ZT-TG500推管机的研制

介绍了ZT-TG500型推管机的参数、工作原理、主要结构构成及其功能、关键技术、用途。推管机在非开挖施工过程中,对非开挖设备起到了辅助的作用,能够“营救”施工中卡死的管线,也可以协助非开挖设备推动管线前进,保证工程的成功。该推管机采用电液比例控制技术,能够实现零到最大无级调速,给施工带来了很多的益处;卡瓦橡胶硫化涂覆技术,保证了卡瓦夹紧时不损坏钢管表面的防腐层,同时保证了足够的夹持力而不打滑;双油缸同步防扭技术,采用滑动导轨与大型分流阀的机液控制方法,来实现油缸的零阻力,使油缸的推力能有效地应用到工程中。通过青州水管铺设与穿越松花江的自来水管铺设的现场应用,取得了良好的效果。     

Occurrence and Chemical Compositions of Amphiboles in Altered Dioritic Rocks of Laiwu Skarn‐Type Iron Deposit in West Shandong Area,China

The Laiwu Fe deposit is the largest skarn‐type deposit in West Shandong in China, with an estimated reserve of 290 Mt of iron ore. Here, we investigate the occurrence and chemical composition of amphiboles in altered dioritic rocks of this deposit. Three generations of amphibole group minerals were identified in these rocks. The first type (Type 1) is a hornblende with a generally euhedral crystal shape, 150–500 μm in size, and dominantly occurs in the host monzonite. The second type (Type 2) of hornblende occurs as fine grains (<100 μm) or concentric rims, less than 50 μm in thickness, around the Type 1 hornblende. The third type (Type 3) of amphibole is anhedral actinolite occurring along the boundary or the cracks of the Type 1 or 2 hornblende grains. The Type 1 hornblende has higher FeO (12.5–15.6 wt.%) and lower MgO contents (11.2–14.6 wt.%) than the Type 2 hornblende, which has an FeO content ranging from 8.8 to 10.5 wt.% and MgO content ranging from 14.2 to 17.1 wt.%. The Type 3 actinolite shows the lowest FeO (4.6–6.4 wt.%) and highest MgO (19.8–21.2 wt.%) contents. We infer that the Type 2 hornblende formed from Fe‐rich hydrothermal fluids released during rapid upwelling of the crystallizing magma. The fluids were relatively reduced and enriched in Fe. The Type 3 actinolite formed by coupled dissolution and reprecipitation, and its formation is one of the features denoting Fe‐enrichment events. Our study of these types of amphibole provides insights into the ore formation process.     

新疆伊吾县宝山铁矿床矽卡岩成因研究

宝山铁矿床位于东准噶尔库兰卡孜干-北塔山-纸房-琼河坝岛弧带东段。宝山铁矿中矽卡岩与铁矿体密切共生,是重要的找矿标志。研究区矽卡岩中石榴子石、透辉石单矿物电子探针分析结果显示,石榴子石属于钙铁榴石-钙铝榴石系列,透辉石属于透辉石-钙铁辉石系列。矽卡岩中高场强元素(如Nb、Ta、Zr、Hf)相对亏损,稀土元素表现出LREE富集,HREE亏损的特点。∑REE为39.90×10~(-6)~178.43×10~(-6),∑LREE/∑HREE比值1.64~7.53,(La/Yb)N比值为1.32~10.10,轻、重稀土元素分异程度较弱,与玄武质凝灰岩具有相似的地球化学特征,这说明矽卡岩是玄武质凝灰岩受后期岩浆热液改造形成,随着温度和压力降低,磁铁矿沉淀形成铁矿体。     

甘肃省肃南县桦树沟铁铜矿床地质特征及成矿模式

甘肃北祁连西段桦树沟铁铜矿床是西北地区一个非常重要的铁铜矿床,对其地质特征及成矿模式的研究,将会对研究该成矿带铁铜矿床的成矿模式具有深远意义。通过大量的工作,认为桦树沟铁铜矿床为产于长城系上岩组的一套陆源碎屑岩夹碳酸沉积建造的同生海底喷流沉积矿床。铁矿体控矿构造主要是区域褶皱带,主要赋存于长城系上岩组的含铁细碎屑—粘土岩建造中,具体岩性为千枚岩。铜矿体的产出明显受后期韧性剪切带和层间滑动带共同控制,主要矿石类型有含铁碧玉岩型和蚀变千枚岩型两种。     

几内亚福雷卡里亚YML铁矿区的富铁矿床地质特征及找矿前景探讨

YML铁矿区位于几内亚福雷卡里亚省,富铁矿以条带状赤铁矿和铁角砾岩矿为主。矿区内共发育7条矿体,条带状赤铁矿体6条,铁角砾岩矿体1条。条带状赤铁矿体赋存部位多为向形地段,次级紧密褶皱发育,沿走向和倾向有逐渐变薄和尖灭的趋势;铁角砾岩矿体覆盖于地表,以风化壳的形式出现。矿床类型属复合类型,即海底热液喷气沉积叠加后期构造变质型+风化淋滤型。该区具备铁矿形成和保存的地质条件,且已发现具一定储量、品位较高的条带状赤铁矿和大面积的铁角砾岩分布区,区内铁矿找矿远景较好。     

云南沾益小米戛磷矿渔户村组磷块岩地球化学特征及成因分析

小米戛磷矿是云南曲靖沾益地区新发现的矿床。本文对该矿床渔户村组磷块岩的主量、微量和稀土元素地球化学特征进行研究,探讨沾益渔户村组磷块岩的成磷环境和成磷物质来源。研究表明小米戛磷矿磷块岩富SiO_2(28.50%～51.47%)、CaO(20.21%～34.31%)、P_2O_5(15.48%～25.42%)。磷块岩中Ba、Sr、Cu、Pb、Zn、V、Mo等元素富集,显示生物聚磷作用。磷块岩的Sr/Ba=0.10～1.40,U/Th比值大于1(1.35～4.15),表明磷块岩的形成可能有热液活动的参与。磷块岩稀土元素总量较高(148.84×10~(-6)～232.16×10~(-6)),经北美页岩标准化的稀土配分模式曲线近水平,但LREE/HREE=2.96～5.37,显示一定程度的轻稀土元素富集,进一步暗示磷矿的形成受热水沉积成矿作用与生物成矿作用共同控制。磷块岩中U元素高度富集(富集系数平均值8.84),V/Cr=1.08～3.01(平均值为2.12),Ce_(anom)=-0.50～-0.35,介于-0.5与-0.1之间,表明磷块岩形成于次氧化环境。综上所述,在早寒武世渔户村期的潮坪-泻湖环境,磷质沉积物发生胶结作用形成初始磷矿层;后期生物繁盛,生物遗体中所含的磷被大量地分解,不同深度的大量含磷物质伴随上升洋流进一步改造初始磷矿层,最终成矿。     

黄原胶改性微米铁修复地下水中Cr(Ⅵ)污染的试验

为了解决微米铁的重力沉降问题,提高微米铁修复地下水Cr（Ⅵ）污染的原位修复效果,本文利用黄原胶对微米铁进行改性,并通过沉降实验探究改性微米铁浆液的稳定性,同时选择Cr（Ⅵ）作为目标污染物,探究黄原胶改性微米铁去除地下水Cr（Ⅵ）污染的降解能力。实验结果显示：当黄原胶的投加质量浓度分别为0.0、1.0、1.5、2.0、2.5、3.0、6.0 g/L时,改性微米铁浆液的悬浮稳定性逐渐得到加强,在5 h沉降实验结束时,对应的相对分光光度值分别为0.05、0.25、0.46、0.57、0.65、0.73和0.87;黄原胶具有抑制微米铁吸附Cr（Ⅵ）的能力,其可促进Cr（Ⅵ）的还原,提高Cr（Ⅵ）的去除率;随着黄原胶投加质量浓度的增加,对应的Cr（Ⅵ）去除率分别为33.4%、41.2%、47.4%、51.1%、53.0%、63.9%和64.1%;6.0 g/L黄原胶改性的微米铁浆液具有最佳的悬浮稳定性,黄原胶的投加提高了微米铁的反应活性,但当黄原胶投加质量浓度超过3.0 g/L时,其对Cr（Ⅵ）的去除率没有显著提高;黄原胶投加质量浓度越大,黄原胶的缓冲作用就越明显。     

白云鄂博矿床东矿段深部及白云向斜核部探矿的可行性探讨

白云鄂博东矿（铁矿石）已属于轻度危机矿山,解决白云鄂博东矿的资源接续问题已迫在眉睫。依据老地质资料和生产过程中的新发现,参考多位矿床成因研究专家的成果,笔者等认为在白云鄂博东矿体深部及白云向斜核部探矿是可行的。     

Adsorption of Pentachlorophenol onto Oxide and Clay Minerals： Surface Reaction Model and Environmental Implications

The adsorption of pentachlorophenol （PCP） onto quartz, kaolinite, illite, montmorillonite and iron oxides has been investigated by batch equilibrium techniques. The pH-dependent isotherms are curves with peak values, the position of which is at about pH = 5-6 depending on the mineral species. Based on distribution of both speciation of surface hydroxyls on minerals and PCP in solution a surface reaction model involving surface complexation and surface electrostatic attraction is presented to fit the pH-dependent isotherms, and both reaction constants are calculated. The results show that on quartz and phyllosilicate minerals the predominant adsorption reaction is surface complexation, meanwhile both of surface electrostatic attraction and surface complexation are involved on the iron oxide minerals. The reaction constants of surface electrostatic adsorption are usually one to three orders in magnitude, larger than that of surface complexation. The concentration-dependent isotherms can be well fitted by Langmnir equation with the correlation coefficient R〉0.93 for kaolinite and iron oxides. The maximum adsorption is found in the order： hematite 〉 lepidocrocite 〉 goethite 〉 kaolinite 〉 quartz 〉 montmorillonite ≈ illite, which can be interpreted by consideration of both reaction mechanism and surface hydroxyl density. The significant adsorption of PCP onto mineral surfaces suggests that clay and iron oxide minerals will play an important role as HIOCs are adsorbed in laterite or latertoid soil, which is widespread in South China.     

河北中关矽卡岩铁矿床钴元素分布规律与沉淀机制研究及意义

河北中关铁矿是“邯邢式”矽卡岩铁矿的代表矿床,本文将中关铁矿床成矿过程划分为5个阶段：干矽卡岩阶段、湿矽卡岩阶段、氧化物阶段、铁铜硫化物阶段和铅锌硫化物阶段。对湿矽卡岩阶段、氧化物阶段和铁铜硫化物阶段的金属矿物（包括黄铁矿、磁铁矿、赤铁矿等）开展电子探针测试,并且对这三个成矿阶段的代表性磁铁矿进行LA-ICP-MS微量元素测试,旨在查明中关铁矿床中Co的赋存状态以及在矿床不同成矿阶段的分布规律,探讨Co元素迁移演化-沉淀机制。研究结果表明,Co主要以类质同象的形式存在于黄铁矿中。不同成矿阶段的Co元素分布不均匀,氧化物阶段黄铁矿和磁铁矿中的Co含量最高,分别为0.12%~1.39%、41×10-6~76×10-6;铁铜硫化物阶段黄铁矿大量出现,且Co含量相对较高,为BDL~0.45%,同时期条带状磁铁矿为32×10-6~71×10-6,故此阶段为Co元素最主要的富集阶段。湿矽卡岩阶段为较高温、弱氧化条件,氧化物阶段温度逐渐降低,氧逸度增加,Co可能主要以CoCl42?形式络合迁移;铁铜硫化物阶段温度进一步降低,但还原性增加,Co可能主要以CoCl42?和Co(HS)+形式络合迁移。温度降低以及氧化还原条件的变化可能是控制Co沉淀的重要因素。