1,2-二氯乙烷和1,2-二氯丙烷在某污染场地包气带的吸附-解吸特性

1,2-二氯乙烷(1,2-DCA)和1,2-二氯丙烷(1,2-DCP)是某污染场地地下水中检出最高的挥发性有机污染物。文中采用批试验方法,研究污染场地包气带中三种不同深度土壤样品对1,2-DCA和1,2-DCP的吸附-解吸特性。结果表明:土壤中有机质决定其吸附行为,三种土壤对1,2-DCA和1,2-DCP的吸附符合Henry线性等温方程,分配系数在20.49～22.43L.kg-1,1,2-DCA和1,2-DCP在三种土壤中分别具有相似的吸附能力;同一土壤中两种目标污染物的吸附能力为Kd(1,2-DCA)>Kd(1,2-DCP),但差别不大。1,2-DCA和1,2-DCP在三种土壤中的解吸可用Freundlich等温方程拟合,解吸的难易程度与土壤中黏粒含量相关,黏粒含量越高,目标污染物的解吸越困难,第三层(地下4.9～5.1m)土壤的防污能力较强;两种污染物在三种土壤中的解吸都存在明显的滞后效应,1,2-DCP的滞后指数比1,2-DCA的大。     

基于混合物理论的水力-化学-力学污染物输运模型研究

由于废弃物的堆积以及填埋场上覆盖层的重量,衬垫因此承受一定的压力,发生力学固结;由于黏土本身的结构特性,当污染物通过黏土垫层时可能会发生化学固结,而固结作用可直接对污染物的对流输运产生影响,也会引起土层体积和结构的变化,从而改变其固有的输运性质。从混合物理论出发,建立了水力-化学-力学作用下的溶质输运理论框架,统一地描述了水力-化学-力学作用下变形、水的吸附或解吸附、对流和扩散现象。将输运系数考虑为有效孔隙率的函数,由此反映固结对输运参数的影响。对所建立的数学模型进行无量纲化处理,并使用有限元软件COMSOL Multiphysics进行求解,最后进行了参数分析。研究结果表明,垫层土体中吸附水和自由水之间的化学势差异越大,层间吸附水的解吸附量越大;当土体的软硬性质不同时,当层间吸附水解吸附后,土体固结程度不同,从而对污染物输运过程的影响不同。而当垫层上覆荷载增大时,土体宏观孔隙的扩张的限制作用增强,从而对土体产生一种修复作用,抑制污染物在土体中的输运。     

低解吸气量页岩气组分校正方法探讨

通过现场解吸试验,采用气相色谱等测试方法,对低解吸气量页岩气组分测定结果校正方法进行了研究。在常规现场解吸试验操作基础上增加校正实验,结合理想气体状态方程,总结归纳出校正参数及适用性研究。结果显示,当解析气量较少时,解吸罐内残留空气对组分测定结果的影响较大,排除解吸罐中空气的影响后,解吸气组分甲烷体积分数普遍增加12.23%~54.44%。研究表明,对低解吸气量页岩气组分结果进行校正十分必要。     

开采扰动下考虑损伤破裂的深部煤体渗透率模型研究

为了研究深部煤体在开采扰动影响下的渗透率演化规律,以三向应力条件下的煤体渗透率模型为基础,从吸附解吸作用引起裂隙变形和损伤破裂造成煤基质弹性模量劣化的角度进行理论推导,引入内膨胀应变系数的概念,同时基于Drucker-Prager破坏准则的损伤本构关系建立了两种考虑煤体损伤破裂的渗透率演化模型——指数型和立方型,并且对常规三轴加载、开采扰动加卸载和改变气体压力下的瓦斯渗透试验结果进行了拟合分析。结果表明：所构建的两种模型可以较好地反映常规三轴加载和开采扰动加卸载下煤体渗透率的分区段变化特征,也可以描述有效围压恒定条件下煤体渗透率随气体压力升高而降低的规律。在开采扰动加卸载和改变气体压力的试验中,指数型的拟合效果略优于立方型。研究结果可为深部煤炭开采及瓦斯抽采的工作提供指导。     

Sensitive and rapid detection of two toxic microalgae Alexandrium by loop-mediated isothermal amplification

A loop-mediated isothermal amplification (LAMP) assay was designed and evaluated for rapid detection of the toxic microalgae Alexandrium catenella and A.minutum,which can produce paralytic shellfish poisoning (PSP).Two sets of four specific primers targeting these two species were derived from the sequence of internal transcribed spacer (ITS) of ribosomal DNA.The method worked well in less than an hour under isothermal conditions of 65 C.LAMP specificity was validated in closely related algae as a comparison,suggesting the strict specificity of the LAMP primers.Two visual inspection approaches were feasible to interpret the positive or negative results.The detection limits of A.catenella and A.minutum samples using the LAMP assay were found to be 5.6 and 4.5 pg DNA,respectively.The sensitivity of this LAMP assay was 10 or 100-fold higher than Polymerase Chain Reaction (PCR) method in detecting the two microalgae.These characteristics of species specificity,sensitivity,and rapidity suggest that this method has the potentiality in the monitoring of red tide caused by A.catenella and A.minutum.     

油基钻屑现场热解析处理技术现状及展望

深部石油勘探和页岩气、致密气等非常规油气开发过程中会产生大量的油基钻屑,热解析技术被认为是最有效的油基钻屑环保处理技术,也是实现油基钻屑废弃物资源化利用的有效途径。本文重点介绍油基钻屑现场热解析处理典型的先进技术、装置与应用情况;针对油基钻屑成分和组分性质复杂多变、热解化学反应过程复杂,热解析设备能耗高、热解温度不确定、进料物性不稳定、不均匀性等问题,建议开展油基钻屑复杂体系在移动床中动态连续热解的动力学及机理分析,建立动力学模型,明确不同组分油基钻屑的最优热解析工艺参数;建立技术经济效益、环境效益及可持续发展等评价体系和准则,为不同体系油基钻屑的高效低耗安全环保热解析现场随钻处理提供科学可靠依据和理论支撑。     

煤层气含量快速测定方法

煤和煤层气地质勘探需要在取到钻孔煤心后的很短时间内获得气含量测值,而现行的煤层气含量测定方法难以满足此要求。基于自然解吸法原理和方法,以自然解吸法的测定结果为基准,在保证解吸量、气组成及其含量基本不变的前提下,通过连续观测、适当提高解吸温度等途径,合理、有效地加速解吸。以快速测定法与自然解吸法的对比试验结果为依据,建立了煤层气含量快速测定方法。此方法将煤层气含量测定周期缩短为几h~几d,可以满足煤和煤层气勘探的需求。      

页岩气等温解吸特性研究

页岩气以吸附态、游离态和溶解态存在于页岩储层中,其中吸附态为主要赋存状态,考察页岩气解吸特征对于我国页岩气勘探开发研究有着重要的理论指导意义。选取了位于南方海相页岩储区的四川和湖北荆门等地的页岩样品,对其常规地球化学性质进行了分析,结果表明页岩样品有机碳含量较高且发育较为成熟;采用MSB磁悬浮天平等温吸附仪进行等温解吸实验并对解吸速率和解吸效率进行计算,结果表明：30~10 MPa时页岩解吸量很低并且无明显变化;10~05 MPa时页岩解吸量迅速上升,该阶段为主要解吸段;吸附势理论可用于判断页岩气解吸情况和页岩样品解吸性能强弱,吸附势越大越不利于解吸     

A theoretical and experimental comparison of the anisotropies of magnetic susceptibility and remanence in rocks and minerals

Summary. Susceptibility, thermo-remanent magnetization (TRM) and isothermal remanent magnetization (IRM) anisotropy ellipsoids have been determined for several rock samples. The results indicate that the ellipsoid of initial susceptibility is less anisotropic than the TRM and low field IRM ellipsoids which are found experimentally to be of identical shape. This suggests that palaeomagnetic data for anisotropic rocks may be corrected by using the anisotropy ellipsoid determined from magnetically non-destructive low field IRM measurements. Such IRM measurements can also be used to obtain anisotropy axes of samples which are inherently anisotropic but which have a susceptibility which is too weak to be accurately measured. The results for a series of artificial anisotropic samples containing magnetite particles of different sizes (in the range 0.2–90 μm) were very similar to those for the rocks. In contrast, a comparison of the susceptibility and IRM ellipsoids for anisotropic samples containing particles from a magnetic tape gave very different results in accordance with theory. Such results imply that susceptibility and IRM ellipsoids could be used to determine whether anisotropic rocks contain uniaxial single-domain particles (magnetization confined to the easy axis) or whether the particles are essentially multidomain.