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161.
162.
Joseph A. Shacat William J. Green Eric H. Decarlo Silvia Newell 《Aquatic Geochemistry》2004,10(3-4):325-352
Lake Joyce is one of the least studied lakes of the McMurdo Dry Valleys. Similar to other lakes in this region, Lake Joyce is a closed-basin, permanently ice-covered, meromictic lake. We present here a detailed investigation of major ions, nutrients, and dissolved trace elements for Lake Joyce. Specifically, we investigate the role of iron and manganese oxides and hydrous oxides in trace metal cycling.Lake Joyce is characterized by fresh, oxic waters overlying an anoxic brine, primarily Na–Cl. Surface waters have a maximum nitrate concentration of 26M with a molar dissolved inorganic nitrogen to phosphorus ratio of 477. The supply of nitrogen is attributed to atmospheric deposition, possibly from polar stratospheric clouds. Dissolved phosphorus is scavenged by hydrous iron oxides. The pH is highest (10.15) just beneath the 7-m thick ice cover and decreases to a minimum of 7.29 in the redox transition zone. Dissolved Al exceeds 8M in surface waters, and appears to be controlled by equilibrium with gibbsite. In contrast, concentrations of other trace elements in surface waters are quite low (e.g., 5.4nM Cu, 0.19nM Co, <20pM La). Dissolved Fe, Mn, Ni and Cd were below our detection limits of 13 nM, 1. 8 nM, 4.7 nM and 15pM (respectively) in surface waters. There was a 6-m vertical separation in the onset of Mn and Fe reduction, with dissolved Mn appearing higher in the water column than Fe. Based on thermodynamic calculations, dissolved Mn appears to be controlled by equilibrium with hausmannite (Mn3 O4 ). Co tracks the Mn profile closely, suggesting Co(III) is bound in the lattice of Mn oxides, whereas the Ce profile is similar, yet the Ce anomaly suggests oxidative scavenging of Ce. Release of Cu, Ni, Cd and trivalent REE appears to be controlled by pH-induced desorption from Fe and Mn oxides, although Cu (and perhaps Ni) may be scavenged by organic matter in surface waters. 相似文献
163.
含铬废水具有有机物含量高,难降解物质浓度高,色度大,悬浮物多,水质、水量变化大,含有微量毒性物质等特点。本文探讨了在不同参数条件下,硫酸亚铁、铁、硫化亚铁三种还原剂对含铬废水处理效果的影响,实验表明:硫酸亚铁具有明显的优越性,在同等条件下其去除率达到99%以上。 相似文献
164.
165.
北京奥运会期间CBM-Z化学机制的模拟应用 总被引:1,自引:0,他引:1
利用CBM-Z化学机制模拟了中国科学院大气物理研究所气象塔站在北京奥运会期间高臭氧时段O3浓度的日变化,评估了气象条件、北京奥运会加强控制措施以及O3前体物浓度对近地面O3生成的影响。结果表明:(1)CBM-Z化学机制较好地模拟了北京奥运会期间典型时段气象塔站O3、NO、NO2日变化特征。(2)有利于局地高臭氧事件发生的气象条件非常相似;北京奥运会加强控制措施的实施显著减少了NOx及VOCs的排放量,导致近地面O3浓度的明显下降。(3)奥运会期间VOCs和CO是影响气象塔站O3生成量的关键因素。 相似文献
166.
纳米铁去除饮用水中As(Ⅲ)和As(Ⅴ) 总被引:3,自引:1,他引:2
在好氧水体中,As(Ⅲ)比As(Ⅴ)更易迁移,而且在水处理过程中去除效率更低。在实验室合成制得BET比表面积为49.16 m2/g,直径范围为20~40 nm的纳米铁。通过批试验考察纳米铁对As(Ⅲ)和As(Ⅴ)去除能力及其反应动力学情况。结果表明,在pH为7,温度20℃时纳米铁能够快速地去除As(Ⅲ)和As(Ⅴ),在60 m in内,0.25 g纳米铁对起始浓度为968.6μg/L As(Ⅲ)和828.9μg/L As(Ⅴ)的去除率大于99.5%。反应遵循准一级反应动力学方程,标准化后的As(Ⅲ)和As(Ⅴ)比表面积速率常数kSA分别为1.30 mL/(m2.m in)和1.64 mL/(m2.m in)。由实验结果可知,具有高反应活性的纳米铁是用于含砷饮用水处理非常有效的吸附材料。 相似文献
167.
168.
169.
P. Sriramachandran S. P. Bagare N. Rajamanickam K. Balachandrakumar 《Solar physics》2008,252(2):267-281
High-resolution Fourier Transform Spectrometer sunspot umbral spectra of the National Solar Observatory/National Optical Astronomy
Observatory at Kitt Peak were used to detect rotational lines from 19 electronic transition bands of the molecules LaO, ScO
and VO, in the wavenumber range of 11 775 to 20 600 cm−1. The presence of lines from the following transitions is confirmed: A
2
Π
r1/2 – X
2
Σ
+(0, 0; 0, 1), A
2
Π
r3/2 – X
2
Σ
+(1, 0), B
2
Σ
+ – X
2
Σ
+(0, 0; 0, 1; 1, 0) and C
2
Π
r1/2 – A′2Δ
r3/2(0, 0; 1, 1) of LaO; A
2
Π
r3/2 – X
2
Σ
+(0, 0), A
2
Π
r1/2 – X
2
Σ
+(0, 0) and B
2
Σ
+ – X
2
Σ
+(0, 0) of ScO; and C
4
Σ
− – X
4
Σ
−(0, 1; 1, 0; 0, 2) and (2, 0) of VO. However, the presence of A
2
Π
r3/2 – X
2
Σ
+(0, 0) and C
2
Π
r3/2 – A′2Δ
r5/2(0, 0; 1, 1) of LaO and C
4
Σ
− – X
4
Σ
−(0, 0) of VO are found to be doubtful because the lines are very weak, and detections are difficult owing to heavy blending
by strong rotational lines of other molecules. Equivalent widths are measured for well-resolved lines and, thereby, the effective
rotational temperatures are estimated for the systems for which the presence is confirmed. 相似文献
170.