绘装备的关键技术,以及无人水下智能海洋测绘的装备产业链,展望了无人水下智能海洋测绘装备的发展趋势及应用前景。     

华北地块南缘花山、五丈山岩体LA-ICP-MS锆石U-Pb年龄、地球化学特征及成因

花山复式岩体位于华北地块南缘,采用LA-ICP-MS技术测得复式岩体中的中细粒似斑状黑云二长花岗岩的锆石U-Pb年龄为128±1Ma,此年龄被解释为成岩年龄。该岩体及邻近的五丈山岩体中花岗岩具有高硅、富碱特征,为准铝-弱过铝质高钾钙碱性系列;在稀土和微量元素上,富集LREE、Rb、Ba、K、Sr等大离子亲石元素,亏损HREE、Zr、Hf、Ta、Nb、P、Ti等高场强元素,总体上Eu异常不明显,显示出I-A过渡型花岗岩的特征。锆石Lu-Hf同位素组成表明,花山花岗岩的ε_Hf(t)主要变化于-25.8~-19.6之间,t_DM2为2.81~2.43Ga,显示源区物质以古老的壳源物质为主,有年轻组分的参与。与岩体外围多金属成矿年龄的对比分析发现,外围金、钼矿床与花山复式岩体的年龄一致,比五丈山岩体晚20~25Ma,表明金、钼矿的形成与花山岩体在时空上联系密切,该岩体可能为成矿提供了热源。     

Molybdenum Mass Fractions and Isotopic Compositions of International Geological Reference Materials

The double‐spike method with multi‐collector inductively coupled plasma‐mass spectrometry was used to measure the Mo mass fractions and isotopic compositions of a set of geological reference materials including the mineral molybdenite, seawater, coral, as well as igneous and sedimentary rocks. The long‐term reproducibility of the Mo isotopic measurements, based on two‐year analyses of NIST SRM 3134 reference solutions and seawater samples, was ≤ 0.07‰ (two standard deviations, 2s, n = 167) for δ^98/95Mo. Accuracy was evaluated by analyses of Atlantic seawater, which yielded a mean δ^98/95Mo of 2.03 ± 0.06‰ (2s, n = 30, relative to NIST SRM 3134 = 0‰) and mass fraction of 0.0104 ± 0.0006 μg g^?1 (2s, n = 30), which is indistinguishable from seawater samples taken world‐wide and measured in other laboratories. The comprehensive data set presented in this study serves as a reference for quality assurance and interlaboratory comparison of high‐precision Mo mass fractions and isotopic compositions.     

浮游有孔虫个体大小对硼同位素分析的影响

对比分析了太平洋(Site 806)、大西洋(Site 664)和加勒比海地区(Site 999)末次冰期最盛期和全新世钻孔顶部不同尺寸大小的浮游有孔虫Globigerinoides sacculifer(500～600μm和300～355μm)和Globi-gerinoides ruber(300～355μm和250～300μm)的硼同位素组分变化,发现个体相对较小的有孔虫样品由于受到样品量以及样品前处理过程的影响,其硼同位素在末次冰期最盛期出现异常,浮游有孔虫硼同位素分析,尤其是冰期-间冰期时间尺度上的硼同位素分析,适合用个体相对较大的有孔虫。末次冰期最盛期太平洋和加勒比海地区溶解作用可能加强,其G.sacculifer的硼同位素偏低,但G.ruber的硼同位素不受溶解作用的影响,能够反映末次冰期海水pH值的变化。三个钻孔末次冰期最盛期G.ruber的硼同位素比全新世的硼同位素平均高(1.3±1.2)‰(2s.e.),与理论预测值1.6‰一致。     

基于同位素与水化学分析法的地下水补径排研究——以苏锡常地区浅层地下水为例

在分析研究区浅层地下水空间分布特征的基础上,采用同位素与化学分析相结合的方法研究苏锡常浅层地下水的补径排条件。利用氢氧同位素的分析结果,建立潜水与微承压水的δD-δ18O关系曲线,分析潜水含水层与河流、湖泊等地表水体关系以及微承水的蒸发程度;利用放射性同位素氚与14C研究微承水与现代水的补给关系;利用常规的水化学分析方法研究浅层地下水补给源的变化问题。结合研究区地下水水位、地层岩性、地形、地貌等多方面因素综合分析了浅层地下水的补径排条件,从而指导苏锡常地区浅层地下水合理开发利用。