光照强度对隐藻吸收铁和磷的影响

在模拟条件下,通过深入研究光照强度对隐藻生长率的影响,以及不同光照强度下藻细胞对Fe和P的吸收差异,提出了光照强度控制藻细胞对营养元素的吸收,最终限制赤潮藻爆发性增殖的作用途径.研究表明,藻细胞的生长率与光照强度之间呈指数相关关系;隐藻生长的光饱和值与光半饱和值分别为150 μmol/(m2·s)和47 μmol/(m2·s);在低光照强度下藻细胞的生长率较低,但是藻细胞却需要吸收更多的Fe和P,以及Zn、Mn、Co和Mo等微量元素,在光照强度为10 μmol/(m2·s)时,藻细胞生长率仅为光照强度150 μmol/(m2·s)时的十分之一,而藻细胞对Fe和P的吸收量分别提高了1.5倍和1倍.这些研究结果为揭示导致赤潮常在光照良好天气后发生的根本原因提供了全新的认识.     

The importance of iron speciation (Fe+2/Fe+3) in determining mineral assemblages: an example from the high‐grade aluminous metapelites of southeastern Madagascar

Metapelitic granulites from the Anosyen domain of southeastern Madagascar are exposed in three intercalated formations: the Amparihy, Bakika and Ihosy formations. Although mineralogically distinct from each other, the rocks from these formations show very similar bulk‐rock compositions when measured on a Fe_T basis. The preserved mineral assemblages thus do not reflect differences in the ratios of the main rock‐forming oxides (i.e. Al₂O₃:Fe_T:MgO), but instead reflect variations in the pre‐metamorphic oxidation state of the protolith rocks. These differences in oxidation state are manifested via differences in iron speciation – either Fe⁺² or Fe⁺³. The relatively reduced rocks of the Amparihy Formation preserve the assemblage bi–sp–sill–g–cd, which contrasts markedly with the mostly garnet and spinel‐absent bi–cd–sill–mt assemblages preserved in the strongly oxidized rocks of the Ihosy Formation. Compositionally intermediate rocks of the Bakika Formation are garnet bearing, but sillimanite‐absent, and contain the assemblage sp–g–cd–mag. Modelling of these rocks in the Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O–TiO₂–O system suggests that they evolved along a heating and cooling P–T path with only limited decompression accompanying cooling on the retrograde path. Peak temperatures and pressures of ～880–920 °C and 6–6.5 kbar are inferred for the majority of the Anosyen domain, with slightly lower peak temperatures (～840 °C) estimated in the extreme northwest of the area. The high‐temperature and relatively low‐pressure nature of metamorphism suggests high geothermal gradients existed during orogenesis, which in southern Madagascar is related to the amalgamation of Gondwana (580–520 Ma). Although metamorphic temperatures may have been augmented via thermal advection from the emplacement of the syn‐ to post‐tectonic Ambalavao suite, the high geothermal gradients nevertheless suggest thin and consequently hot lithosphere existed prior to orogenesis.     

Sunrise Hill unconformity: A newly discovered regional hiatus between Archaean granites and greenstones in the northeastern Pilbara Craton

Contacts between Archaean granites and greenstones in the northeastern part of the Pilbara Craton have been described as intrusive and tectonic. New field observations in the Shay Gap region demonstrate that greenstones of the Gorge Creek Group unconformably overlie the Muccan and Warrawagine batholiths. Regionally, the unconformity is marked by a persistent but relatively thin basal clastic sequence, locally with a granite boulder conglomerate, overlain by ore‐bearing banded iron‐formation, fine‐grained clastic rocks and chert. The granite basement is dated at 3443 ± 6 Ma. The precise age of the hiatus is unknown but its maximum effect might have been the removal of a substantial thickness of Early to Middle Archaean strata.     

Iron porphyrins in the Permian Kupferschiefer of the lower Rhine Basin, N.W. Germany

Immature samples of the Permian Kupferschiefer from the Lower Rhine Basin in N.W. Germany were analysed for tetrapyrrole pigment type and abundance. The sediment, thought to have been deposited in a marine regime with enhanced salinity, was found to contain high concentrations of metalloporphyrins. The porphyrins are complexed to nickel (Ni) and oxovanadium (V=0), but high abundances of iron (Fe) porphyrins were also detected using UV/visible spectroscopy and mass spectrometry. The presence in the latter of series of aetioporphyrins, cycloalkanoporphyrins, di-cycloalkanoporphyrins and benz-cycloalkanoporphyrins was confirmed by accurate mass measurements; HPLC co-injection of deoxophylloerythroetioporphyrin (C₃₂ DPEP) with the demetallated iron porphyrins indicated its presence in the sediment as an iron complex. The study provides the first evidence for the occurrence of Fe porphyrins in geological samples other than coals and lignites, and reports the highest concentrations in sedimentary organic matter to date.     

游离氧化铁形态转化对红粘土工程性质的影响

本文通过模拟环境中的有机质使游离氧化铁形态转化对典型红粘土工程性质的影响试验,系统地测试了游离氧化铁的形态分布与物性指标的关系。试验结果表明,在渍水条件下,游离氧化铁的形态转化对红粘土性质的影响不显著,但在渗水条件下,由于游离氧化铁的流失使得胶结作用减弱,它对红粘土工程性质的影响逐渐明显,其潜在的危害仍然是不容忽视的。     

微波等离子体炬原子发射光谱法测定铁和铝的研究

研究了低功率微波等离子体炬原子发射光谱法（ＭＰＴ－ＡＥＳ）对Ｆｅ，Ａｌ的测定。样品经气动雾化后，分别以流动注射与连续式两种方式引入ＭＰＴ。考察了用这两种进样方式时ＭＰＴ－ＡＥＳ的分析性能，证明低功率ＭＰＴ－ＡＥＳ具有良好的分析特性。     

辉碲铋矿单矿物的化学分析

辉碲铋矿物经ＨＮＯ３－ＫＣｌＯ３溶解，用火焰原子吸收法或乙二胺四乙酸二钠事滴定法测定Ｂｉ，火焰原子吸收法测定Ｔｅ、Ｆｅ、Ｃｕ，３，３＇－二氨基联苯胺光度法测定Ｓｅ，硫酸重量法测定Ｓ。其结果与矿物化学成分理论值十分接近，主、次量元素平行测定６次，其ＲＳＤ小于０．８％，痕量元素ＲＳＤ（ｎ＝６）小于１０％。     

四川紫色水稻土氧化铁的分异

以岷江冲积物、黄壤残积物发育成的水稻土为对照,研究了紫色砂岩泥岩母质发育成的紫色水稻土氧化铁的形态及其含量和转化。揭示了紫色水稻土具有无定形铁含量,铁活化度较高,氧化铁的转化作用较弱等独特的发生特性。     

冀东迁安铁矿区早前寒武纪硅铁岩矿层褶皱变形序列

文中根据硅铁矿层的褶皱形态、复合关系等确定迁安铁矿区在中元古代之前发生过6期褶皱变形,叙述了这6期褶皱的特征和分布,讨论了褶皱的成因。区内各期褶皱形态演化规律反映了变形过程中岩石塑性有规律递减的特点。这一演化规律对研究早前寒武纪地区褶皱变形和指导该区找矿工作有重要意义。